Quantum dot with core shell structure and preparation method of quantum dot
A core-shell structure and quantum dot technology, applied in the field of nanomaterials for photovoltaic cells, can solve the problems of high cost and hinder the rapid development of the photovoltaic cell industry, and achieve the effects of less structural defects, stable fluorescence emission performance, and long service life
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0029] The quantum dot with core-shell structure of this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell. The particle diameter of the core is 3-6 nm, and the thickness of the shell is 0.1-6 nm. 0.5nm. The fluorescence excitation peak λ of the quantum dot ex.max Located at 358nm, emission peak λ em.max Located at 470nm.
[0030] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and L-cysteine as raw materials, and measures 100ml of cadmium acetate aqueous solution of 0.1mol / L and 0.1mol / L of L-cysteine Aqueous acid solution 110mL, then put into conical flask and mix to prepare reaction solution, wherein the molar ratio of Cd / S is 0.91, wherein the concentration of cadmium acetate in the reaction solution is 47.6mmol / L, L-cysteine in the reaction The concentration in the solution is 52.4 mmol / L, and then the pH value is adjusted to 10 with po...
Embodiment 2
[0032] The quantum dot with core-shell structure in this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell.
[0033] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and thiourea as raw materials, measures 85 ml of 0.1 mol / L cadmium acetate aqueous solution and 110 mL of 0.1 mol / L thiourea aqueous solution, and then puts them into a cone mixed in a shaped bottle to prepare a reaction solution, wherein the mol ratio of Cd / S is 0.77, wherein the concentration of cadmium acetate in the reaction solution is 43.6mmol / L, and the concentration of thiourea in the reaction solution is 56.4 mmol / L. Potassium hydroxide adjusts the pH value to 9, and then transfers the above-mentioned pH-adjusted reaction solution into the inner tank of the autoclave, seals the autoclave and tightens the closed nuts of the autoclave symmetrically in stages, and heats the autocla...
Embodiment 3
[0035] The quantum dot with core-shell structure in this embodiment has a core-shell structure with cadmium sulfide material as the core and cadmium sulfite material as the shell.
[0036] The preparation method of quantum dots with a core-shell structure in this embodiment uses cadmium acetate and thiourea as raw materials, measures 108 ml of 0.1 mol / L cadmium acetate aqueous solution and 110 mL of 0.1 mol / L thiourea aqueous solution, and then puts them into a cone mixed in a shaped flask to prepare a reaction solution, wherein the mol ratio of Cd / S is 0.98, wherein the concentration of cadmium acetate in the reaction solution is 49.5mmol / L, and the concentration of thiourea in the reaction solution is 50.5mmol / L. Potassium hydroxide adjusts the pH value to 13, and then transfers the above-mentioned pH-adjusted reaction solution into the inner tank of the autoclave, seals the autoclave and tightens the closed nuts of the autoclave symmetrically in stages, and heats the autocla...
PUM
| Property | Measurement | Unit |
|---|---|---|
| particle diameter | aaaaa | aaaaa |
| thickness | aaaaa | aaaaa |
| size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More 


