Nanocrystalline high-chromium cast-iron composite nucleating agent for engineering machinery as well as preparation method and application method thereof

A composite inoculant and high-chromium cast iron technology, which is applied in the field of cast iron alloys, can solve the problems that the comprehensive mechanical properties of high-chromium cast iron alloys cannot be effectively improved, and the grain and microstructure refinement effect of the cast iron alloy matrix is ​​not ideal. The effects of matrix grain refinement, increased interface energy, and uniform distribution

Active Publication Date: 2010-01-06
天津万石科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the preparation methods of cast iron inoculants reported in the above-mentioned literatures are all produced by traditional processes such as crushing and mixing, and the application of these inoculants in cast iron alloy casting is smelted and crushed into small pieces by ordinary smelting processes. When used, the grain size of its refiner is several hundred microns, which is far from nano

Method used

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  • Nanocrystalline high-chromium cast-iron composite nucleating agent for engineering machinery as well as preparation method and application method thereof
  • Nanocrystalline high-chromium cast-iron composite nucleating agent for engineering machinery as well as preparation method and application method thereof
  • Nanocrystalline high-chromium cast-iron composite nucleating agent for engineering machinery as well as preparation method and application method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] The weight ratio by element composition is Fe:Ti:B=0.37~0.47:3.35~0.45:0.14~0.22, take the required pure Fe, pure Ti block and B powder, and weigh the pure Fe, pure Ti block and B powder in a vacuum electric arc furnace to smelt into a button-shaped alloy ingot to obtain a Fe-Ti-B master alloy. The refining process is well known.

[0047] figure 1 The metallographic diagram of the Fe-Ti-B master alloy obtained for the present embodiment, figure 1 It can be seen that the grain size of the Fe-Ti-B master alloy is 50-100 μm.

Embodiment 2

[0050] Weigh 1000 grams of Fe-Ce-Si-Ca master alloy and 100 grams of Fe-Ti-B master alloy, break them into small pieces, put them in the water-cooled copper crucible of the vacuum quenching furnace, adjust the electrode position, make it with The distance between the alloy particles in the crucible is 0.75mm, close the furnace door, the inlet and outlet and the air release valve, and vacuumize until the vacuum degree is higher than 3.8×10 -3After Pa, wash the furnace with argon gas, then fill it with argon gas until the pressure is 0.04Pa, adjust the arc current to gradually increase to 500A after arcing, melt the above alloy, and when the above alloy is completely melted into a liquid state, tilt the crucible to make the alloy The liquid is led to the high-speed rotating water-cooled molybdenum wheel through the flow channel. The surface temperature of the molybdenum wheel is 10°C. After the molten liquid alloy contacts the molybdenum wheel, it solidifies rapidly. The edge spe...

Embodiment 3

[0052] Take by weighing 1200 grams of Fe-Ce-Si-Ca master alloy and 80 grams of Fe-Ti-B master alloy, they are broken into fritters, put into the water-cooled copper crucible of vacuum quenching furnace, and fritters are placed on the bottom, relatively Put the big piece on top, adjust the position of the electrode so that the distance between it and the alloy particles in the crucible is 1.0 mm, close the furnace door, the inlet and outlet, and the air release valve, and evacuate until the vacuum degree is higher than 3.8×10 -3 After Pa, wash the furnace with argon, then fill it with argon until the pressure is 0.045Pa, adjust the arc current to gradually increase to 550A after arcing, melt the above alloy, and when the above alloy is completely melted into a liquid state, tilt the crucible to make the alloy The liquid is led to the high-speed rotating water-cooled molybdenum wheel through the flow channel. The surface temperature of the molybdenum wheel is 12.5°C. After the mo...

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Abstract

The invention relates to a nanocrystalline high-chromium cast-iron composite nucleating agent for engineering machinery as well as a preparation method and an application method thereof and relates to chromium-contained cast-iron alloys. The nanocrystalline high-chromium cast-iron composite nucleating agent is a sheet nanocrystalline high-chromium cast-iron composite nucleating agent for the engineering machinery containing nanocrystalline rear-earth silicoferrite and Fe-Ti-B, comprises an Fe-Ce-Si-Ca interalloy and a Fe-Ti-B interalloy in a mass ratio of 100: (6.67-10.0), has a nanocrystalline grain size smaller than 100 nm and is prepared by adopting a centrifugal quenching and flinging method. Grains and texture of the high-chromium cast-iron alloys for the engineering machinery are produced and thinned by the nanocrystalline high-chromium cast-iron composite nucleating agent by a metal melting die-casting method so that substrate grains and a cementite phase of the high-chromium cast-iron alloys are remarkably thinned, cementite layered sheets and particles are further thinned, and the distribution is evener. In-situ generated TiB2 particles in high-chromium cast-iron liquid also take the action of enhancing a substrate, thereby obviously improving the comprehensive mechanical performance of the high-chromium cast-iron alloys for the engineering machinery.

Description

technical field [0001] The technical scheme of the invention relates to a chromium-containing cast iron alloy, in particular to a nanocrystalline high-chromium cast iron composite inoculant for construction machinery and a preparation and application method thereof. Background technique [0002] As a high wear-resistant material, high chromium cast iron is used in crushing, grinding and material conveying machinery and metallurgical equipment, especially in abrasive wear and impact wear parts, such as crusher drum, silo lining board, blast furnace bell, hopper, transportation It is widely used in coal channel liner, coal mill roll sleeve, roll and slurry pump flow parts. [0003] With the continuous development of new construction machinery, more and more stringent requirements are put forward for the mechanical properties of high chromium cast iron wear parts. Experimental studies by many scholars and technicians have found that: on the one hand, high-chromium cast iron ca...

Claims

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Application Information

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IPC IPC(8): C22C35/00C22C33/08B22D1/00B22D11/06
Inventor 崔春翔石卫东
Owner 天津万石科技发展有限公司
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