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Device for enriching and recovering carbon dioxide gas

A carbon dioxide enrichment technology, applied in the direction of inorganic chemistry, carbon compounds, chemical instruments and methods, etc., can solve the problems of corrosion, solvent degradation and solvent condensation, limit the application of enrichment and recovery, and reduce the impact of NHD solvents on Carbon dioxide absorption efficiency and other issues, to achieve the effect of solvent stability and applicability enhancement, investment and energy consumption reduction, and energy consumption reduction

Inactive Publication Date: 2010-09-22
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Utility model patent ZL200820069819.3 provides a process device for recovering carbon dioxide in flue gas using NHD as a solvent. This device will introduce more water in the desulfurization and regeneration process, which will reduce the absorption efficiency of NHD solvent for carbon dioxide
[0006] Invention patent ZL200310106564.5 provides a high-pressure method for removing sulfide and carbon dioxide. In this process, a desulfurization tower and a stripping tower are also used, and a large amount of water will also be introduced; Corrosion of equipment, degradation of solvents, and condensation of solvents limit its application for carbon dioxide enrichment and recovery to a certain extent.

Method used

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Examples

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Embodiment

[0017] Recovery of carbon dioxide in the hydrogen production, the carbon dioxide gas source comes from the split pipeline of the pressure swing adsorption hydrogen production gas source, the pressure is 2.5MPa, the temperature is 40°C, and the gas volume is 21000Nm 3 / h, the gas composition is as follows:

[0018] components

H 2

CO

CO 2

CH 4

h 2 o

total

%(v)

71.23

2.5

21.73

4.32

0.22

100.00

[0019] The raw material gas first passes through the water separator 15 to divide the water, then passes through the heat exchanger 1 to cool down, enters the water separator 2 to remove most of the water, and then enters the absorption tower 3. The decarburized gas enters the liquid separation tank 14 after going out from the top of the tower. The adsorption tank 4 is dehydrated, and then returns to the PSA hydrogen production inlet after passing through the heat exchanger 1; the saturated NHD first ent...

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PUM

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Abstract

The invention relates to a device for enriching and recovering carbon dioxide gas, which belongs to the technical field of gas separation. The invention is characterized in that the device comprises a gas heat exchanger, a manifold, an absorption tower, an adsorption tank, a flash tower, a vacuum pump, an intermediate storage tank, a barren liquor pump, an ammonia cooler and a compressor, and the solvent adopted by the device is polyethylene glycol dimethyl ether (NHD) in which a corrosion inhibitor, an anti-degradation agent and an anticoagulant are added. The NHD adopted by the invention has high utilization rate, simple process and low energy consumption, and is suitable for the enrichment and recovery of carbon dioxide in gas sources with higher pressure for producing hydrogen, natural gas, conversion gas, synthesized ammonia gas, methanol synthesis gas and the like. The invention has the advantages that the conventional NHD process is improved, the preparation recovery concentration of the carbon dioxide can reach more than 98%, and the application prospect is broad.

Description

technical field [0001] The invention belongs to the technical field of gas separation, and relates to a device for enriching and recovering carbon dioxide gas. Background technique [0002] The greenhouse effect caused by the massive emission of carbon dioxide has made the earth's climate environment increasingly worse. The convening of the "Copenhagen Climate Conference" indicates that the reduction of carbon dioxide emissions has reached an imminent level. However, at present, the main energy consumption in the world is still fossil energy, and no clean energy that can be completely replaced has been found. Therefore, slowing down the emission of carbon dioxide is the main task at this stage, and the separation, recovery, storage and utilization of carbon dioxide are a key to control carbon emissions. proven method. [0003] The separation and recovery methods of carbon dioxide mainly include: absorption method, adsorption method, membrane separation method and so on. A...

Claims

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Application Information

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IPC IPC(8): B01D53/14B01D53/18C01B31/20C01B32/50
CPCY02P20/151
Inventor 张永春陈绍云李桂民
Owner DALIAN UNIV OF TECH
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