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Calcining-free desulfurization gypsum/phosphogypsum self-insulation gypsum brick and production method thereof

A technology for desulfurization gypsum and a production method, which is applied to other household appliances, sustainable waste treatment, solid waste management, etc., can solve the problems of large equipment investment, unstable product quality, and low strength, and save natural gypsum resources and land. resources, reducing secondary pollution and energy consumption, and improving strength and water resistance

Inactive Publication Date: 2010-11-24
SHANGHAI JINMA BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The problems brought about are: first, the initial investment in equipment is large and the process is complicated; second, secondary energy consumption and secondary pollution; third, the product is "low in strength and not resistant to water"; fourth, the product quality is unstable and affects the use ; Fifth, the cost is high and not environmentally friendly
[0004] It is found in the retrieval documents that the application number is: 200610150190.0 "A Self-insulating Wall Brick, Block or Porous Brick and Its Preparation Method". ②The solid waste has not been utilized; ③The strength is low; ④The cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0025] The preparation method of self-insulating gypsum brick of the present invention is:

[0026] ① Pre-mix and grind the three major materials of active mineral material, activator and coagulant in dry powder form to reach more than 250 mesh, and pack them into bags for use as the core masterbatch;

[0027] ② During on-site production, at the same time, semi-wet (attached water ≤ 10%) dihydrate desulfurized gypsum and phosphogypsum are vibrated and sieved (¢5mm), and mixed with core masterbatch, aggregate, and lightweight aggregate with appropriate amount of water (because Adhesive water content is different, find out the law on the spot, take out the data);

[0028] ③Through forming machine, extruding molding; let stand for 8-24 hours naturally.

[0029] ④Atmospheric pressure, damp heat curing 50-85℃, 8-24h

[0030] ⑤Conservation under natural conditions. ≥10°C or higher.

Embodiment 1

[0032] The raw material ratio of this example is:

[0033] Non-calcined dihydrate desulfurized gypsum: 75%

[0034] Fly Ash: 3%

[0035] Slag fine powder: 15%

[0036] Cement: 5%

[0037] Calcium Oxide: 2%

[0038] Calcium formate: 0.5%

[0039] Crushed melon slices: 150%

[0040] Closed Cell Perlite: 6%

[0041] Slag: 30%

[0042] The production method is:

[0043] 1. The undisturbed dihydrate desulfurized gypsum, with attached water content ≤ 10%, is vibrated and sieved (¢5mm) on site or rolled and mixed, and measured into the mixing mixer;

[0044] 2. Pre-grind and mix into dry powder, fineness ≥ 250 mesh, fly ash grade I or II, slag micropowder S95 grade, cement 32.5, calcium oxide, calcium formate, measure and pour from the packaging bag mixer mixer.

[0045] 3. The on-site gravel and closed-cell perlite have a bulk density of 130-135kg / m 3 , water slag are measured separately, into the mixing mixer.

[0046] 4. Vibration extrusion molding. Let stand for 8-24...

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Abstract

The invention discloses a high-strength waterproof self-insulation gypsum brick prepared by using calcining-free desulfurization gypsum dihydrate / phosphogypsum in the technical field of solid waste recycle of a power plant or a phosphate fertilizer plant and a production method thereof. The brick comprises the following components in percentage by weight: 60 to 80 percent of original desulfurization gypsum dihydrate / phosphogypsum, 10 to 25 percent of active material of volcanic ash mineral, 5 to 15 percent of exciting material, 0.5 to 2 percent of coagulant material, 100 to 200 percent of aggregate and 25 to 40 percent of light aggregate. The preparation method comprises the following steps of: screening semi-moist desulfurization gypsum dihydrate / phosphogypsum, metering, mixing and stirring the screened semi-moist desulfurization gypsum dihydrate / phosphogypsum, the powdery active mineral material ground into powder in advance, the exciting material, the coagulant material, the aggregate and the light aggregate on site, adding a proper amount of water into the mixture, molding the mixture in a molding machine, and then damply and thermally curing the mixture for 24 hours. The method consumes a large amount of solid waste and reduces secondary energy consumption and secondary pollution; and the product has the advantages of light dead weight, high strength, energy conservation, fire prevention, water resistance, acid and alkali resistance and the like, and is suitable for a separating wall, a partition wall, a filling wall, a toilet and a kitchen.

Description

technical field [0001] The invention belongs to the technical field of resource utilization of industrial solid waste. It specifically relates to a kind of solid waste produced after wet desulfurization in thermal power plants - desulfurized gypsum, and solid waste produced in phosphate fertilizer plants - phosphogypsum, without pretreatment, implementing a calcination-free process. Modified to prepare a high-strength, water-resistant self-insulating gypsum brick. Background technique [0002] my country is a big thermal power generation country in the world, every year SO 2 The emission is the first in the world, 25 million tons. The country has adopted mandatory desulfurization measures. By 2010, the desulfurization gypsum produced by desulfurization will reach 50 million tons. In 2009, 50 million tons of solid waste—phosphogypsum—was generated from the production of phosphate fertilizers, and 100 million tons are now in stock. The numbers are staggering. The method of...

Claims

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Application Information

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IPC IPC(8): C04B28/14C04B18/06C04B22/14C04B24/04C04B14/02C04B14/06C04B14/18C04B16/08C04B18/14
CPCC04B20/026C04B2103/12C04B28/142C04B2111/28C04B2103/0088C04B2103/0007C04B28/144Y02W30/91C04B7/02C04B14/02C04B18/027C04B40/0028C04B40/0281C04B14/068C04B14/185C04B16/08C04B18/0418C04B18/141C04B22/064C04B38/0061C04B18/08C04B22/142C04B24/04C04B20/0076
Inventor 马振义
Owner SHANGHAI JINMA BUILDING MATERIALS
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