Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant and its preparation and application

A technology of potato starch and polymerized ferric sulfate, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of refractory organic polymer components, damage to the nervous system, affecting application, etc., and achieves simple steps, improved efficiency, and improved operation. handy effect

Inactive Publication Date: 2011-12-14
GANSU TIPTOP PLANT TECH CORP
View PDF10 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although a wide variety of inorganic-synthetic organic polymer composite flocculants have been produced over the years, the cost is relatively high due to the refractory organic polymer components, and some are toxic. For example, polyacrylamide is safe and non-toxic, but its decomposition The acrylamide monomer is a kind of neurotoxic agent, which can damage the nervous system. After poisoning, it will show symptoms such as body weakness and ataxia, which also greatly affects their application.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 1:3.

[0019] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:

[0020] (1) Preparation of polymerized ferric sulfate: first, dissolve 10-16g of ferrous sulfate heptahydrate in 30-100mL of water to prepare a solution with a mass fraction of ferrous sulfate of 5.2%-22.6%; then, use 0.40-1.20mL, mass Concentrated sulfuric acid with a concentration of 95% to 98% adjusts SO in the solution 4 2- content, so that [SO 4 2- ] / [Fe 3+ ] The ratio of the amount of substance is 1.2 ~ 1.4; Finally, 1.0 ~ 5.0mL of hydrogen peroxide with a mass concentration of 30% is added dropwise under continuous stirring at 20 ~ 100 ° C to make F...

Embodiment 2

[0025] Example 2 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 1:1.

[0026] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:

[0027] (1) Preparation of polyferric sulfate is the same as in Example 1.

[0028] (2) Prepare carboxymethyl potato starch with embodiment 1.

[0029] (3) 0.84 g of carboxymethyl potato starch was dissolved in 60 mL of distilled water to obtain an aqueous solution with a mass fraction of 1.4%.

[0030] (4) the aqueous solution of step (3) gained is added dropwise in the polyferric sulfate with the speed of 0.1~1.0mL / min, makes the ratio of the iron quality in the polyferric sulfate and carboxymethyl potato starch quality be 1: 1, React for 60 minutes under ...

Embodiment 3

[0031]Example 3 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 3:1.

[0032] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:

[0033] (1) Preparation of polyferric sulfate is the same as in Example 1.

[0034] (2) Prepare carboxymethyl potato starch with embodiment 1.

[0035] (3) 0.28 g of carboxymethyl potato starch was dissolved in 60 mL of distilled water to obtain an aqueous solution with a mass fraction of 0.5%.

[0036] (4) the aqueous solution of step (3) gained is added dropwise in the polyferric sulfate with the speed of 0.1~1.0mL / min, makes the ratio of the iron quality in the polyferric sulfate and carboxymethyl potato starch quality be 3: 1, React for 30 minutes under n...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a polymeric ferric sulfate-carboxymethyl potato starch composite flocculant. The flocculant is complexed by polymeric ferric sulfate and carboxymethyl potato starch, wherein the weight ratio of Fe in polymeric ferric sulfate to carboxymethyl potato starch is 1:3-3:1. The invention also discloses a preparation method of the flocculant and an application of the flocculant in the COD wastewater treatment. After the composite flocculant prepared from carboxymethyl potato starch is introduced in polymeric ferric sulfate, the defect that the molecular chain of the inorganicflocculant is short can be overcome, the damage of the residues generated in the flocculation process of polymeric aluminum and the synthetic macromolecular flocculant can be avoided; and the charge neutralization capability can be fully utilized, the flocculant has high-effect functions of bridging and net capturing and tiny particles in wastewater can be removed through sweeping, thus the removal efficiency can be increased.

Description

technical field [0001] The invention relates to the technical field of water treatment flocculants, in particular to a polymeric ferric sulfate-carboxymethyl potato starch composite flocculant and its preparation and application. Background technique [0002] Inorganic polymer flocculant is a new type of water treatment agent developed on the basis of traditional aluminum salt and iron salt flocculant. Traditional aluminum salt and iron salt flocculants have been used for a long time, but there are many problems in the process of water treatment. They were replaced by inorganic polymer flocculants that gradually developed rapidly in the late 1960s. The latter has better performance than the former. Excellent flocculation effect and low price. So far, there have been quite large-scale productions in the United States, Japan, Western Europe, and Russia, and the process control automation has been achieved, and the product quality is stable. With the development of my country...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/56
Inventor 何玉凤刘世磊王荣民王华张玲
Owner GANSU TIPTOP PLANT TECH CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products