Processes for dewatering digested sewage sludge
A technology for digesting sludge and sewage, applied in chemical instruments and methods, sludge treatment, separation methods, etc., can solve the problems of being unsuitable for centrifugal dehydrators, moving, etc., and achieve excellent clarification, reduced usage, and flocculation excellent filterability
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[0107] Hereinafter, an Example and a comparative example are given, and this invention is demonstrated more concretely. It should be noted that in the following content, "%" refers to "mass%" unless otherwise specified.
[0108] The cation equivalent value (Cv) and 0.5% salt concentration of the high molecular coagulant (polymer) were measured as follows.
[0109] [Measurement of Cv]
[0110] (1) Titration method
[0111] Measure 90 ml of deionized water in a conical beaker, add 10 ml of a 500 ppm sample solution, adjust the pH to 4.0 with aqueous hydrochloric acid, and stir for about 1 minute. Next, add 2 to 3 drops of toluidine blue indicator, and titrate with N / 400 polyvinyl potassium sulfate reagent (hereinafter referred to as N / 400PVSK). The titration speed is 2ml / min, and the time point when the water changes from blue to purple and remains for more than 10 seconds is taken as the end point.
[0112] (2) Preparation of sample 500ppm aqueous solution
[0113] Accurat...
manufacture example A
[0121] Using 79wt% aqueous solution of dimethylaminoethyl acrylate chloride addition product (hereinafter referred to as "DAC"), 40wt% aqueous solution of acrylamide (hereinafter referred to as "AM") and ion-exchanged water, the monomer concentrations were respectively 80mol%, 20mol%, and mixed so that the monomer concentration is 50wt%, and the total amount reaches 450ml.
[0122] It was degassed in a nitrogen flow for more than 30 minutes and adjusted to 15°C. A 10 wt % aqueous solution of 2,2'-azobisisobutylamidine dihydrochloride (hereinafter referred to as "V-50") was added at 1000 ppm in terms of solid content relative to the total monomers, and the total monomers , A 5% aqueous solution of 15 ppm of sodium metabisulfite (hereinafter referred to as "SHS") was added in terms of solid content.
[0123] Put it in and adjust the irradiation intensity to 0.4mW / cm 2 in the ultraviolet irradiation device. The reaction started within 1 minute and reached a maximum temperature...
manufacture example B
[0126] In Production Example A, instead of DAC and AM, dimethylaminoethyl methacrylate chloride addition product was changed to 100 mole%, monomer concentration was 74wt%, V-50 was 400ppm and SHS was 5ppm, according to Production Example A method for aggregation.
[0127] The obtained polymer was cut, dried and pulverized in the same manner as in Production Example A to obtain a powdery polymer coagulant.
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