Ru-Pd-Co-coated Titanium Electrode with Sn-Sb Interlayer

An intermediate layer and titanium electrode technology, applied in the direction of electrodes, electrolytic components, electrolytic process, etc., can solve the problems of harsh preparation conditions, short service life, short service life of electrodes, etc., and achieve improved electrochemical performance, increased service life, high The effect of oxygen evolution potential

Inactive Publication Date: 2011-12-07
NANJING UNIV OF SCI & TECH
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Problems solved by technology

Different anode materials will have a great impact on the type of catalytic reaction, the degradation efficiency of organic matter and the service life of the electrode
[0003] The traditional titanium-based ruthenium dioxide (RuO2/Ti) that is often used as an anode in electrocatalysis technology is easily dissolved during use, resulting in a short service life of the electrode, and its electrocatalytic performance is not high, and it can catalyze and degrade pollution in water treatment. A large amount of oxygen w

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  • Ru-Pd-Co-coated Titanium Electrode with Sn-Sb Interlayer
  • Ru-Pd-Co-coated Titanium Electrode with Sn-Sb Interlayer
  • Ru-Pd-Co-coated Titanium Electrode with Sn-Sb Interlayer

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Embodiment Construction

[0013] The present invention will be further described below in conjunction with accompanying drawing.

[0014] combine figure 1 , the ruthenium-palladium-cobalt-coated titanium electrode containing the tin-antimony intermediate layer of the present invention, the surface of the titanium plate main body 1 has several layers of tin-antimony oxide coatings 2 as the intermediate layer, and the surface of the intermediate layer has several layers of ruthenium-palladium-cobalt oxide coatings 3 As the surface layer; by adding a certain proportion of palladium (Pd, PdO) cobalt (Co, CoO, Co2O3) elements to RuO2 as the electrode surface layer, the electrocatalytic performance and service life of the electrode are improved; by adding tin antimony oxide intermediate layer, Further improve the electrocatalytic performance and service life of the electrode; through various testing methods and using the electrode in the water treatment process, it is proved that the electrode of the utility...

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Abstract

The invention discloses a ruthenium-palladium-cobalt coating electrode containing a tin-antimony intermediate layer. The surface of the main body of a titanium plate is coated with 3-7 layers of tin-antimony oxide coating as the intermediate layer of the target electrode; the surface of the intermediate layer is coated with There are 15-24 layers of ruthenium palladium cobalt oxide coating as the surface layer of the target electrode. Compared with the traditional ruthenium dioxide coated titanium electrode (RuO2/Ti), the coated titanium electrode of the present invention has higher oxygen evolution potential and lower Excellent chlorine evolution potential and longer service life can effectively improve the current efficiency and electrode service life of the electrocatalytic oxidation reaction system.

Description

technical field [0001] The invention belongs to the electrocatalytic oxidation reaction system anode coating material in the field of electrochemical technology, in particular to a ruthenium palladium cobalt coating titanium electrode containing a tin antimony intermediate layer. Background technique [0002] Coated titanium electrode, also known as DSA (Dimensionally Stable Anodes, DSA) electrode, is one of the most successful technological breakthroughs in the field of electrochemical research in recent years. Good removal effect. The anode is the place where the electrocatalytic reaction proceeds and active species are produced. Different anode materials will have a great impact on the type of catalytic reaction, the degradation efficiency of organic matter and the service life of the electrode. [0003] The traditional titanium-based ruthenium dioxide (RuO2 / Ti) that is often used as an anode in electrocatalysis technology is easily dissolved during use, resulting in a ...

Claims

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Application Information

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IPC IPC(8): C25B11/04C25B11/10
Inventor 安立超卢强
Owner NANJING UNIV OF SCI & TECH
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