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Preparation method of magnetic rectorite/chitosan nano-grade composite material

A chitosan nano-composite material technology, applied in chemical instruments and methods, adsorbed water/sewage treatment, other chemical processes, etc., can solve the problem of poor separation of adsorbed substances, limited application of rectorite, limited adsorption, etc. problems, to achieve the effect of improving the reuse rate, good adsorption efficiency, and control of the preparation process

Inactive Publication Date: 2014-01-15
WUHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the hydrolysis of cations between rectorite layers, its adsorption is limited, and the separation effect of adsorbed substances is not good, which limits the application of rectorite in water treatment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of preparation method of magnetic rectorite / chitosan nano composite material, its steps are:

[0023] 1. Magnetic Fe 3 o 4 preparation of

[0024] 6.9g Fe 3 o 4 Dissolve with 75mL concentrated hydrochloric acid under the protection of nitrogen to form a yellow-brown transparent solution, add 2mL of surfactant Tween-80, and slowly add ammonia water dropwise under vigorous stirring. When the pH value is maintained at about 9, a large amount of black precipitates will form . Continue to stir for 15 minutes, then raise the temperature of the water bath to 80° C., and age at this temperature for 3 hours. After the reaction is completed, let it stand for precipitation at room temperature for 24 hours, and place the beaker containing the precipitation on a permanent magnet to accelerate the precipitation. Remove the supernatant, wash the precipitate with distilled water repeatedly for 3 times, then disperse the reactant in distilled water, then carry out magnetic s...

Embodiment 2

[0034] A kind of preparation method of magnetic rectorite / chitosan nano composite material, its steps are:

[0035] 1. Magnetic Fe 3 o 4 preparation of

[0036] 6.9g Fe 3 o 4 Dissolve with 75mL concentrated hydrochloric acid under the protection of nitrogen to form a yellow-brown transparent solution, add 2mL of surfactant Tween-80, and slowly add ammonia water dropwise under vigorous stirring. When the pH value is maintained at about 9, a large amount of black precipitates will form . Continue to stir for 15 minutes, then raise the temperature of the water bath to 80° C., and age at this temperature for 3 hours. After the reaction is completed, let it stand for precipitation at room temperature for 24 hours, and place the beaker containing the precipitation on a permanent magnet to accelerate the precipitation. Remove the supernatant, wash the precipitate with distilled water repeatedly for 3 times, then disperse the reactant in distilled water, then carry out magnetic s...

Embodiment 3

[0046] A kind of preparation method of magnetic rectorite / chitosan nano composite material, its steps are:

[0047] 1. Magnetic Fe 3 o 4 preparation of

[0048] 6.9g Fe 3 o 4 Dissolve with 75mL concentrated hydrochloric acid under the protection of nitrogen to form a yellow-brown transparent solution, add 2mL of surfactant Tween-80, and slowly add ammonia water dropwise under vigorous stirring. When the pH value is maintained at about 9, a large amount of black precipitates will form . Continue to stir for 15 minutes, then raise the temperature of the water bath to 80° C., and age at this temperature for 3 hours. After the reaction is completed, let it stand for precipitation at room temperature for 24 hours, and place the beaker containing the precipitation on a permanent magnet to accelerate the precipitation. Remove the supernatant, wash the precipitate with distilled water repeatedly for 3 times, then disperse the reactant in distilled water, then carry out magnetic s...

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Abstract

The invention discloses a preparation method of a magnetic rectorite / chitosan nano-grade composite material. The method comprises steps that: (1) Fe3O4 is dissolved in concentrated hydrochloric acid under the protection of nitrogen, such that a tawny transparent solution is formed; a surfactant is added to the solution, such that powdery nano-grade particles are prepared; (2) natural rectorite is soaked by using distilled water; dross is separated and removed; rectorite is soaked, and is subject to pump-filtration; and rectorite is calcined and activated in a muffle furnace; (3) a chitosan solution is dissolved in a dilute weak acid solution, such that a chitosan solution is prepared; (4) magnetic rectorite is synthesized, wherein the magnetic Fe3O4 suspension solution is directly added into a 3-neck flask containing a rectorite suspension solution; the mixture is centrifuged, and is separated by pump-filtration, such that magnetic rectorite is obtained; (5) chitosan is added for carrying out modification regulation upon the magnetic rectorite; the mixture is dried, such that magnetic rectorite / chitosan is obtained. The preparation method is advantaged in simple technology, controllable preparation procedure, and low cost. The obtained material is advantaged in good crystallinity and high purity. When the material is used in waste water processing, a good absorption effect is provided.

Description

technical field [0001] The invention relates to a magnetic composite adsorption material, more specifically to a preparation method of a magnetic rectorite / chitosan nanocomposite material, which can be used for adsorption and magnetic separation to remove heavy metal ions in water, and can be used for actual wastewater treatment. Background technique [0002] Rectorite belongs to mica-montmorillonite regular interlayer minerals. This structural feature determines that it has expandability in the vertical direction and large internal and external areas, so that it has a large interlayer spacing. Therefore, it has certain adsorption properties for heavy metal cations in water. Rectorite mineral has the advantages of large specific surface area, strong surface activity and adsorption performance, high cation exchange performance, and cheap and easy to obtain. It is widely used as a new type of mineral adsorption material. However, due to the hydrolysis of interlayer cations of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L5/08C08K9/00C08K3/22C08K3/34B01J20/24B01J20/30C02F1/28
Inventor 周培疆李世迁
Owner WUHAN UNIV