Method for preparing foamed aluminium and aluminum alloy by secondary foaming with novel blowing agent

A foamed aluminum alloy and foamed aluminum technology are applied in the field of preparation of closed-cell foamed aluminum and foamed aluminum alloy, which can solve problems such as high cost, increased production cost, and unstable process, and achieve enhanced stability, increased viscosity, and convenient storage Effect

Inactive Publication Date: 2011-04-20
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the high-tech fields such as aerospace and aerospace, foamed aluminum and alloy special-shaped parts have become the frontier hotspots of international material research as ultra-light materials. It is difficult to prepare special-shaped parts by melt foaming, and the production of foamed aluminum special-shaped parts by powder metallurgy is costly. , Disadvantages of unstable process
Traditional aluminum foam uses titanium hydride as the foaming agent, which has the advantages of mature technology and large gas production. It begins to decompose at 340°C, and it decomposes obviously above 400°C. Bubbles form rapidly in aluminum melt (660°C), but it does not work at high temperatures. The bottom is extremely unstable, so the titanium hydride foaming agent needs to be subjected to physical grinding, heating oxidation, gel wrapping, metal wrapping and other artificial passivation treatments before use. The processing technology requires high requirements and the process parameters are difficult to master, which further increases production Cost, especially when it is used to prepare secondary foamed aluminum and aluminum alloy billets, the combustion and decomposition are seriously difficult to control, and it is difficult to ensure that a sufficient amount of titanium hydride remains in the billet, resulting in the failure of secondary foaming, so carbonic acid is considered Salt as a blowing agent to prepare aluminum foam and aluminum alloy has important application prospects

Method used

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  • Method for preparing foamed aluminium and aluminum alloy by secondary foaming with novel blowing agent
  • Method for preparing foamed aluminium and aluminum alloy by secondary foaming with novel blowing agent
  • Method for preparing foamed aluminium and aluminum alloy by secondary foaming with novel blowing agent

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Embodiment 1 A kind of preparation of aluminum foam special-shaped parts

[0028] Step 1: Heat the aluminum until it melts, keep it warm at 660-720°C for 30 minutes, add calcium carbonate powder accounting for 0.5-3.0% of the mass fraction of the molten aluminum, and stir at a speed of 400-600r / min for 5-15 minutes;

[0029] The second step: add calcium carbonate powder accounting for 0.5-4.0% of the mass fraction of the aluminum liquid, the rotation speed is 700-1200r / min, the stirring time is 3.0-7.0min, and after stopping, it is cooled to room temperature by water within 40s to form a porosity of less than 65%. Aluminum foam billet with spherical holes;

[0030] Step 3: keep the above-mentioned spherical porous aluminum foam billet in the range of 300-570°C for 10-15 minutes;

[0031] Step 4: Put the above-mentioned spherical porous aluminum foam billet in the mold and make the calcium carbonate in the billet secondary thermally decompose to produce secondary foam i...

Embodiment 2

[0032] Embodiment 2 Preparation of a foamed aluminum-silicon alloy special-shaped part

[0033] Step 1: Heat the aluminum-silicon alloy until it melts, keep it at 660-720°C for 30 minutes, add calcium carbonate powder accounting for 0.5-3.0% of the mass fraction of the aluminum-silicon alloy liquid, and stir at 400-600r / min for 5-15 minutes;

[0034] The second step: add calcium carbonate powder accounting for 00.5-4.0% of the mass fraction of the aluminum-silicon alloy liquid, the speed is 700-1200r / min, the stirring time is 3.0-7.0min, and after stopping, it is cooled to room temperature by water within 40s to form a porosity lower than 65%. Al-Si Alloy billets with spherical cells;

[0035] The third step: keep the above-mentioned spherical porous aluminum-silicon alloy blank in the range of 300-570°C for 10-15 minutes;

[0036] Step 4: Put the above-mentioned spherical porous aluminum-silicon alloy billet in the mold to cause the secondary thermal decomposition of calcium...

Embodiment 3

[0037]Embodiment 3 Preparation of a foamed aluminum-copper alloy special-shaped part

[0038] Step 1: Heat the aluminum-copper alloy until it melts, keep it at 660-720°C for 30 minutes, add calcium carbonate powder accounting for 1.0-4.0% of the mass fraction of the aluminum-copper alloy liquid, and stir at a speed of 400-600r / min for 5-15 minutes;

[0039] The second step: add calcium carbonate powder accounting for 0.5-4.0% of the mass fraction of the aluminum-copper alloy liquid, the rotation speed is 700-1200r / min, the stirring time is 3.0-7.0min, and after stopping, it is cooled to room temperature by water within 40s to form a porosity of 30%. Spherical porous aluminum-copper alloy blank;

[0040] Step 3: Heat the above-mentioned aluminum-copper alloy foam with spherical holes in the range of 300-570°C for 10-15 minutes;

[0041] Step 4: Put the above-mentioned spherical cell foamed aluminum-copper alloy billet in the mold at 760-950°C to cause secondary thermal decompo...

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Abstract

The invention belongs to the preparation field of foaming metal and discloses a method for adopting the secondary foaming behavior of a novel foaming agent to prepare a foamed aluminum and an aluminum alloy; the steps include: 1, heating the aluminum or the aluminum alloy until smelting and preserving the temperature for 30min under the temperature of 660 to 720 DEG C, adding the powder of lime carbonate accounting for 0.5 to 3.0 percent of the weight portions of an aluminum liquor and stirring for 5 to 15 min with a rotating speed of 400 to 600rpm; 2, adding the powder of lime carbonate accounting for 0.5 to 4.0 percent of the weight portions of the aluminum liquor and after stirring for 3 to 7 min with a rotating speed of 700 to 1200rpm, quickly cooling and shaping; the hole rate is lower than that of the spherical hole foamed aluminum of 65 percent or an alloy blank; 3, preserving the temperature of the spherical hole foamed aluminum blank for 10 to 15min under the temperature of 300 to 570 DEG C; 4, arranging the spherical hole foamed aluminum blank into a die and leading the lime carbonate in the blank to be secondarily decomposed by heat under the temperature range of 810 to950 DEG C to generate the secondary foaming behavior and to be fasted cooled to obtain the foam, the aluminum and the product of the product of the irregular-shaped part of the aluminum alloy.

Description

technical field [0001] The invention relates to a method for preparing closed-cell foamed aluminum and foamed aluminum alloy, in particular to a method for preparing foamed aluminum and foamed aluminum alloy by using a novel foaming agent through secondary foaming. Background technique [0002] Aluminum foam and aluminum alloy are a new type of aluminum-based metal material containing a large number of uniform closed pores. Due to its unique physical structure, it has light weight (ρ<1), high specific strength and specific stiffness, and has sound insulation and insulation Various properties such as heat, flame retardancy, damping, impact energy absorption, and electromagnetic shielding have realized the lightweight and multifunctional structural materials, so they have broad application prospects. In the high-tech fields such as aerospace and aerospace, foamed aluminum and alloy special-shaped parts have become the frontier hotspots of international material research as ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/08C22C21/00
Inventor 何德坪褚旭明何思渊张勇明戴戈
Owner SOUTHEAST UNIV
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