Method for industrially and continuously producing crystalline urea
A urea and crystal technology, applied in urea compound fertilizer, agriculture, nitrogen fertilizer, etc., can solve the problems of strong hygroscopicity, inconvenient use, easy moisture absorption, etc., achieve the effects of not easy to absorb moisture, easy to purchase raw materials, and improve production efficiency
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Embodiment 1
[0034] (1) Dissolve ultrapure water and urea in 10 reaction kettles at a molar ratio of 1:1.5, each reaction kettle is heated by heat conduction oil partition heating method, and the heating temperature of the reaction kettle is controlled at 60°C, keeping The reaction solution was stirred continuously to make it heated evenly.
[0035] (2) When heating until the urea is nearly dissolved completely, directly add industrial sulfuric acid with a volume concentration of 98% to adjust the pH=4, and keep until the urea dissolves completely.
[0036] (3) The solution in the reaction kettle is evenly heated, and finally melts into a saturated urea slurry. The slurry is discharged from the lower outlet of the reaction kettle to the crystallizer, and when it is cooled to 45°C by the cooling system, it is fully stirred evenly, and finally cooled to room temperature After obtaining urea crystals, after solid-liquid separation, the solution can be temporarily stored in the mother liquor t...
Embodiment 2
[0038] (1) Dissolve urea and ultrapure water in 5 reactors at a molar ratio of 1:1.8, and each reactor is heated by a heat transfer oil partition heating method, and the heating temperature of the reactor is controlled at 80°C. The reaction solution was stirred continuously to make it heated evenly.
[0039] (2) When heating until the urea is almost completely dissolved, directly add zinc sulfate solution to adjust the pH value to 6.5, and keep until the urea is completely dissolved.
[0040] (3) The solution in the reaction kettle is evenly heated, and finally melts into a saturated urea slurry. The slurry is discharged from the lower outlet of the reaction kettle to the crystallizer, and when it is cooled to 45°C by the cooling system, it is fully stirred evenly, and finally cooled to room temperature After obtaining urea crystals, after solid-liquid separation, the solution can be temporarily stored in the mother liquor tank, and then circulated back to the reactor; the sep...
Embodiment 3
[0042] (1) Put ultrapure water and urea into 6 reaction kettles according to the molar ratio of 1:2 to dissolve respectively, each reaction kettle is all dissolved in the reaction kettle, adopt steam heating method to heat the reaction kettle, and the reaction kettle heating temperature is controlled at 80°C, keep stirring the reaction solution to make it heated evenly.
[0043] (2) When heating until the urea dissolves completely, directly add industrial phosphoric acid with a volume concentration of 85% to adjust the pH=5, and keep until the urea dissolves completely.
[0044] (3) The solution in the reaction kettle is evenly heated, and finally melts into a saturated urea slurry. The slurry is discharged from the lower outlet of the reaction kettle to the crystallizer, and when it is cooled to 45°C by the cooling system, it is fully stirred evenly, and finally cooled to room temperature After obtaining urea crystals, after solid-liquid separation, the solution can be tempor...
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