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Quantum dot with core shell structure and preparation method of quantum dot

A core-shell structure and quantum dot technology, applied in the field of nanomaterials for photovoltaic cells, can solve the problems of high cost and hinder the rapid development of the photovoltaic cell industry, and achieve the effects of less structural defects, stable fluorescence emission performance, and long service life

Inactive Publication Date: 2013-06-19
HENAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the high cost of directly converting solar energy into electricity through photovoltaic cells, for example, the cost is 5 to 10 times that of nuclear energy and 25 to 50 times that of primary fossil energy, the problem of high cost has consistently hindered the development of photovoltaic cells. The rapid development of the industry
However, the pure chemical synthesis method to synthesize core-shell structure nanocrystals and directly use them to improve the photoelectric conversion efficiency of silicon solar cells has not been reported.

Method used

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  • Quantum dot with core shell structure and preparation method of quantum dot
  • Quantum dot with core shell structure and preparation method of quantum dot
  • Quantum dot with core shell structure and preparation method of quantum dot

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Embodiment 1

[0029] The quantum dot with core-shell structure of this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell. The particle diameter of the core is 3-6 nm, and the thickness of the shell is 0.1-6 nm. 0.5nm. The fluorescence excitation peak λ of the quantum dot ex.max Located at 358nm, emission peak λ em.max Located at 470nm.

[0030] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and L-cysteine ​​as raw materials, and measures 100ml of cadmium acetate aqueous solution of 0.1mol / L and 0.1mol / L of L-cysteine Aqueous acid solution 110mL, then put into conical flask and mix to prepare reaction solution, wherein the molar ratio of Cd / S is 0.91, wherein the concentration of cadmium acetate in the reaction solution is 47.6mmol / L, L-cysteine ​​in the reaction The concentration in the solution is 52.4 mmol / L, and then the pH value is adjusted to 10 with po...

Embodiment 2

[0032] The quantum dot with core-shell structure in this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell.

[0033] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and thiourea as raw materials, measures 85 ml of 0.1 mol / L cadmium acetate aqueous solution and 110 mL of 0.1 mol / L thiourea aqueous solution, and then puts them into a cone mixed in a shaped bottle to prepare a reaction solution, wherein the mol ratio of Cd / S is 0.77, wherein the concentration of cadmium acetate in the reaction solution is 43.6mmol / L, and the concentration of thiourea in the reaction solution is 56.4 mmol / L. Potassium hydroxide adjusts the pH value to 9, and then transfers the above-mentioned pH-adjusted reaction solution into the inner tank of the autoclave, seals the autoclave and tightens the closed nuts of the autoclave symmetrically in stages, and heats the autocla...

Embodiment 3

[0035] The quantum dot with core-shell structure in this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell.

[0036] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and thiourea as raw materials, measures 108 ml of 0.1 mol / L cadmium acetate aqueous solution and 110 mL of 0.1 mol / L thiourea aqueous solution, and then puts them into a cone mixed in a shaped flask to prepare a reaction solution, wherein the mol ratio of Cd / S is 0.98, wherein the concentration of cadmium acetate in the reaction solution is 49.5mmol / L, and the concentration of thiourea in the reaction solution is 50.5mmol / L. Potassium hydroxide adjusts the pH value to 13, and then transfers the above-mentioned pH-adjusted reaction solution into the inner tank of the autoclave, seals the autoclave and tightens the closed nuts of the autoclave symmetrically in stages, and heats the autocla...

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Abstract

The invention discloses a quantum dot with a core shell structure and a preparation method of the quantum dot. The quantum dot with the core shell structure is provided with the core shell structure with a cadmium sulfide material as a core and a cadmium sulfite material as a shell and is prepared through a hydrothermal synthesis method. The quantum dot with the core shell structure, provided by the invention, has the core with the size of 3-6 nm and a shell layer with the thickness of 0.1-0.5 nm. The quantum dot is perfectly crystallized and has the advantages of high stability, favorable fluorescence emission peak shape, stable maximum emission peak position, and the like. Because the hydrothermal synthesis method is adopted for the preparation method of the quantum dot with the core shell structure, provided by the invention, the defects of many structural imperfections, poor chemical stabilization and poor fluorescence emission performance of the quantum dot prepared by the traditional water method are overcome, the toxicity and high cost of the quantum dot prepared by a metal organic method are also avoided, the preparation method has the advantages of simplicity, easiness for operation and low cost, and the quantum dot with the core shell structure and adjustable granularity can be prepared by utilizing the hydrothermal synthesis method.

Description

technical field [0001] The invention relates to the technical field of nanomaterials for photovoltaic cells, in particular to a quantum dot with a core-shell structure and a preparation method thereof. Background technique [0002] The sun provides about 100,000 megawatts of energy that we can use, which is about 10,000 times the current energy consumption rate of the earth. Photovoltaic cells are increasingly being used to exploit this vast energy resource and will play a key role in future sustainable energy systems. However, due to the high cost of directly converting solar energy into electricity through photovoltaic cells, for example, the cost is 5 to 10 times that of nuclear energy and 25 to 50 times that of primary fossil energy, the problem of high cost has consistently hindered the use of photovoltaic cells The rapid development of the industry. [0003] Recent experiments have shown that the new quantum dot technology based on nanotechnology can significantly im...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/54C09K11/02
Inventor 许荣辉文九巴贾江议李海涛赵飞韩金波尚兴记
Owner HENAN UNIV OF SCI & TECH