Process for extracting phytosterol from papermaking wood pulp oil slick pitch
A technology of phytosterols and wood pulp slick oil, which is applied in the direction of preparation of steroids, steroids, chemical instruments and methods, and can solve the problem of difficult separation of long-chain alcohols and acidic impurities, which consumes manpower, material resources, financial resources, and phytosterols. Purity is not reached and other problems, to achieve the effect of industrialized production and environmental protection, great social and economic benefits, and a high degree of comprehensive utilization
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Embodiment 1
[0023] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 45L of methanol and 0.55L of concentrated sulfuric acid into the reaction kettle, heat it to 68°C under stirring conditions, then reflux for 2 hours, add 100L of hot water at 75°C, and let it stand After 15 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.
[0024] The upper oil phase is washed with hot water at 95°C until it is neutral, then heated to 110°C to remove the water in the oil phase, and the oil phase that has been completely dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 180°C, and the fractions at 120°C-210°C are collected as fatty acid esters, and the residual liquid containing phytosterols in the evaporator is dissolved in isopropanol, and then passed throu...
Embodiment 2
[0027] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 45L of methanol and 1.0L of concentrated sulfuric acid into the reaction kettle, heat to 70°C under stirring conditions, then reflux for 2 hours, add 100L of 70°C hot water, and let it stand After 20 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.
[0028] The upper oil phase is washed with hot water at 90°C to neutral, then heated to 115°C to remove the water in the oil phase, and the oil phase that has been dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 190°C, and the fractions from 120°C to 210°C are collected as fatty acid esters. The residual liquid containing phytosterols in the evaporator is dissolved in absolute ethanol, and then passed through anion exchange re...
Embodiment 3
[0031] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 64L of methanol and 1.0L of concentrated sulfuric acid into the reaction kettle, heat it to 72°C under stirring conditions, then reflux for 2 hours, add 100L of 80°C hot water, and let it stand After 18 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.
[0032] The upper oil phase is washed with hot water at 98°C to neutral, then heated to 120°C to remove the water in the oil phase, and the oil phase that has been dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 195°C, and the fractions at 120°C to 210°C are collected as fatty acid esters. The residual liquid containing phytosterols in the evaporator is dissolved in acetone, and then absorbed by anion exchange resin , and ...
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