Method for manufacturing sintered iron strontium oxide permanent magnetic material

A technology of permanent magnet material and strontium ferrite, which is applied in the direction of magnetism of inorganic materials, can solve the problems affecting the performance of strontium permanent magnet ferrite, poor mixing uniformity, poor consistency, large water content of slurry, etc., so as to shorten the sintering time. time, reduced energy consumption, high performance

Active Publication Date: 2012-10-31
江门江益磁材有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The wet process manufacturing method is to make various raw materials into slurry, mix and sinter through wet ball milling or sand milling, so as to ensure that various raw materials are mixed evenly and can obtain high-performance sintered strontium ferrite permanent magnet materials, but This process has the defect of high water content in the slurry, which results in high energy consumption; the dry process manufacturing method refers to the use of a dry strong mixer to mix various raw materials in a certain proportion, pelletize and sinter. Factors such as agglomeration of raw materials and poor fluidity lead to poor mixing uniformity and consistency, which ultimately affect the performance of strontium permanent magnet ferrite
Moreover, the sintering time of the existing dry process for manufacturing sintered strontium ferrite permanent magnet materials generally takes 4-8 hours, and the sintering time is long, so the energy consumption is large

Method used

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  • Method for manufacturing sintered iron strontium oxide permanent magnetic material
  • Method for manufacturing sintered iron strontium oxide permanent magnetic material
  • Method for manufacturing sintered iron strontium oxide permanent magnetic material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] SKM-1C iron oxide produced by South Korea's EG CORPORATION and strontium carbonate produced by Xiangyun County Pingnan Huagong Co., Ltd. are selected. The ingredients of the two raw materials are as follows:

[0027] The main components of table 2SKM-1C iron oxide

[0028] project

Fe 2 o 3

SiO 2

CaO

al 2 o 3

MnO

average particle size

unit

ppm

ppm

ppm

ppm

Micron

data

99.16

112

121

546

1860

0.85

[0029] Table 3 Main components of strontium carbonate produced by Xiangyun County Pingnan Huagong Co., Ltd.

[0030] project

SrCO 3

CaCO 3

BaCO 3

average particle size

unit

Micron

data

97.58

0.35

0.50

1.5

[0031] Weigh 37.4 kg of SrCO 3 , 233 kg of Fe 2 o 3 , 0.812 kg of SiO 2 and 0.406 kg of Al 2 o 3 After batching, first mix and disperse...

Embodiment 2

[0036] Select the raw material of embodiment 1 for use, take by weighing 38 kilograms of SrCO 3 , 232.8 kg of Fe 2 o 3 , 0.54 kg of SiO 2 and 0.140 kg of Al 2 o 3 After carrying out batching, other processing conditions are with embodiment 1.

[0037] Measuring magnetic properties: Add 1.2% CaCO when wet grinding 3 , 0.3% H 3 BO 3 , 0.1% SiO 2and 1% A20 dispersant, make a round blank according to the process of Example 1, and sinter the green body at a temperature of 1200° C. (sample 3) and 1230° C. (sample 4) respectively. The magnetic performance test results of the samples are as follows:

[0038] Table 5 Sample magnetic properties of trial materials

[0039] sample

Embodiment 3

[0041] Select the raw material of embodiment 1 for use, weigh 37.7 kilograms of SrCO 3 , 233 kg of Fe 2 o 3 , 0.812 kg of SiO 2 and 0.271 kg of Cr 2 o 3 After carrying out batching, other processing conditions are with embodiment 1.

[0042] Measuring magnetic properties: Add 1.2% CaCO when wet grinding 3 , 0.4% H 3 BO 3 and 1% A20 dispersant, the process of embodiment 1 is used to make a circular blank, and the green body is sintered at 1200° C. (sample 5), 1210° C. (sample 6) temperature respectively. The magnetic performance test results of the samples are as follows:

[0043] Table 6 Sample magnetic properties of trial-produced materials

[0044] sample

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Abstract

The invention relates to a method for manufacturing a sintered iron strontium oxide permanent magnetic material, comprising the following steps of: preparing materials, wherein raw materials comprise 84.4-87.05 percent of Fe2O3 with purity higher than 99 percent and 12.95-15.60 percent of SrCO3 with the purity higher than 97 percent, as well as 0.05-0.4 percent of industrial pure silicon dioxide and 0.05-0.3 percent of industrial pure alumina or chromic oxide relative to the total charge weight, and the raw materials are powdery with the particle mean size smaller than 1 micron; and carrying out the steps of strong dry-type mixing, continuous dry-type sanding, palletizing, screening and sintering on the prepared powdery materials to obtain the sintered iron strontium oxide permanent magnetic material. The manufacturing method of the invention can ensure that various raw materials are uniformly mixed, refined and closely contacted so that the sintered iron strontium oxide permanent magnetic material with higher property can be obtained, and can ensure that material pellets are smaller in sphere diameter and narrower in dimensional range so that the sintering time is shortened, the production efficiency is improved and the energy consumption is reduced, and moreover, the manufacturing method is simple in process and has no pollution to the environment.

Description

technical field [0001] The invention relates to a method for manufacturing a magnetic material, in particular to a method for manufacturing a sintered strontium ferrite permanent magnet material. Background technique [0002] The formation of ferrite is the result of solid-state reaction between the powder particles of each component. To obtain ferrite whose chemical composition strictly conforms to the formula, the uniform mixing of raw materials and the close contact between raw materials are very important. At present, the manufacturing methods of sintered strontium ferrite permanent magnet materials can be divided into wet process manufacturing method and dry process manufacturing method according to the mixing method. The wet process manufacturing method is to make various raw materials into slurry, mix and sinter through wet ball milling or sand milling, so as to ensure that various raw materials are mixed evenly and can obtain high-performance sintered strontium ferri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/11C04B35/26C04B35/622
Inventor 汪南东吴捷吕兆民姚少喜陈才强王顺尧黄秀芬
Owner 江门江益磁材有限公司
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