Unlock instant, AI-driven research and patent intelligence for your innovation.

Process for extracting phytosterol from papermaking wood pulp oil slick pitch

A technology of phytosterols and wood pulp slick oil, which is applied in the direction of preparation of steroids, steroids, chemical instruments and methods, and can solve the problem of difficult separation of long-chain alcohols and acidic impurities, which consumes manpower, material resources, financial resources, and phytosterols. Purity is not reached and other problems, to achieve the effect of industrialized production and environmental protection, great social and economic benefits, and a high degree of comprehensive utilization

Inactive Publication Date: 2011-01-12
东莞市赫尔逊生物科技有限公司
View PDF2 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Regardless of using a single solvent method or a mixed solvent method to extract phytosterols from wood pulp tall oil pitch, they cannot overcome the characteristics that long-chain alcohols and acidic impurities are difficult to separate from sterols In order to overcome the deficiency of solvent extraction method, people begin to introduce the method of distillation recently, and people such as Diaz and Michael. Great improvement, but there are still disadvantages such as large amount of saponified substances polluting the environment, high ordinary distillation temperature, some sterols are destroyed, and the purity of phytosterols has not reached the standards of European and American countries, etc.
[0008] In addition, to prepare phytosterols from tall oil pitch, as far as the basic raw material is concerned, it is necessary to extract tall oil by leaching wood with high tall oil content. Asphalt, this step alone has already consumed a lot of manpower, material resources, and financial resources, and the subsequent sterol extraction process still has many of the above-mentioned defects, so we must conduct research based on our country's raw material resources and industrialization priorities

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Process for extracting phytosterol from papermaking wood pulp oil slick pitch
  • Process for extracting phytosterol from papermaking wood pulp oil slick pitch

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 45L of methanol and 0.55L of concentrated sulfuric acid into the reaction kettle, heat it to 68°C under stirring conditions, then reflux for 2 hours, add 100L of hot water at 75°C, and let it stand After 15 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.

[0024] The upper oil phase is washed with hot water at 95°C until it is neutral, then heated to 110°C to remove the water in the oil phase, and the oil phase that has been completely dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 180°C, and the fractions at 120°C-210°C are collected as fatty acid esters, and the residual liquid containing phytosterols in the evaporator is dissolved in isopropanol, and then passed throu...

Embodiment 2

[0027] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 45L of methanol and 1.0L of concentrated sulfuric acid into the reaction kettle, heat to 70°C under stirring conditions, then reflux for 2 hours, add 100L of 70°C hot water, and let it stand After 20 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.

[0028] The upper oil phase is washed with hot water at 90°C to neutral, then heated to 115°C to remove the water in the oil phase, and the oil phase that has been dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 190°C, and the fractions from 120°C to 210°C are collected as fatty acid esters. The residual liquid containing phytosterols in the evaporator is dissolved in absolute ethanol, and then passed through anion exchange re...

Embodiment 3

[0031] Add 50kg of wood pulp tall oil pitch containing 8.1% phytosterols, 64L of methanol and 1.0L of concentrated sulfuric acid into the reaction kettle, heat it to 72°C under stirring conditions, then reflux for 2 hours, add 100L of 80°C hot water, and let it stand After 18 minutes, the aqueous phase containing sulfuric acid and methanol in the lower layer was discarded, and the oil phase containing phytosterols and fatty acid esters in the upper layer was retained.

[0032] The upper oil phase is washed with hot water at 98°C to neutral, then heated to 120°C to remove the water in the oil phase, and the oil phase that has been dehydrated is added to the distillation still of molecular distillation. Keep under the condition of 2Pa, the distillation temperature is 195°C, and the fractions at 120°C to 210°C are collected as fatty acid esters. The residual liquid containing phytosterols in the evaporator is dissolved in acetone, and then absorbed by anion exchange resin , and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a process for extracting phytosterol from papermaking wood pulp oil slick pitch. The method comprises the following steps of: selecting the waste of wood pulp used in the papermaking industry, i.e. wood pulp oil slick pitch; and directly extracting phytosterol from the wood pulp oil slick pitch by utilizing an ion exchange resin method. The invention can be used for directly extracting the phytosterol from the papermaking wood pulp oil slick pitch instead of the steps of extracting tall oil from the wood pulp and then extracting the phytosterol from the tall oil and has the advantages of low raw material cost, high comprehensive utilization degree and high purity and yield of the extracted phytosterol.

Description

technical field [0001] The invention discloses a method for extracting phytosterols from papermaking wood pulp tall oil pitch. Background technique [0002] Phytosterols are a class of natural components present in plants. A large number of animal experiments and human clinical trial data show that phytosterols and their esters have significant significance in reducing blood cholesterol levels and reducing the occurrence of cardiovascular diseases. They are an important medicine Raw materials and health food ingredients. [0003] The Finnish Rasio company introduced the phytosterol-containing product Benecol to the market in 1995. It is the first country in the world to introduce phytosterol-lowering cholesterol functional foods. Later, Australia, Belgium, Brazil, Denmark, France, Germany, Japan, the Netherlands, Spain, Products from Switzerland, Sweden, the United Kingdom, the United States and other countries have been launched one after another. In 1999, phytosterol foo...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07J75/00
Inventor 曾昭利
Owner 东莞市赫尔逊生物科技有限公司