Polyvinyl chloride/nitrile rubber/phyllo-silicate nano composite material and preparation method thereof

A nano-composite material and layered silicate technology, which is applied in the field of polymer materials, can solve the problems of affecting the strength of PVC, affecting the service life, and large unit weight.

Inactive Publication Date: 2009-06-17
生寿斋
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the harsh environment mentioned above, some of the humidity can reach more than 90%. Among these materials, steel has the disadvantages of being not corrosion-resistant, easy to rust, heavy, difficult to carry, and high in use cost. And the shortcomings of low strength lead to short service life and flammability (not conducive to coal mine safety). At the same time, the wall thickness of the same pipe diameter is 1/4 thicker than PVC, and the cost is high, and the unit weight is large; more importantly, raw materials are expensive and production The cost is high. It takes 7-8 tons of oil to produce 1 ton of PE material, which is not conducive to the energy saving and consumption reduction of strategic resources. Due to the poor toughness of PVC materials, it is easy to become brittle and break at low temperature (-20C°). It also affects its service life, and the use environment is restricted by temperature
[0003] At present, modified PE materials and PVC materials are the key research and developmen

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Embodiment 1: this polyvinyl chloride / acrylonitrile-butadiene rubber / phyllosilicate nanocomposite material is grouped into by raw material weight:

[0022] Name Weight (kg)

[0023] PVC 100

[0024] Nano layered silicate 4

[0025] Nitrile rubber powder 6

[0026] Light calcium carbonate 9

[0027] Conductive carbon black 1

[0028] Plasticizer 10

[0029] lubricant 1

[0030] heat stabilizer 2

[0031] Weigh and mix according to the above formula, after mixing, heat it through a high-speed kneader, and the kneading temperature is 110°C, then put the kneaded material into a cold mixer for cold mixing, and add 6 parts of nitrile rubber powder during cold mixing, and cool Mixing to below 40°C and extruding with an extruder can also be made into pipes, pipe fittings and roller bodies by multi-layer co-extrusion.

Embodiment 2

[0032] Embodiment 2: this polyvinyl chloride / acrylonitrile-butadiene rubber / phyllosilicate nanocomposite material is grouped into by raw material weight:

[0033] Name Weight (kg)

[0034] PVC 100

[0035] Nano layered silicate 12

[0036] Nitrile rubber powder 13

[0037] Light calcium carbonate 5

[0038] Conductive carbon black 6

[0039] Plasticizer 5

[0040] lubricant 5

[0041] heat stabilizer 7

[0042] Weigh and mix according to the above formula. After mixing, knead with a high-speed kneader. The kneading temperature is 120°C. Then put the kneaded material into a cold mixer for cold mixing, and add 13 parts of nitrile rubber powder during cold mixing. After mixing to lower than 40°C, discharge the material, and then extrude with an extruder or multi-layer co-extrusion to make pipes, pipe fittings and roller bodies.

Embodiment 3

[0043] Embodiment 3: this polyvinyl chloride / acrylonitrile-butadiene rubber / phyllosilicate nanocomposite material is grouped into by raw material weight:

[0044] Name Weight (kg)

[0045] PVC 100

[0046] Nano layered silicate 20

[0047] Nitrile rubber powder 20

[0048] Light Calcium Carbonate 1

[0049] Conductive carbon black 12

[0050] Plasticizer 1

[0051] lubricant 8

[0052] heat stabilizer 12

[0053]Weigh and mix according to the above formula, knead with a high-speed kneader after mixing, the kneading temperature is 125°C, then put the kneaded material into a cold mixer for cold mixing, and add 20 parts of nitrile rubber powder during cold mixing, and cool After mixing to lower than 40°C, discharge the material, and then extrude with an extruder or multi-layer co-extrusion to make pipes, pipe fittings and roller bodies.

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PUM

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Abstract

The invention relates to a polyvinyl chloride/nitrile rubber/layered silicate nano-composite and a preparation method thereof, which mainly uses the polyvinyl chloride as a substrate, by adding in certain proportions of nitrile rubber powder, nano-layered silicate, conductive carbon black, light calcium carbonate, lubricant, plasticizer and heating composite stabilizer materials, a new polyvinyl chloride/nitrile rubber/layered silicate nano-composite is prepared. The raw materials mentioned above are weighed and mixed except the nitrile rubber powder, and kneaded by a high-speed kneading machine after being mixed, with a kneading temperature of 110-125 DEG C, then material being kneaded is put into a cold mixer for cold mixing, and the weighed nitrile rubber powder is added in when in cold mixing, material is discharged when being cold mixed to lower than 40 DEG C, an extruder is used for plastic extrusion or multi-layer co-extrusion mold, and finally a pipe, a fitting and a roller body are manufactured. Compared with present flame retardant and antistatic PE and PVC materials, the polyvinyl chloride/nitrile rubber/layered silicate nano-composite not only has the toughness of the PE, but also is provided with the intensity of the PVC, thus being capable of being widely applied to such combustible and explosive areas as coal mine, oil field, natural gas and mine.

Description

Technical field: [0001] The invention belongs to the field of polymer materials, and in particular relates to a polyvinyl chloride / nitrile rubber / layered silicate nanocomposite material and a preparation method thereof. technical background: [0002] At present, the pipes, pipe fittings and roller bodies used for drainage, ventilation, compressed air and gas drainage in coal mines, oil fields, natural gas and underground mines are mainly made of steel and modified PE and PVC materials with flame retardant and antistatic properties. host. Due to the harsh environment mentioned above, some of the humidity can reach more than 90%. Among these materials, steel has the disadvantages of being not corrosion-resistant, easy to rust, heavy, difficult to carry, and high in use cost. And the shortcomings of low strength lead to short service life and flammability (not conducive to coal mine safety). At the same time, the wall thickness of the same pipe diameter is 1 / 4 thicker than PVC...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08K13/02C08K3/34B29B7/00C08L9/02C08K3/26C08K3/04
Inventor 生寿斋
Owner 生寿斋
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