Skin-core composite electromagnetic shielding fiber and preparation method thereof
A composite electromagnetic and fiber technology, applied in fiber processing, fiber chemical characteristics, conjugated synthetic polymer artificial filament, etc., can solve problems such as difficult to be widely used, low electromagnetic shielding efficiency, and easy agglomeration of conductive powder. Achieve the effect of low cost, good practical value and high shielding efficiency
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Embodiment 1
[0040] (1) Pretreatment of low melting point metals and / or alloys
[0041] Isopropyl tricarboxylic titanate and the tin-antimony alloy (60 / 40) particles with an average particle size of 5mm are put into a high-temperature kneader and stirred; when stirring, the rotating speed is 200r / min, and high-speed stirring is performed for 15min, and the treated tin-antimony ( 60 / 40) alloy particles were dried for 2 hours; wherein the mass ratio of tin-antimony (60 / 40) alloy particles to isopropyl tricarboxylic titanate was 99.8:0.2;
[0042] (2) Skin-core composite melt extrusion
[0043] The skin-core composite structural fiber is prepared by two-component composite spinning, and the specific steps are:
[0044] a) Dry the mixture of pretreated tin-antimony (60 / 40) alloy particles and isopropyl tricarboxylic titanate; vacuum-dry PP; The mass ratio of the carboxy titanate mixture to PP is 3:5;
[0045] b) The spinning equipment is preheated to 230°C, and the dried PP is fed into one ...
Embodiment 2
[0048] (1) Pretreatment of low melting point metals and / or alloys
[0049] Mix and dilute isopropyl dioleoyl diisooctyl phosphate acyloxy voltate and isopropanol in equal proportions, then put 1mm tin gold particles into a high-temperature kneader, and spray the above solution directly on the tin gold particles and Stir; rotating speed 200r / min during stirring, high-speed stirring 15min, the tin gold particle after the gained treatment carries out 2h drying; Wherein the mass ratio of tin gold particle and dioleoyl diisooctyl phosphate acyloxy voltate isopropyl voltate is 97: 3;
[0050] (2) Skin-core composite melt extrusion
[0051] The skin-core composite structural fiber is prepared by two-component composite spinning, and the specific steps are:
[0052] a) Dry the mixture of the pretreated tin gold particles and dioleoyl diisooctyl phosphate acyloxy voltate isopropyl voltate; PET is vacuum dried; The mass ratio of the mixture of isopropyl phosphonic acid and PET is 20:...
Embodiment 3
[0057] (1) Pretreatment of low melting point metals and / or alloys
[0058] Mix and dilute isopropyl trioleate and petroleum ether in equal proportions, then put 2mm bismuth gold particles into a high-temperature kneader, and directly spray the above solution on the bismuth gold particles and stir; Rotating speed 200r / min, stirring at high speed for 15min, the obtained treated bismuth particles were dried for 2h; wherein the mass ratio of bismuth gold particles to isopropyl trioleate acyloxy titanate was 97:3;
[0059] (2) Skin-core composite melt extrusion
[0060] The skin-core composite structural fiber is prepared by two-component composite spinning, and the specific steps are:
[0061] a) drying the mixture of pretreated bismuth gold particles and isopropyl trioleate acyloxy titanate; PBT is vacuum dried; bismuth gold particles and isopropyl trioleate acyloxy titanate The mass ratio of the mixture and PBT is 20:5;
[0062] b) The spinning equipment is preheated to 290°C...
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