Method for manufacturing high wet modulus fiber

A technology of high wet modulus fiber and manufacturing method, applied in wet spinning, fiber processing, textile and papermaking, etc., can solve the problems of harsh raw material requirements, high hemicellulose, increase the cost of raw materials for fiber production, etc., and achieve high strength. , bright dyeing effect

Inactive Publication Date: 2009-12-02
HANGZHOU AUTOON ENVIRONMENTAL TECH CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in cellulose pulp with low A-cellulose content < 95%, there are many impurities such as hemicellulose, if not effectively removed, it will affect the production and spinning of viscose, and it is difficult to produce high wet modulus fibers
For example, the Chinese patent application "High Wet Modulus Viscose Fiber and Its Preparation Method" of Publication No. CN101024907 discloses a method for preparing high wet modulus viscose fiber, but its production ...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Using a cellulose content (the content refers to the weight percentage, the same below) of 92% wood cellulose pulp is immersed and alkalized by 230g / l NaOH solution once, the concentration of the porridge is 4.5%, and the immersion temperature is At 50°C, add 0.1% of the viscose auxiliary agent relative to the methyl cellulose content-fatty alcohol ether (code EBZ) during dipping, and the first dipping time is 1.5 hours. After squeezing and crushing, it is dipped and alkalized by 160g / l NaOH solution twice. The concentration of the second dipping porridge is 4.0%, the second dipping temperature is 42℃, and the second dipping time is 1 hour. Cellulose dissolves, and its content is less than 20g / l. After squeezing and pulverizing again, an alkali cellulose with a squeezing ratio of 2.8 and a pulverization degree of 120 g / l was obtained. Alkaline cellulose is aged at 30°C for 4 hours to produce alkali cellulose with a cupramide viscosity of 70 mps. Combine 7500kg of alkali cel...

Embodiment 2

[0039] Wood cellulose pulp with a cellulose content of 89% and cotton pulp with a cellulose content of 94%, each accounting for 50% of the total weight of the raw materials, are mixed, and then immersed and alkalized by a 240g / L NaOH solution. The concentration of porridge is 4.8%, the immersion temperature is 52°C, the immersion time is 1 hour, and the viscose auxiliary agent-fatty alcohol ether (code EBZ), which is 0.1% relative to the methyl cellulose content, is added. After squeezing, it is immersed and alkalized by 170g / l NaOH solution twice. The concentration of the porridge is 4.5%, the temperature of the second immersion is 48℃, and the time of the second immersion is 1.5 hours, so that the half fiber in the lye can be impregnated. The dissolution of vegetarian, its content is less than 25g / l. After squeezing and pulverizing again, alkali cellulose with a squeezing ratio of 3.0 is obtained. The alkali cellulose is aged for 5 hours at 25°C to produce alkali cellulose with ...

Embodiment 3

[0041] The cotton pulp with a cellulose content of 94.5% was immersed and alkalized by a 235g / l NaOH solution. The concentration of the porridge was 3.8%, the immersion temperature was 52℃, and the amount of para-methyl cellulose was 0.2. % Of viscose additives-fatty alcohol ether (code EBZ). The immersion time is 2.5 hours to dissolve the hemicellulose in the immersion alkali solution, and its content is less than 30g / l. After squeezing and pulverizing, alkali cellulose with a squeezing ratio of 3.2 is obtained. Alkali cellulose is aged for 2.5 hours at 35°C to produce alkali cellulose with a copper ammonia viscosity of 80 mps. Combine 8000kg of alkali cellulose with 840 liters of CS 2 The yellowing reaction takes 55 minutes to generate cellulose xanthate. After the yellowing is completed, add 48g / l of NaOH dilute lye to dissolve at 8°C. During the dissolution of cellulose xanthate, add 2.0% relative to the weight of methyl cellulose. The viscose denaturant-the alkylene oxide add...

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PUM

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Abstract

The invention discloses a method for manufacturing high wet modulus fiber, which comprises the process steps of alkalization reaction, ageing reaction, etiolation reaction, viscose dissolution, viscose filtration, viscose defoaming, viscose maturation, spinning, drafting and post-treatment in turn, adopts cellulose pulp of which the alpha cellulose content is less than 95 percent as a raw material, uses a common device for producing ordinary viscose short fiber, and adopts a special process formulation and a spinning drafting mode with simple and practical process control to manufacture the high wet modulus fiber capable of meeting the international standard. The method has less investment, adopts easily obtained low-cost raw materials, and has high productivity and simple process operation, and the manufactured high wet modulus fiber has excellent quality and stable performance.

Description

Technical field: [0001] The invention relates to a method for producing regenerated cellulose, in particular to a high wet modulus fiber. Background technique: [0002] The gloss, softness, moisture absorption, dyeability, and color fastness of the high wet modulus fiber are better than pure cotton products; the fabric made with it shows a silky luster with a pleasant soft touch feeling and drape Sensation and excellent durability. [0003] At present, the high wet modulus fibers made in China and put into the market cannot meet the international standards for high wet modulus fibers. Therefore, the fabric made with it cannot achieve the performance of high wet modulus products. [0004] Generally, the production of high wet modulus fibers requires high methylcellulose content pulp. In order to have a good impregnation effect, the hemicellulose content in the impregnation solution is low, and the viscose solution obtained has good filtration and spinnability properties. In the ce...

Claims

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Application Information

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IPC IPC(8): D01D5/06D01D1/10D01D10/00D01D11/00C08B9/00
Inventor 冉国庆郑睿敏李文峰
Owner HANGZHOU AUTOON ENVIRONMENTAL TECH CORP
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