Silicious organic phosphonium salt antibacterial finishing agent and preparation method and application thereof
The technology of an antibacterial finishing agent and a quaternary phosphonium salt is applied in the field of antibacterial finishing agent and its preparation, which can solve the problems such as no silicon-containing organic quaternary phosphonium antibacterial finishing agent, and achieves good application prospect, good washing resistance and convenient source of raw materials. Effect
Inactive Publication Date: 2010-10-13
DONGHUA UNIV
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Problems solved by technology
The textile industry is a major pillar industry in my country, and the development of new, efficient and environmentally friendly antibacterial agents that can be applied to textiles is a major research focus in the industry. So far, there has been no relevant research on silicon-containing organic quaternary phosphonium antibacterial finishing agents. Literature report
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Abstract
The invention relates to a silicious organic phosphonium salt antibacterial finishing agent. The chemical structure of the antibacterial finishing agent is shown as the accompanying drawing, wherein R1, R2 and R3 are long-chain alkyl groups, methyl groups, ethyl groups, propyl groups, phenyl groups, butyl groups, benzyl groups or aromatic ring substituent groups of C8 to C18, R4 is a methyl group, a ethyl group or a propyl group, and n is 1 to 10. A preparation method of the antibacterial finishing agent includes the following steps that: compound containing tertiary phosphine and halogenated alkyl organosilicon coupling agent are dehydrated in advance, and are then mixed in alcohol solvent according to the molar ratio of 1:0.9 to 1.2, reflux reaction is carried out under the protection of nitrogen, the reaction solvent and the residual reaction material are removed under vacuum, the pressure and the temperature are reduced, and organic solvent is added to dissolve a product. The antibacterial finishing agent can ensure that a fabric has a broad-spectrum antibacterial property, washing fastness and good environmental safety; moreover, the operation of the preparation method is simple, the materials can be conveniently obtained, the preparation method is environment-friendly and suitable for industrial production, and therefore the invention has good application prospect.
Description
technical field The invention belongs to the field of antibacterial finishing agent for textiles and its preparation, in particular to a silicon-containing organic quaternary phosphonium salt antibacterial finishing agent and its preparation method and application. Background technique In recent years, with the improvement of living standards, people's awareness of health and environmental protection has been continuously strengthened. While emphasizing the beauty and comfort of textiles and clothing, they have put forward higher requirements for their health care functions. The production of textiles with antibacterial functions is to make people free. One of the effective ways to suffer or be less affected by bacteria, so textiles with antibacterial function are more and more favored by people. The antibacterial and hygienic finishing of textiles is the processing technology of treating fabrics with antibacterial agents or antibacterial agents to obtain antibacterial, ant...
Claims
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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/513C07F9/54
Inventor 闵洁潘建君
Owner DONGHUA UNIV
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