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Organic / inorganic composite layered compound containing ruthenium 535 dye and preparation method thereof

A layered compound, inorganic composite technology, applied in organic dyes, chemical instruments and methods, azo dyes, etc., can solve the problems of application limitation, difficult to arrange, limited effect, etc., to improve selectivity, improve catalytic efficiency, The effect of extending the scope of application

Inactive Publication Date: 2012-03-21
SHANGHAI UNIV
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  • Application Information

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Problems solved by technology

But since in those two-dimensional layered materials, organic molecules cannot be fixed regularly
Therefore, the effect of changing the inorganic layered nanospace environment through post-processing of organic molecules is very limited, and it is difficult to effectively control the arrangement of molecules in the layer space.
This greatly limits the application of these materials

Method used

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  • Organic / inorganic composite layered compound containing ruthenium 535 dye and preparation method thereof
  • Organic / inorganic composite layered compound containing ruthenium 535 dye and preparation method thereof
  • Organic / inorganic composite layered compound containing ruthenium 535 dye and preparation method thereof

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Embodiment 1

[0036] Embodiment one: Preparation of ruthenium 535 amide phenyl silica layered compound;

[0037] (1) Prepare p-aminophenyl silicon oxide-dodecylsulfate layered compound in advance; its preparation method is: first dissolve 2.88mmol of sodium laurylsulfate into 250ml of deionized water, then add 2.74mmol of p-aminophenyltrimethoxysilane, then slowly drop 0.5mol / L hydrochloric acid to adjust the pH value of the mixed solution to 2.07, and magnetically stir at room temperature for 12 days to carry out the sol-gel process; Washing with deionized water and ethanol, and drying in vacuum to obtain p-aminophenyl silicon oxide-dodecylsulfate layered structure compound;

[0038] In order to prove the chemical and three-dimensional structure of p-aminophenyl silica-dodecylsulfuric acid nanocomposite layered structure, a series of analytical experiments were carried out. Firstly, octaalkyl sulfate anion is used, and chloride anion carries out anion exchange reaction with p-aminopheny...

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Abstract

The invention relates to an organic / inorganic composite layered compound containing ruthenium 535 dye and a preparation method thereof. According to the invention, a synthesized organic / inorganic composite layered compound p-aminophenyl silicon oxide- dodecyl sulfuric acid layered compound with regular arranged amino and acylated ruthenium 535 are treated with amidation grafting reaction to finally obtain stable organic / inorganic composite layered compound containing ruthenium 535 dye, which is a ruthenium 535 amide phenyl silicon oxide layered compound. The novel organic / inorganic composite two-dimensional layered compound overcomes disadvantage of difficultly controlled layer space environment of existing montmorillonite and hydrotalcite layered materials; and ruthenium dye organometallic compound has good visible light response photoelectric physical properties. Development of synthesis of the organic / inorganic composite layered compounds containing ruthenium dye can substantially broaden application scope of ruthenium dye and develop series novel organic / inorganic composite layered compounds with various performances.

Description

technical field [0001] The invention relates to an organic / inorganic composite layered compound containing ruthenium 535 dye and a preparation method thereof. Background technique [0002] As we all know, nanomaterials science is the focus of the future development of materials science, and its research and development have a profound impact on various fields of chemistry. As an important part of nanomaterials, layered nanospace materials such as montmorillonite and hydrotalcite, due to their clear nanoscale space structure and stable physical and chemical properties, make them useful in catalytic chemistry, materials The fields of chemistry, electrochemistry and biochemistry are widely studied and applied. In the layered nanospace, functional inorganic or organic molecules can exist in the form of a monolayer, which is impossible to obtain in the macroscopic space, so it is possible to form composite materials with new properties and obtain all the properties in the macr...

Claims

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Application Information

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IPC IPC(8): C09B57/10
Inventor 黎慜姚建李聪邵雪袁坚上官文峰
Owner SHANGHAI UNIV
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