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Forming method of lithium ion secondary battery using vacuum system

A chemical formation method and secondary battery technology, applied in secondary batteries, secondary battery charging/discharging, secondary battery repair/maintenance, etc., can solve the problems of weakening effect, uneven formation of negative electrode SEI film, affecting battery capacity, etc.

Inactive Publication Date: 2008-10-15
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Existing studies have shown that during formation, the relevant components in the electrolyte will react on the surface of the carbon material. In addition to forming an SEI film, it will also generate various gases such as ethylene, carbon dioxide, hydrogen, and carbon monoxide. If the gas cannot be discharged from the cell in time, It will cause uneven formation of SEI film on the negative electrode, which will affect the cycle life and rate characteristics of the battery.
Based on the above understanding, in the current chemical formation process, most of the initial small current charging, adding static steps to exhaust and improve the SEI film, and centrifugal exhaust to weaken the impact of the generated gas, these methods are time-consuming , laborious and unable to achieve the best exhaust and film forming effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] This embodiment is a 10Ah power battery capable of 4C (40A) charge and discharge using lithium manganate as the positive electrode material and natural graphite as the negative electrode material. Compared with Embodiment 2, it is a lower-end battery.

[0011] After the battery is injected with 35-55ml of liquid, seal the liquid injection port with a stop tape and let it stand for 4-10 hours to ensure that the electrolyte fully infiltrates the diaphragm and pole pieces. Then put the battery on the shelf, charge it with a constant current of 0.1-0.5A, suspend charging when it reaches 3.08V, take the battery off the shelf, and put it in a vacuum oven to evacuate to -0.09MPa. After 5 minutes, refill high-purity argon gas, then seal the liquid injection hole by laser welding aluminum foil, continue to put it on the shelf, charge it with a constant current of 5A to 4.25V, and switch to constant voltage charging for 2 hours. After charging, let it stand for 0.5h, then dischar...

Embodiment 2

[0013] The operation process is the same as in Example 1, wherein the charging cut-off voltage before vacuuming becomes 3.4V, and it is placed in a vacuum oven and vacuumed to -0.1MPa to calculate the formation efficiency and the gram capacity of the positive electrode material, and measure the contact resistance and mass transfer resistance , during the whole process of formation, the ambient temperature is 30°C.

Embodiment 3

[0015] This example uses lithium manganese oxide as the positive electrode material and natural graphite as the negative electrode material, an 8Ah power battery capable of charging and discharging at 15C (120A). Compared with Example 1 and Example 2, it is a higher-end battery. The size of the battery case used in Example 2 is the same as that of Example 1, but a pole with a larger diameter, a tab with a larger total cross-sectional area, and a thinner positive and negative coating are used instead.

[0016] After the battery is injected with 35-55ml of liquid, seal the liquid injection port with a stop tape and let it stand for 4-10 hours to ensure that the electrolyte fully infiltrates the diaphragm and pole pieces. Then put the battery on the shelf, pump out the gas in the battery case through the liquid injection hole, and maintain a negative pressure of -0.07MPa, charge it with a constant current of 0.1-0.5A to 3.6V, suspend charging, and vacuumize to -0.09MPa And keep i...

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PUM

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Abstract

The invention discloses a forming method of lithium ion secondary batteries by using a vacuum system, and relates to a forming method of lithium ion batteries, which is characterized in that: the vacuum system is added and applied during the forming process, which leads the lithium ion secondary batteries to be capable of exhausting generated gas during the forming process, while uniform and solid electrolyte interface films (SEI film) can be formed by each part of pole pieces so as to improve the cycle performance as well as the high-rate discharge property of the lithium ion secondary batteries. In addition, the forming method of the lithium ion batteries can also solve the problems of insufficient electrolyte and the corrosion of battery shells caused by the overflow of the electrolyte during the forming process, thus saving the materials and production cost.

Description

technical field [0001] The invention relates to a method for forming a lithium ion battery, more specifically to a method for forming a lithium ion secondary battery using a graphite negative electrode. Background technique [0002] Since the successful commercialization of lithium-ion secondary batteries in the 1990s, they have rapidly occupied the field of high-end mobile electronics with their outstanding charge-discharge performance and high energy density. In recent years, with the advancement of battery technology and the increasing availability of petroleum resources Lithium-ion secondary batteries have gradually entered the application fields that require high power and high energy density, such as electric vehicles and large UPS power supplies. Contrary to the continuous commercialization of new positive electrode materials, the negative electrode materials of lithium-ion secondary batteries are always carbon materials represented by artificial graphite, natural gra...

Claims

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Application Information

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IPC IPC(8): H01M10/40H01M10/38H01M10/44H01M10/058
CPCY02E60/122Y02E60/10Y02P70/50
Inventor 邱新平郑曦安杰吴方旭朱文涛王健
Owner TSINGHUA UNIV
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