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Waste plastics pretreatment process based on coking by coke oven

A waste plastics pretreatment technology, applied in coking ovens, petroleum industry, special forms of dry distillation, etc., can solve the problems of coke quality degradation, impact on coke quality, uneven dispersion of waste plastic particles, etc., to meet energy saving and consumption reduction, guarantee The effect of coke quality

Inactive Publication Date: 2010-09-15
武钢集团有限公司 +2
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AI Technical Summary

Problems solved by technology

[0011] 1. When processing waste plastics with high chlorine content, if they are directly mixed with coking coal, most of the decomposed chlorine will enter the coke oven gas during the coking process, which will cause serious corrosion to gas pipelines and gas purification equipment, affecting equipment When the temperature is higher than 500°C, the chlorine in waste plastics will generate dioxins, which will have a serious impact on the environment
[0012] 2. Due to the plasticity of waste plastics, commonly used pulverizers cannot crush waste plastics to a finer particle size (≤1mm). When mixed into coking coal, it will cause uneven dispersion of waste plastic particles in coking coal, resulting in coke quality loss problem
[0013] 3. Due to the wide range of sources of waste plastics, it is inevitable to be mixed with various inclusions, especially trademark paper, fine sand, gravel or metal particles attached to the surface of the plastic or dissolved in it. These substances are difficult to pass through conventional waste plastics. The method is difficult to remove, and it will also affect the quality of coke after being mixed with coking coal

Method used

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  • Waste plastics pretreatment process based on coking by coke oven
  • Waste plastics pretreatment process based on coking by coke oven
  • Waste plastics pretreatment process based on coking by coke oven

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Embodiment 1

[0032] Source of waste plastics: Waste plastics used for coal blending and coking are collected from various mixed waste plastics recovered from society in Wudong Waste Plastics Processing Plant, Wuhan City, with a chlorine content of 51.10% (mass percentage).

[0033] Pretreatment process:

[0034] (1) Wash the above-mentioned waste plastics with water through a washing machine to remove the surface soil and then send them to the coarse crusher, and coarsely crush the waste plastics to 8-12mm;

[0035] (2) The coarsely crushed waste plastics are sent to the waste plastics pyrolysis furnace, and the waste plastics are heated to 225-275°C at a heating rate of 5°C / min under the condition of isolating the air, and after 30-90min constant temperature pyrolysis, the heat is obtained Decomposed gas and fluid pyrolysis residues, the precipitated pyrolysis gas accounts for 56% of the mass of waste plastics, which contains HCl gas generated by more than 96% (mass percentage) of chlorin...

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Abstract

The invention discloses a waste plastics pretreatment process based on coking by a coke oven, which solves the problems of low equipment life, large environmental influence and influenced coke quality after coal blending in the process of treating waste plastics by using the coking process in the prior art. The technical scheme adopted by the invention is as follows: (1) performing coarse crushing on the waste plastics by a crusher until the grain size is 8-12mm; (2) feeding the waste plastics with the grain size of 8-12mm after coarse crushing in a pyrolysis oven, heating to 225-275 DEG C under the condition of air isolation, pyrolyzing for 30-90min at a constant temperature and dissolving out pyrolysis gas; (3) cooling the fluid residue of the waste plastics after pyrolysis to form solid-state solids, and feeding the solid-state solids in the crusher again for crushing until the grain size is no more than 1mm; and (4) blending the solid-state solids in coking coal according to the proportioning of 1% by weight. The invention has the advantages of simple process, no environment pollution and no influence on coke quality.

Description

technical field [0001] The invention relates to an environmental protection technology, in particular to a waste plastic pretreatment process based on coking in a coke oven. Background technique [0002] Recycled waste plastics have the following characteristics: [0003] 1. This kind of waste plastics has a large amount of recycling, and most of them contain chlorine, and some chlorine content is even as high as 51.10%. [0004] 2. Wide range of sources and many inclusions: this type of plastic comes from scraps, defective products, etc. produced during the production process of the factory, as well as various post-consumer products recycled in the society, etc. Such waste products have often been discarded Pollution, some have been colored and printed with trademarks, and some also contain impurities such as sand, broken metal, wood chips or shredded paper. Small solid impurities are difficult to remove through ordinary sorting or pre-treatment. [0005] 3. Different deg...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B53/07C10B57/04
CPCY02P20/143
Inventor 吴高明梁玉河杜健敏李清田史世庄王光辉童俊张大华吴声浩朱静
Owner 武钢集团有限公司
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