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SiC based composite material component and on-line jointing preparation method thereof

A composite material component and composite material technology, applied in the field of SiC-based composite material components, can solve the problems of reducing the high-temperature service performance of connecting joints, reducing the joint performance of connecting joints, and PCS melting loss, etc., achieving good chemical and mechanical compatibility, The effect of good integrity and guaranteed reliability

Inactive Publication Date: 2008-07-23
NAT UNIV OF DEFENSE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the connection of SiC-based composite materials, silicone resin bonding adhesives are mostly used at present. The cracked connection layer components (Si-O-C ceramics) have poor high temperature resistance and can only be used under conditions below 1100 °C.
The precursor polycarbosilane (PCS) of SiC is used as the adhesive mainly for the connection of hot-pressed SiC-based ceramics, and there are also a few reports for the connection of SiC / SiC composite materials, but generally the active filler Si is added to the PCS. To reduce the volume shrinkage of PCS during the pyrolysis process, and the presence of Si will greatly reduce the high-temperature performance of the connection joint; in addition, if a single-component PCS is used as the adhesive, the melting loss of PCS will occur during the high-temperature cracking process, resulting in reduced binding properties of the connecting joints

Method used

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  • SiC based composite material component and on-line jointing preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] As shown in Figure 1 and Figure 2, a SiC-based composite material component is formed by connecting the prefabricated SiC-based composite material online by the connector b, the component of the connecting layer a is SiC material, and the two are connected Part b adopts a lap joint structure at the connection joint. There is a pin c connecting the connected part and the connection layer at the connection joint. The diameter of the connection hole of the pin c is Φ5mm. The material is processed. The SiC-based composite material component is prepared by the following method:

[0024] (1) Weave the No. 2 rubber carbon fiber prepared by 6K Jilin Carbon Fiber Factory into a flat plate, vacuum impregnate the mixed solution of PCS / xylene (the mass ratio of PCS to xylene is 1:1), and heat it at 1100 ° C under Ar gas Carry out high-temperature pyrolysis under protection, repeat the impregnation and cracking process for 6 cycles, process the obtained SiC-based composite material...

Embodiment 2

[0030] As shown in Figure 1, a SiC-based composite material component is formed by connecting prefabricated SiC-based composite materials online by a connector b, the component of the connecting layer a is SiC material, and the two connected parts b are in The connecting joint adopts a lap joint structure, and the connecting joint is provided with a pin c connecting the connected part b and the connecting layer a. The diameter of the connecting hole of the pin c is Φ3mm, and the connecting pin c is a one-dimensional SiC / SiC-based composite material processed. The SiC-based composite material component is prepared by the following method:

[0031] (1) Weave Hi-Nicalon SiC fibers into a flat plate, vacuum impregnate PCS in xylene solution (the mass ratio of PCS to xylene is 1:1), and heat it at 1200 °C under N 2 Carry out high-temperature pyrolysis under protection, repeat the impregnation and cracking process for 6 cycles, and process the obtained SiC-based composite material ...

Embodiment 3

[0035] A SiC-based composite material component, which is formed by connecting prefabricated SiC-based composite material connected parts online, the component of the connecting layer is SiC material, and the two connected parts are connected in a wedge-shaped connection at the joint, There is also a pin connecting the connected part and the connecting layer at the connecting joint. The diameter of the connecting hole of the pin is Φ6mm. obtained by densification. The SiC-based composite material component is prepared by the following method:

[0036] (1) Weave T300 carbon fiber into a flat plate, vacuum impregnate PCS in a xylene solution (the mass ratio of PCS to xylene is 1:1), and heat it at 1200 ° C under N 2 Carry out pyrolysis under protection, repeat the impregnation and cracking process for 6 cycles, process the obtained C / SiC composite material into a connected part with a wedge-shaped connection structure, and make the joints of the two connected parts cooperate wi...

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Abstract

The invention discloses a SiC matrix composite material element and the online connection and preparation method. The element is connected into a whole by the connecting piece through the connection layer at the connector lug, which is characterized in that the component of the connection layer is pure SiC material and the SiC material uses the mix solution of PCS and divinylbenzene as the adhesive, and uses SiC fine power as the packing medium, and can be achieved though preceramic polymer pyrolysis; SiC matrix composite material element with stronger connection strength can be gained through the auxiliary connection and the reinforcement of the fastener of SiC matrix composite material. The SiC matrix composite material element and the online connection and the preparation method has the advantages of simple and practical preparation method, low cost, good thermostable performance and mechanics compatibility, good structural integrity. The connecting preparation method is especially suitable for the connection formation and preparation of large-scale complex components.

Description

technical field [0001] The invention relates to a SiC-based composite material component, and also relates to a connection preparation method for the SiC-based composite material component. Background technique [0002] At present, SiC-based composite materials have good high-temperature mechanical properties. For example, C / SiC composite materials can still maintain high strength and high fracture toughness in an inert environment exceeding 1600 ° C. At the same time, SiC-based composite materials also have thermal expansion coefficients. These excellent properties make it widely used as a high-temperature thermal structural material in aviation, aerospace and energy fields. However, the disadvantages of SiC-based composite materials are also obvious: firstly, it is difficult to form, difficult to process, and high in cost; secondly, the complex high-temperature resistant structural parts made by traditional mechanical connection methods cannot obtain high-temperature conne...

Claims

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Application Information

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IPC IPC(8): C04B37/00
Inventor 张玉娣胡海峰张长瑞王军曹英斌
Owner NAT UNIV OF DEFENSE TECH
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