Casting coated sand suitable for selective laser sintering forming and manufacturing method thereof

A technology of selective laser sintering and coated sand, which is applied to casting molding equipment, casting molds, manufacturing tools, etc., to achieve the effect of high blank strength, small gas generation, and good forming dimensional accuracy

Active Publication Date: 2012-02-08
SHENZHEN SUNSHINE LASER & ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, there are the following main problems in the casting coated sand material and its preparation method used in SLS forming at present: most of the rapid laser forming is still directly used (or slightly added Modification) The phenolic resin coated sand materials used in traditional casting methods, even if a small part of them are foundry coated sand materials developed for SLS forming characteristics, also generally have low strength of the laser sintered preform, which leads to laser sintered forming Parts are easily broken, damaged or missing during the powder cleaning and transfer process. The main reason is that the laser sintering process is different from traditional heating. It is a "rapid melting and rapid cooling" method. Under the action of this instantaneous heat, the layer The curing reaction of the phenolic resin at the local and interlayer joints is incomplete or has no cross-linking and curing at all, the degree of resin curing is not high, and even locally between the particles, there is still a bond that only depends on the softening of the resin, resulting in the initial failure of the SLS molded part. Billet strength is low
In addition, the coated sand mold (core) formed by laser sintering has a large amount of gas generation, which is easy to cause casting defects such as pores and shrinkage porosity, which directly limits the popularization and application of coated sand rapid prototyping
The main reason is that the amount of phenolic resin added in the coated sand for laser sintering is too large (all greater than 3%). At the same time, some additives in the coated sand, such as the commonly used lubricant: calcium stearate, can also easily cause Air volume increased

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Sieve spherical or very spherical pearl sand particles with a diagonal coefficient ≤ 1.1 to obtain a 70 / 270 mesh five-sieve sand with a main content of ≥90% and a dusting density of five-sieve sand of 2.01g / cm 3 ;

[0027] (2) pulverizing the solid thermoplastic phenolic resin into a uniform phenolic resin powder with a particle size of 60 μm;

[0028] (3) grinding the ammonium dihydrogen phosphate powder into a particle size of uniform ammonium dihydrogen phosphate fine powder of 50 μm;

[0029] (4) Prepare phenolic resin-coated sand by thermal coating method, wherein 1000g of the above-mentioned five-sieve sand, 12g of phenolic resin powder with a particle size of 60μm (the mass fraction of the five-sieve sand is 1.2%), coupling agent 0.12g (the addition amount accounts for 1% of the mass fraction of the phenolic resin powder, and is made into an aqueous solution with a mass fraction of 10%) and 1.44g of hexamethylenetetramine (the addition amount accounts for 12...

Embodiment 2

[0032] (1) Sieve spherical or very spherical pearl sand particles with a diagonal coefficient ≤ 1.1 to obtain a 70 / 200 mesh four-sieve sand with a main content of ≥85% and a dusting density of four sieve sands of 1.92g / cm 3 ;

[0033] (2) pulverizing the solid thermoplastic phenolic resin into a uniform phenolic resin powder with a particle size of 40 μm;

[0034] (3) grinding the ammonium dihydrogen phosphate powder into a uniform fine powder of ammonium dihydrogen phosphate with a particle size of 80 μm;

[0035] (4) Prepare phenolic resin-coated sand by thermal coating method, including 1000g of the above-mentioned four-sieve sand, 15g of phenolic resin powder with a particle size of 40μm (the mass fraction of the four-sieve sand is 1.5%), coupling agent 0.15g (the addition amount accounts for 1% of the mass fraction of the phenolic resin powder, and is made into an aqueous solution with a mass fraction of 10%) and 1.8g of hexamethylenetetramine (the addition amount accou...

Embodiment 3

[0038] (1) Sieve spherical or very spherical pearl sand particles with a diagonal coefficient ≤ 1.1 to obtain 100 / 270 mesh four-sieve sand with a main content of ≥ 85%, and the powder density of the four-sieve sand is 1.85g / cm3 ;

[0039] (2) pulverizing the solid thermoplastic phenolic resin into a uniform phenolic resin powder with a particle size of 20 μm;

[0040] (3) grinding the ammonium dihydrogen phosphate powder into a particle size of uniform ammonium dihydrogen phosphate fine powder of 30 μm;

[0041] (4) Prepare phenolic resin coated sand by thermal coating method, in which 2000g of the above-mentioned four-sieve sand, 36g of phenolic resin powder with a particle size of 20μm (the mass fraction of the four-sieve sand is 1.8%), coupling agent 0.36g (the addition amount accounts for 1% of the mass fraction of the phenolic resin powder, and is made into an aqueous solution with a mass fraction of 10%) and 5.04g of hexamethylenetetramine (the addition amount accounts f...

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Abstract

The invention discloses casting coated sand suitable for selective laser sintering forming and a manufacturing method thereof. The coated sand is made from roughing sands, an organic binder, an inorganic binder, a coupling agent and a curing agent, further, additives, such as a lubricant, a light absorber and the like are not required; and the roughing sand is spherical pearl sand with the angular coefficient less than or equal to 1.1, wherein the sand grains consist of adjacent four-sieve sands or five-sieve sands. The manufacturing method of the casting coated sand comprises the following steps of: sieving the roughing sands to obtained the required four-sieve sands or five-sieve sands; carrying out thermal coating on the roughing sands by using phenolic resin powder, the coupling agentand the curing agent according to a certain proportion so as to obtain phenolic resin coated sand; and evenly mixing monoammonium phosphate fine powder and the phenolic resin coated sand which are ina certain proportion to obtain the casting coated sand suitable for the selective laser sintering forming. The coated sand laser sintering forming part has high preform strength, good forming accuracy and little gas forming amount and can be applied to a casting sand mold (core) with an intricate structure in laser fast forming, therefore, the fast trial-production and the manufacturing capacity of intricate castings are enhanced.

Description

technical field [0001] The invention belongs to the field of advanced manufacturing technology, and in particular relates to casting coated sand suitable for area-selective laser sintering and a preparation method thereof. Background technique: [0002] Casting is one of the basic processes of modern machinery manufacturing industry and an important component of advanced manufacturing technology. Among them, the casting method of coated sand is a kind of precision sand casting (Precision-type Sand Casting), its dimensional accuracy is greatly improved, and the dimensional accuracy of ordinary sand castings can be improved from CT9-10 to CT6-7. The roughness is reduced to Ra<3.2-6.3μm. As the main body of the coated sand casting process, the coated sand material has attracted the attention of a large number of researchers and suppliers. At present, the developed and applied coated sand materials are all formed by pressing the mold to prepare the coated sand mold (core). ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22C1/00B22C1/02B22C1/22B22C1/18
Inventor 徐志锋余欢蔡长春熊博文杨伟梁培严青松卢百平朱佩兰
Owner SHENZHEN SUNSHINE LASER & ELECTRONICS TECH CO LTD
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