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Comprehensive process technology of solid waste in alumina plant

A solid waste and comprehensive treatment technology, which is applied in the field of solid waste treatment process of Bayer process alumina production, can solve the problems of alkali adverse effects, land occupation, high cost, etc., so as to alleviate the pressure of environmental protection, realize waste recycling and Environmental friendliness and remarkable benefits

Active Publication Date: 2010-12-22
CHIPING XINFA HUAYU ALUMINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The stockpiling of solid waste produced in alumina plants not only occupies land and costs a lot, but also if the anti-seepage treatment is not good, the alkali in solid waste will cause serious adverse effects on the environment, especially groundwater, which is a major safety hazard in alumina production. Therefore, the accumulation of solid waste has always been a difficult problem for alumina manufacturers, and how to recycle it is imminent
At present, the solid waste treatment technologies used at home and abroad mainly include dry storage, gravity sand extraction for iron extraction, magnetization iron extraction, and processing of building materials. The treated solid waste cannot be directly used as raw materials for cement plants due to its high alkali content.

Method used

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  • Comprehensive process technology of solid waste in alumina plant
  • Comprehensive process technology of solid waste in alumina plant

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Comprehensive treatment process of solid waste in alumina plant:

[0020] (1) Pump the last underflow red mud from the sedimentation process in the alumina production process to the sand extraction and iron extraction process to extract sand and iron from solid waste; gravity separation is used for sand extraction, and gravity or magnetization separation is used for iron extraction Filter the treated solid waste to remove the moisture in the solid waste, and mix the obtained filter cake with solid or liquid caustic soda, the overflow of the crystallization settling tank obtained in the subsequent steps, and calcium carbide mud or milk of lime in the batching tank The caustic ratio of the final batching slurry is controlled to 20 to 30 to ensure that the caustic ratio of the eluate is 8 to 15, and the mass fraction ratio (C / S) of calcium oxide and silicon dioxide in the dissolved solid waste is 2.0 to 3.5;

[0021] (2) Pump the batching slurry into high-pressure dissolut...

Embodiment 2

[0025] Comprehensive treatment process of solid waste in alumina plant:

[0026] The operation is the same as in Example 1, except that step (3) the temperature of the stripper is 300-305° C., and the holding time is 40 minutes.

Embodiment 3

[0028] Comprehensive treatment process of solid waste in alumina plant:

[0029] The operation is the same as in Example 1, except that step (3) the temperature of the stripper is kept at 290 to 300° C., and the time of the soak is 50 minutes.

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Abstract

The invention discloses a comprehensive process technology of solid waste in an alumina plant, belonging to the technical field of solid waste processing. The technology blends the solid waste after sand-extraction and iron-extraction or solid waste to directly with carbide slurry or milk of lime, liquid or solid caustic soda, follow-up alkali liquor and the like and mainly utilizes the digestionprocess with high temperature and high caustic ratio to change the slag phase of the red mud, so as to realize efficient recycling of alumina and sodium oxide and to realize systematic circulation bymating with sedimentation and separation, evaporation and concentration, crystallization separation of sodium aluminate and the like. The solid waste is red mud, tailings or low-grade aluminium ore in the aluminium plant. In the technology, the recovery rate of alumina in the solid waste can reach 60%-90% and the recovery rate of sodium oxide can reach over 90% with notable benefits; the alkali in the solid waste can be reduced to below 1%, reaching the basicity range of alkalis soil; after filter pressing, the invention can be used as soil directly without environmental protection risks, thus realizing waste resource utilization and environmental friendliness in deed.

Description

Technical field: [0001] The invention relates to a treatment technology for solid waste, in particular to a treatment process for solid waste produced by Bayer process alumina. Background technique: [0002] The stockpiling of solid waste produced in alumina plants not only occupies land and costs a lot, but also if the anti-seepage treatment is not good, the alkali in solid waste will cause serious adverse effects on the environment, especially groundwater, which is a major safety hazard in alumina production. Therefore, the accumulation of solid waste has always been a difficult problem for alumina manufacturers, and how to recycle it is imminent. At present, the solid waste treatment technologies used at home and abroad mainly include dry storage, gravity sand extraction for iron extraction, magnetization iron extraction, and processing of building materials. The treated solid waste cannot be directly used as raw materials for cement plants due to its high alkali content....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B7/00
CPCY02P10/20
Inventor 贾启张刚潘士刚白东林邹玉国
Owner CHIPING XINFA HUAYU ALUMINA
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