Biological treatment technique for coking waste water

A technology for biological treatment and coking wastewater, applied in sustainable biological treatment, biological water/sewage treatment, chemical instruments and methods, etc., can solve the problems of occupying the effective reaction space of the filter, shortening the hydraulic retention time, and long hydraulic retention time. , to achieve the effect of shortening hydraulic retention time, reducing infrastructure investment, and stabilizing the operation effect.

Active Publication Date: 2008-07-09
北京嘉瑞环保股份有限公司
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  • Abstract
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  • Claims
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Problems solved by technology

[0003] 1. Anaerobic-anoxic-aerobic (A 1 -A 2 -O) or anoxic-aerobic (A-O) serial biologically activated sludge method has the disadvantages of low treatment load (for example, the COD sludge load in the aerobic pool is only 0.4-0.7kgCOD/kg.mlvss.d, and the aerobic Pool COD volume load is only 0.7~1.2kgCOD/m 3 .d; A-A-O overall COD volume load is only 0.6~1.0kgCOD/m 3 .d), the hydraulic retention time is long (30-90h, depending on the quality of the wastewater), and a secondary sedimentation tank must be installed, resulting in a large area and high infrastructure investment
[0004] 2. Anaerobic-anoxic-aerobic (A 1 -A 2 -O) or anoxic-aerobic (A-O) biofilm reactors connected in series to form a biological treatment process, although the treatment load is increased and the hydraulic retention time is shortened compared with the activated sludge treatment process, however, the treatment load Still low (for example, the COD volume load of the aerobic pool is only 0.8-1.5kgCOD/m 3 .d; A-A-O overall COD volume load is only 1.0~1.8kgCOD/m 3 .d), the hydraulic retention time is still too long (25-60h, depending on the qu

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  • Biological treatment technique for coking waste water

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Effect test

Embodiment 1

[0022] Example 1, higher concentration coking wastewater: influent water quality is as follows: COD 3300mg / l, ammonia nitrogen 200mg / l, CN -12mg / l, oil 50mg / l, phenol 680mg / l, pH6-9. In Figure 1, after pretreatment (adjustment, oil separation, flotation), the wastewater enters the anaerobic ceramsite filter. The ceramsite filter (reflux ratio 1:1), the effluent of the anoxic ceramsite filter enters the aerobic ceramsite filter, the outlet of the aerobic ceramsite filter enters the post-coagulation treatment section, and part of it flows back into the anoxic ceramsite filter pool (reflux ratio 6:1), there is no secondary sedimentation tank after the aerobic ceramsite filter; anaerobic, anoxic and aerobic ceramsite filters use spherical ceramsite filter material as the film-hanging filler. The ceramsite filter material in the anaerobic ceramsite filter has a particle size of 8-10mm in the lower layer and 6-8mm in the upper layer; in the anoxic ceramsite filter, the particle siz...

Embodiment 2

[0023] Example 2, lower concentration coking wastewater: influent water quality is as follows: COD 1500mg / l, ammonia nitrogen 70mg / l, CN - 8mg / l, oil 50mg / l, phenol 400mg / l, pH6.5-8.5. In Figure 1, after pretreatment (adjustment, oil separation, flotation), the wastewater enters the anaerobic ceramsite filter, and the outlet end of the anaerobic ceramsite filter enters the anoxic filter, and part of it flows back into the anaerobic ceramsite filter (reflux ratio 1:1), the effluent from the anoxic ceramsite filter enters the aerobic filter, the effluent from the aerobic ceramsite filter enters the post-coagulation treatment section, and part of it flows back into the anoxic ceramsite filter (reflux ratio 6:1), there is no secondary sedimentation tank after the aerobic ceramsite filter; anaerobic, anoxic and aerobic ceramsite filters use irregular shaped ceramsite filter material as the hanging film filler. The ceramsite filter material in the anaerobic ceramsite filter has a m...

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Abstract

The invention discloses a technique of biological treatment for coking wastewater. The filter chamber is composed of a preprocessing part, a biological treatment part and a physical treatment part, wherein the biological treatment part is composed of an anaerobic ceramsite filter chamber, an anoxia ceramsite filter chamber and an aerobic ceramsite filter chamber which are connected in series, spherical ceramsite filtering materials or irregular-shape ceramsite filtering materials are all filled in the anaerobic ceramsite filter chamber, the anoxia ceramsite filter chamber and the aerobic ceramsite filter chamber as biofilm culturing filling and filtrating precoats, the anaerobic ceramsite filter chamber employs an internal reflux mode, a reversed flow mode is employed between the anoxia ceramsite filter chamber and the aerobic ceramsite filter chamber, the precoats in the filter chambers are respectively formed by ceramsite filtering materials with different thickness, the filter chambers employs backwash to exclude accumulated sludge and suspended substance in the filter chambers into flotation tanks of the preprocessing part, the anaerobic ceramsite filter chamber, an anoxia ceramsite filter chamber employs regular water scrubbing to drive macro-gas-bubble in the chambers. Compared with the prior art, the technique has the advantages of prolonging sluicing periodic time, stabilizing operational effect, improving treatment loading, thereby reducing retention time of waterpower, decreasing accommodation area and investment of pile plant.

Description

technical field [0001] The invention relates to a biological treatment process of coking wastewater, in particular to a biological treatment process in which different types of biological ceramsite filters are connected in series for the biological treatment of coking wastewater. Background technique [0002] The coking wastewater treatment process generally consists of three parts: pretreatment (such as adjustment, oil removal, flotation, etc.), biological treatment and physical and chemical treatment (such as coagulation, sedimentation, etc.), and the biological treatment is the core of the whole process. So far, the biological treatment part of most coking wastewater treatment processes at home and abroad has adopted two forms: the first is anaerobic-anoxic-aerobic (A 1 -A 2 -O) or anoxic-aerobic (A-O) series biologically activated sludge method, which uses activated sludge to remove pollutants as the main means of purifying wastewater; the second is anaerobic-anoxic-aer...

Claims

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Application Information

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IPC IPC(8): C02F9/14C02F3/30C02F3/10
CPCY02W10/10
Inventor 汤苏云
Owner 北京嘉瑞环保股份有限公司
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