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Flame retardant polypropylene resin blend and preparation method thereof

A technology for flame retardant polypropylene and polypropylene resin, applied in the field of flame retardant polypropylene resin blend and its preparation, can solve the problems of high specific gravity, easy migration of flame retardants, low thermal oxygen resistance and light aging resistance, etc. Achieve the effect of realizing large-scale industrial production, excellent light aging resistance, and reducing the migration of flame retardants

Active Publication Date: 2009-06-17
KINGFA SCI & TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But its specific gravity is higher than 1.1g / cm 3 At the same time, the thermal oxygen resistance and light aging resistance of the composition are low, which limits the wide application of this type of material
[0005] Chinese patent application CN1479803A discloses a polypropylene resin composition. The resin achieves light-resistant and aging-resistant flame-retardant polypropylene by adding a low-melting flame retardant, antimony oxide, and light-aging agent. The density of the composition is between 1.0- 1.1g / cm 3 However, the addition of flame retardant reduces the effect of heat and oxygen aging resistance of the composition, and at the same time, the melt dripping is relatively large and the flame retardant is easy to migrate
[0006] U.S. patent application US7067576B2 discloses a polypropylene resin composition, which achieves better light aging resistance and rain-drenched flame retardancy through low-melting flame retardants, antimony oxide, anti-aging agents, titanium dioxide and coupling agents Polypropylene, but it does not have long-term heat and oxygen aging resistance, and the melt dripping is unstable

Method used

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  • Flame retardant polypropylene resin blend and preparation method thereof

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Effect test

Embodiment 1

[0024] According to the flame-retardant polypropylene resin blend prepared in Table 1, various items are tested, and the test items and test results thereof are shown in Table 2: Embodiment 1 is to further optimize the long-term aging resistance of the material. After introducing tetrabromobisphenol After grafting polypropylene with epoxy oligomer and maleic anhydride, it can further improve the resistance to heat, oxygen and light aging of the system.

Embodiment 2

[0026] All materials are prepared according to the flame retardant polypropylene resin blend in Example 2 in Table 1, and its density is only 0.93g / cm 3 , according to UL test its flame retardant grade is V2. After thermal oxygen aging test and xenon arc accelerated aging test, its performance retention rate is very high, and it also slows down the rate of precipitation and migration of flame retardants.

Embodiment 3

[0028] According to the flame retardant polypropylene resin blend prepared in Example 3 in Table 1, its flame retardant performance is only V2, and it has excellent thermal oxygen resistance and light aging resistance. At the same time, it can pass the glow wire temperature test and needle flame test at 850°C according to IEC60695.

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Abstract

The invention discloses a flame retarding polypropylene resin blend and a preparation method thereof. The flame retarding polypropylene resin blend is prepared according to a weight ratio by 56-90 percent of polypropylene resin, 3-18 percent of flame retardant, 3-6 percent of auxiliary flame retardant, 1-6 percent of flame retarding synergist, 2-8 percent of compatibilizer, 0.5-5 percent of melt strength regulator, 0.1-0.5 percent of antioxidant, 0.1-0.5 percent of heat stabilizer, and 0.3-0.5 percent of light stabilizer. The components are mixed in a high-speed mixer for 2-5 minutes, then extruded by a twin-screw extruder and finally granulated. The flame retarding polypropylene resin blend of the invention can maintain a flame retarding property, and at the same time, has the advantages of low proportion, excellent mechanical property, long thermo oxidative aging, excellent lightfast aging capability, and reduced flame retardant migrating, etc.

Description

technical field [0001] The invention relates to a flame-retardant polypropylene resin blend and a preparation method thereof. Background technique [0002] Polypropylene is widely used in automobiles, home appliances, construction and other industries due to its excellent mechanical properties, chemical resistance and light specific gravity. However, polypropylene has a low oxygen index, is easy to burn, and the flame is easy to spread, which limits its wider application. In recent years, with the strengthening of people's safety awareness and the continuous improvement of safety regulations in electrical appliances, construction and other industries, higher requirements have been put forward for the flame retardancy of polypropylene and other plastic products. The United States, Canada, France and other countries have clearly stipulated the flame retardant materials used in electrical appliances and buildings, and promulgated relevant laws and regulations, requiring electr...

Claims

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Application Information

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IPC IPC(8): C08L23/10C08K5/524B29C47/40C08L51/06C08K5/29C08K3/22C08K5/01C08K5/3472B29C48/40
CPCB29C48/40
Inventor 陶四平宁凯军郭熙桃姜向新夏建盟何浏炜
Owner KINGFA SCI & TECH CO LTD
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