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Catalyst conversion method for producing high-octane gasoline by using crude oil

A technology of high-octane gasoline and catalytic conversion method, which is applied in the direction of catalytic cracking, cracking, and petroleum industry, and can solve problems affecting gasoline octane number, poor gasoline properties, and insufficient utilization of gasoline latent content, etc.

Active Publication Date: 2014-04-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has many disadvantages such as poor gasoline properties and high energy consumption.
[0004] In addition, the octane number of the heavy fraction of catalytic cracked gasoline is low, which affects the octane number of gasoline; the quality of catalytic cracked diesel oil is poor, but the catalytic cracked diesel oil contains more single-ring aromatics. If the single-ring aromatics in diesel oil are converted As a gasoline component, it is conducive to the increase of gasoline yield and at the same time can improve the octane number of gasoline
Therefore, the existing technology does not fully utilize the gasoline octane number and the gasoline potential content in diesel oil, and there is room for improvement in gasoline yield and quality

Method used

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  • Catalyst conversion method for producing high-octane gasoline by using crude oil
  • Catalyst conversion method for producing high-octane gasoline by using crude oil
  • Catalyst conversion method for producing high-octane gasoline by using crude oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0084] This example follows the attached image 3 MGCO-2 is used as the catalyst, and feedstock oil A is directly used as the easy-to-crack feedstock oil for catalytic cracking. The test is carried out on a medium-sized device with a riser reactor. The easy-to-crack feedstock oil enters the middle and upper part of the reaction zone I. Cracked raw oil enters the bottom of reaction zone I. At the bottom of reaction zone I, the refractory raw material oil is heated at a reaction temperature of 600°C and a weight hourly space velocity of 240h -1 , the weight ratio of catalytic cracking catalyst to refractory feed oil is 30, and the weight ratio of water vapor to refractory feed oil is 0.20 to carry out the cracking reaction; Hourly space velocity 90h -1 The cracking reaction is carried out under the condition that the weight ratio of the catalytic cracking catalyst to the easy-to-crack raw oil is 10, and the weight ratio of the water vapor to the easy-to-crack raw oil is 0.15. ...

Embodiment 2

[0090] This example follows the attached Figure 4 The test is carried out according to the process, with MGCO-2 as the catalyst, the raw material oil B is directly used as the difficult-to-crack raw material oil of catalytic cracking, and the test is carried out on a medium-sized device with a riser reactor. The cracked raw oil enters the upper part of the reaction zone I to react. At the bottom of the reaction zone I, the refractory feed oil is heated at a reaction temperature of 580°C and a weight hourly space velocity of 200h -1 , the weight ratio of catalytic cracking catalyst to refractory feed oil is 60, and the weight ratio of water vapor to refractory feed oil is 0.20 to carry out the cracking reaction; Hourly space velocity 120h -1 , the weight ratio of catalytic cracking catalyst to easily cracked raw oil is 30, and the weight ratio of water vapor to easily cracked raw oil is 0.15 to carry out the cracking reaction; in addition, the supplementary part of the raw c...

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Abstract

The invention provides a catalytic conversion method for producing high-octane gasoline by using crude oil, which comprises: contacting pretreated crude oil serving as raw material oil with a catalyst which contains macroporous zeolite and is distributed according to a coarse particle size in a catalytic conversion reactor to perform a reaction according to reaction temperature, oil gas dwell time and catalyst to raw material oil weight ratio, which are proper enough to enable the reaction to obtain a reaction product containing catalytic wax oil which accounts for 15 to 60 percent of the weight of the raw material oil, wherein the weight hourly space velocity is 25 to 100h<-1>, the reaction temperature is 450 to 600 DEG C, and he weight ratio of the catalyst to the raw material oil is 1 to 30. In the method, while low-quality crude oil is converted into high-octane gasoline, the dry gas and coke yields are reduced considerably, the high-efficient utilization of oil resources is realized, and the higher particle uniformity of the catalyst makes the local temperature distribution in a regeneration process more uniform and the breakage orientation of the catalyst lowered correspondingly.

Description

technical field [0001] The invention relates to a method for catalytic conversion of crude oil, in particular to a method for converting heavy crude oil into high-octane gasoline while greatly reducing dry gas and coke yields so as to realize efficient utilization of petroleum resources. Background technique [0002] With the development of the economy, the number of gasoline vehicles in the world is increasing year by year, so the demand for high-quality gasoline is increasing. Catalytic cracking (FCC) gasoline has good anti-knock performance and is one of the main sources of motor gasoline. [0003] The production of FCC gasoline generally uses straight-run vacuum distillate (VGO) as raw material and blends some residues such as atmospheric residue (AR) and vacuum residue (VR). Heavy raw materials such as residual oil contain high content of heavy metals such as residual carbon, sulfur, nitrogen, nickel, and vanadium. In order to improve the feed properties of these cata...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/04C10G55/06C10G11/05C10G11/20
Inventor 唐津莲许友好崔守业汪燮卿
Owner CHINA PETROLEUM & CHEM CORP
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