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Functional filling capable of improving wear-resistant property of plastic and rubber and preparation method thereof

A technology of functional fillers and wear resistance, applied in the field of functional fillers and their preparation, can solve the problems of not meeting the requirements of high wear resistance, limited effect of wear resistance modification, high product cost, etc., and achieve excellent scratch resistance Performance, low production cost, and low equipment investment

Active Publication Date: 2011-04-20
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, to improve the wear resistance of plastics and rubber materials, it is generally to choose high polymer resins with better wear resistance or add resins and fillers with better wear resistance to general-purpose resins. For example, adding polyurethane to PVC can enhance the wear resistance. Abrasiveness, but polyurethane is expensive, and only a high blending ratio can have wear resistance, resulting in high product cost; adding common fillers such as calcium carbonate, talcum powder, mica powder, etc. to PVC, PP, rubber, etc. It can improve wear resistance, but because these fillers themselves have low hardness, their wear-resistant modification effect is limited; adding calcium carbonate whiskers and barium sulfate whiskers to PVC, PP, and rubber can improve wear resistance, because the whiskers Special structure, the wear resistance effect of modified plastic rubber is better than that of ordinary fillers, but there are still deficiencies. The whisker material is relatively brittle and easy to break during processing. After being manufactured into products, it still cannot meet the requirements for high wear resistance.

Method used

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  • Functional filling capable of improving wear-resistant property of plastic and rubber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Example 1: Preparation of a functional filler A for soft and hard PVC.

[0014] Weigh the silicate compound particles according to a certain amount, put them into a high-speed stirrer, and then add stearic acid accounting for 1.0% of the total mass of functional fillers + titanate accounting for 1.0% of the total mass of functional fillers as activation Coupling agent, stirring speed 1200-1500 rev / min, stirring for 10-15 minutes. The stirring temperature was 100°C.

Embodiment 2

[0015] Example 2: Preparation of a functional filler B for polypropylene.

[0016] Weigh the silicate compound particles according to a certain amount, put them into a high-speed stirrer, and then add KH-560 silane coupling agent accounting for 1.0% of the total mass of functional fillers, stirring at a speed of 1200-1500 rpm, stirring 10-15 minutes. The stirring temperature is 90°C.

Embodiment 3

[0017] Embodiment 3: Preparation of a functional filler C for nitrile rubber.

[0018] Weigh the silicate compound particles according to a certain amount, put them into a high-speed stirrer, and then add stearic acid accounting for 1.0% of the total mass of functional fillers + aluminum-titanium coupling agent accounting for 1.5% of the total mass of functional fillers (commercially available product), stirring speed 1200~1500 rpm, stirring for 10~15 minutes. The stirring temperature was 110°C.

[0019] Changes in the amount of the coupling agent within the scope of the present invention will not affect its effect, and the preparation method is the same.

[0020] The following examples are specific implementations of the application of three functional fillers. Each part number is a mass part number.

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Abstract

The invention provides a functional filling capable of improving the wear-resistant property of plastic and rubber, which is characterized in that the raw material of the filling is the fragments generated during jade processing, the silicate compound grains with a laminated structure having an average particle size of 0.5 to 20 micron are obtained after the raw material is grinded, screened, graded and dried, the water content is less than 0.4%, and the functional filling is obtained after activating treatment is done to the silicate compound grains and an coupling agent. Plastic or rubber modified by the functional filling has excellent wear-resisting property, and materials made by which have excellent processing property and excellent mechanical property. The filling is mainly applied to the industries having high requirements on wear-resisting properties such as the PVC plastic wire and cable industry and the rubber conveyer belt industry. The invention is also advantaged in that the fragments produced during jade processing is better used, thereby turning wastes into treasure and reducing environmental pollution effectively. Moreover, the production process is simple and the production cost is low.

Description

technical field [0001] The invention relates to a functional filler capable of improving the wear resistance of plastics and rubber and a preparation method thereof. Background technique [0002] With the rapid development of the plastic and rubber industry, the grades of various functional plastic and rubber products are getting higher and higher, and the demand is also increasing. The performance of existing products can no longer meet the demand. Products and raw materials with high wear-resistant and super wear-resistant plastic rubber have broad application space and market prospects, and meet the development needs of my country's new material market. [0003] At present, to improve the wear resistance of plastics and rubber materials, it is generally to choose high polymer resins with better wear resistance or add resins and fillers with better wear resistance to general-purpose resins. For example, adding polyurethane to PVC can enhance the wear resistance. Abrasiven...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K3/34C08K9/04C08L27/06
Inventor 李静王晶程志凌刘容德贾小波刘浩桂俊杰孙丽朋王秀丽
Owner CHINA PETROLEUM & CHEM CORP
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