Pressure-sensitive adhesive sheets for wafer grinding and warp inhibiting
A pressure-sensitive adhesive sheet, pressure-sensitive adhesive layer technology, applied in the direction of film/sheet-like adhesives, applications, adhesives, etc., can solve the problem of expensive pressure-sensitive adhesive sheets, complicated steps, and not always performance. best and so on
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Embodiment 1
[0056] In toluene, 97 parts by weight of butyl acrylate, 2 parts by weight of methyl methacrylate, and 3 parts by weight of acrylic acid were copolymerized by a solution polymerization method to obtain an acrylic polymer having a weight average molecular weight of 550,000. 100 parts by weight of this acrylic polymer was mixed with 0.3 parts by weight of an epoxy crosslinking agent (trade name "TETRAD C", manufactured by Mitsubishi Gas Chemical Co., Ltd.) to obtain a pressure-sensitive adhesive composition A. Using a fountain die method, the pressure-sensitive adhesive composition A was applied to a processing sheet for casting (50 μm-thick PET film, produced by Toray Industries, Inc.) in an amount such that a dry thickness of 20 μm was obtained. . In this way, a pressure-sensitive adhesive layer was formed.
[0057] A laminated film A having a thickness of 150 μm and including a three-layer structure of polyethylene / amorphous polypropylene / polyethylene was prepared as a subst...
Embodiment 2
[0059] In toluene, 50 parts by weight of ethyl acrylate, 50 parts by weight of butyl acrylate, and 5 parts by weight of acrylic acid were copolymerized to obtain an acrylic polymer having a weight average molecular weight of 650,000. 100 parts by weight of this acrylic polymer was mixed with 20 parts by weight of an ultraviolet curable oligomer (trade name "UV-1700", produced by The Nippon Synthetic Chemical Industry Co., Ltd.), 1 part by weight of polyisocyanate cross-linked (trade name "Coronate L", manufactured by Nippon Polyurethane Co., Ltd.) and 3 parts by weight of a photopolymerization initiator (trade name "Irgacure 651", manufactured by Ciba Specialty Chemicals Co.). In this way, an energy ray-curable acrylic pressure-sensitive adhesive composition B was obtained.
[0060] Subsequent operations were performed in the same manner as in Example 1 except that pressure-sensitive adhesive composition B was used instead of pressure-sensitive adhesive composition A. In this...
Embodiment 3
[0062] The same procedure as in Example 1 was performed except that a polyimide film (trade name "200H", manufactured by Du Pont-Toray Co., Ltd.) having a thickness of 50 μm was used as a base material. In this way, a pressure-sensitive adhesive sheet C was obtained.
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