Chromium(vi)-free black passivation of surfaces containing zinc
A black, passivation layer technology, applied in the field of black conversion layer treatment solution, can solve the problem of black zinc alloy surface that cannot be successfully
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[0076] An aqueous reaction solution having the composition shown in Table 1 was prepared (individual components were added in the same form as in Comparative Example 2). The pH of each solution was adjusted to the value shown in Table 1 with nitric acid and sodium hydroxide.
[0077] Steel structural elements are coated electrochemically with the zinc-containing alloys indicated under the respective headings in Table 1 and, after electrochemical coating, rinsed thoroughly with demineralized water and subsequently in 0.3% nitric acid at 20-30°C 10 seconds of activation followed by a full rinse. Next, the elements were immersed in the reaction solution under the conditions (temperature, treatment time) shown in Table 1. Subsequently, the surface coating ("Versiegelung") was carried out with Corrosil 501, which consists of an aqueous polymer dispersion with a silicate component. The results of a visual (color) evaluation and a salt spray test according to DIN 50021 SS before an...
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