Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant and its preparation and application
A technology of potato starch and polymerized ferric sulfate, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of refractory organic polymer components, damage to the nervous system, affecting application, etc., and achieves simple steps, improved efficiency, and improved operation. handy effect
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Embodiment 1
[0018] Example 1 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 1:3.
[0019] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:
[0020] (1) Preparation of polymerized ferric sulfate: first, dissolve 10-16g of ferrous sulfate heptahydrate in 30-100mL of water to prepare a solution with a mass fraction of ferrous sulfate of 5.2%-22.6%; then, use 0.40-1.20mL, mass Concentrated sulfuric acid with a concentration of 95% to 98% adjusts SO in the solution 4 2- content, so that [SO 4 2- ] / [Fe 3+ ] The ratio of the amount of substance is 1.2 ~ 1.4; Finally, 1.0 ~ 5.0mL of hydrogen peroxide with a mass concentration of 30% is added dropwise under continuous stirring at 20 ~ 100 ° C to make F...
Embodiment 2
[0025] Example 2 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 1:1.
[0026] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:
[0027] (1) Preparation of polyferric sulfate is the same as in Example 1.
[0028] (2) Prepare carboxymethyl potato starch with embodiment 1.
[0029] (3) 0.84 g of carboxymethyl potato starch was dissolved in 60 mL of distilled water to obtain an aqueous solution with a mass fraction of 1.4%.
[0030] (4) the aqueous solution of step (3) gained is added dropwise in the polyferric sulfate with the speed of 0.1~1.0mL / min, makes the ratio of the iron quality in the polyferric sulfate and carboxymethyl potato starch quality be 1: 1, React for 60 minutes under ...
Embodiment 3
[0031]Example 3 Polymerized ferric sulfate-carboxymethyl potato starch composite flocculant, the flocculant is compounded by polyferric sulfate and carboxymethyl potato starch, wherein the ratio of iron quality in polyferric sulfate to carboxymethyl potato starch quality It is 3:1.
[0032] The preparation method of this polyferric sulfate-carboxymethyl potato starch composite flocculant comprises the following steps:
[0033] (1) Preparation of polyferric sulfate is the same as in Example 1.
[0034] (2) Prepare carboxymethyl potato starch with embodiment 1.
[0035] (3) 0.28 g of carboxymethyl potato starch was dissolved in 60 mL of distilled water to obtain an aqueous solution with a mass fraction of 0.5%.
[0036] (4) the aqueous solution of step (3) gained is added dropwise in the polyferric sulfate with the speed of 0.1~1.0mL / min, makes the ratio of the iron quality in the polyferric sulfate and carboxymethyl potato starch quality be 3: 1, React for 30 minutes under n...
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