Silicate substrate luminescent material with multiple emission peak, preparation method thereof and luminescent device using the same
A technology for luminescent materials and light-emitting devices, applied in luminescent materials, chemical instruments and methods, electrical components, etc., can solve problems such as poor chemical stability and aging resistance, shortened service life, and low luminous brightness
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Embodiment 1
[0057] raw material
[0058] The raw materials of the above composition are fully ball milled and mixed, put into a crucible, and after cooling, put them into a furnace filled with a mixed gas of 95% nitrogen and 5% hydrogen for sintering, and heat-preserve and sinter at 1200°C for 6 hours . After the sintered body is cooled, pulverize, grind with a ball mill, and then sieve with a 325-mesh sieve, the chemical composition obtained in the present invention is 2.97BaO 1.02MgO 2.01SiO 2 :0.01Eu 2+ 0.05Mn 2+ 0.005F - 0.005 Li + of luminous materials. The excitation spectrum of the material is in the range of 240-450nm; the emission spectrum has three emission peaks in the range of 400-760nm, and the emission peak wavelengths are respectively located at 438nm, 502nm and 617nm.
Embodiment 2~36
[0060] Prepare Examples 2-36 according to the process flow in Example 1, wherein the element types and contents of A and A' in the matrix composition are changed according to the wavelength position of the emission peak; the firing temperature is in the range of 1000-1300 ° C according to the furnace capacity It varies with the weight of the material, the type of the material and the formula; the reducing atmosphere is in the presence of hydrogen, ammonia, nitrogen and hydrogen or carbon particles. Luminescent material examples of the following chemical compositions with double emission peaks were obtained.
Embodiment 2
[0061] Example 2 2.03SrO·0.92MgO·1.0SiO 2 :0.03Eu 2+ 0.02F - 0.07Li +
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