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High-temperature alloy base self-lubricating composite material and surface pattern treatment method thereof

A technology of composite materials and high-temperature alloys, applied in metal processing equipment, manufacturing tools, mechanical equipment, etc., can solve the problem that it is difficult to predict the improvement degree of micropores to the lubrication state, it is rarely used in solid lubrication occasions, and it is difficult to achieve micropore shape and The design and accurate control of the distribution state can achieve the effect of increasing the service life and improving the tribological performance

Inactive Publication Date: 2007-11-28
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the patterning treatment method is mainly used in mechanical seals to improve the lubrication state of end seals under elastohydrodynamic lubrication conditions, and is rarely used in solid lubrication applications, especially high temperature solid lubrication applications
[0005] The patent CN1586770 published in 2005 prepared self-lubricating materials by compounding solid lubricating particles into a metal matrix. The sintered matrix has sweat gland-like micropores of 0.05-8 μm, and solid lubricant particles are compounded in sweat gland-like micropores. The lubricant in the medium diffuses to the friction surface to achieve the purpose of high temperature self-lubrication. This method is difficult to realize the design and accurate control of the shape and distribution of the micropores, so it is difficult to predict the degree of improvement of the micropores to the lubrication state.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: The components and their mass percentages of the superalloy-based self-lubricating composite material of the present invention are Ni: 56.8%, Fe: 10.0%, Cr: 11.4%, W: 10.0%, C: 6.0%, Si : 0.8%, MoS 2 : 5.0%. The particle size of Ni is less than 45 μm, and the purity is greater than 96%, and the reduced iron powder with a purity greater than 98% is used for Fe. After mixing the above components and their mass percentages of metal powders, mix them on a ball mill at a speed of 150r / min for 30 minutes. Cold press the mixed powders into a disc-shaped sample (Φ45×8mm) in a steel mold , and then put the samples into the graphite mold in turn, and separate each two samples with a graphite sheet, and hot press them on the FVPHP-R-10 Fuji vacuum hot press, and first vacuumize to 1×10 -5 Pa, filled with nitrogen for protection, then heated up to 1200-1240°C, after reaching the temperature, apply a positive pressure of 16MPa, and hold the temperature for 30min. The n...

Embodiment 2

[0019] Example 2: The components of the superalloy-based self-lubricating composite material of the present invention and their mass percentages are Ni: 36.6%, Fe: 30%, Cr: 9.2%, W: 10%, Si: 1.2%, C : 3%, MoS 2 : 10%. The particle size of Ni is less than 45 μm, and the purity is greater than 96%, and the reduced iron powder with a purity greater than 98% is used for Fe. After mixing the above-mentioned components and their mass percentages of metal powder, first cold-press them into a disc-shaped sample (Φ45×8mm) in a steel mold, and then put the samples into graphite molds in turn. In the FVPHP-R-10 type Hot press molding on Fuji vacuum hot press, first vacuum to 9×10 -5 Pa, filled with nitrogen for protection, then heated up to 1240-1280°C, after reaching the temperature, apply a positive pressure of 12MPa, and keep the pressure for 20min. The surface patterning method of superalloy-based self-lubricating composite materials is to use a 124-type Nd:YAG laser to etch micro...

Embodiment 3

[0020] Example 3: The components of the superalloy-based self-lubricating composite material of the present invention and their mass percentages are Ni: 28.8%, Fe: 30.0%, Cr: 7.2%, W: 15.0%, Si: 1.0%, C : 3.0%, MoS 2: 15.0%. After mixing the above-mentioned components and their mass percent powders, they are cold-pressed into a disc-shaped sample in a steel mold, and then the samples are sequentially loaded into a graphite mold and heated on a FVPHP-R-10 Fuji vacuum hot press. Press molding, first vacuum to 5×10 -5 Pa, filled with nitrogen for protection, then heated up to 1240-1280°C, after reaching the temperature, apply a positive pressure of 12MPa, and keep the pressure for 20min. The surface patterning treatment method of superalloy-based self-lubricating composite materials is to use a 124-type Nd:YAG laser to etch micropores, the wavelength is 1064nm, the focal length is adjusted to 40mm, the spot diameter at the focus is 0.15mm, and the pulse width is adjusted to 450...

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Abstract

A kind of high temperature alloy group self-lubricating compound material and the method to pattern surface of it. The components and the mass percent of them are as following: Ni: 28.8-56.8%, Fe: 10.0-30.0%, Cr: 7.2-14.2%, W: 5.0- 15.0%, C: 3.0-6.0%, Si: 0.8%-1.2%, MoS2: 5.0%-15.0%. The method to pattern it' s surface contains the following steps: The surface of the nickel chromium alloy group self-lubricating compound material sample after being hot pressed and mould will be polished. A gammaray laser will be used to corrase micropore on the surface, the focus of the focusing lens will be adjusted to 40-60mm, the facula diameter at the focus is 0.15- 0.20mm, the impulse duration will be adjusted to 450-500ns, the laser bean will process micropore according to ring shape from outside to inside. The surface after being corrased and polished will be lubricated by daubing the fat of solid layered dry lubricant. The alloy group material not only owns high mechanical strength but also owns high temperature self-lubricating ability. The coefficient of friction can be decreased, the application life can be prolonged, and low attrition abrasion in wide temperature range can also be realized by patterning the surface.

Description

technical field [0001] The invention belongs to the self-lubricating composite material and its surface modification technology, which is used to solve the lubrication problem of space mechanical bearings and sealing parts that cannot be lubricated by grease under harsh conditions such as high temperature and high pressure, especially a high-temperature alloy-based self-lubricating composite material and a surface patterning treatment method thereof. Background technique [0002] The development of high and new technologies such as aviation, aerospace, nuclear energy, etc. has put forward higher requirements for high-temperature performance and high-temperature lubrication of materials. For example, the working temperature of adiabatic diesel engine bearing liners reaches 600-1000 °C. Ordinary lubricating grease is no longer applicable. Solid lubricants, such as some metal sulfides, oxides, soft metals, etc., can withstand high temperatures and reduce wear. Therefore, the us...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05C22C30/00C22C1/04B24B1/00B23K26/00F16C33/12B23K26/362
Inventor 熊党生李建亮
Owner NANJING UNIV OF SCI & TECH
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