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Graphene band prepared with acid oxidized flat carbon nano-tube and method for preparing graphene band

A carbon nanotube and graphene technology, applied in the field of graphene strips and their preparation, can solve problems such as difficult directional cutting, lack of special defect sites, etc., and achieve the effects of simple method, easy realization and control, and narrow width.

Inactive Publication Date: 2012-07-25
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, it is difficult to form regular graphene strips by the physical and chemical tailoring graphene approach used, and it is also difficult to obtain regular graphene strips by acid oxidation or plasma cutting methods using carbon nanotubes as raw materials, because The carbon nanotubes used are all circular tubes with uniform structure and lack of special defect sites, so it is difficult to cut them into regular graphene strips

Method used

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  • Graphene band prepared with acid oxidized flat carbon nano-tube and method for preparing graphene band
  • Graphene band prepared with acid oxidized flat carbon nano-tube and method for preparing graphene band
  • Graphene band prepared with acid oxidized flat carbon nano-tube and method for preparing graphene band

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Embodiment 1

[0028] Example 1: Carbon nanotube fibers are prepared according to the method reported in patent CN101665997A, and the flat carbon nanotube fibers are formed by connecting and arranging flat carbon nanotubes. The flat carbon nanotubes prepared by the above-mentioned patented method are used as raw materials, and the microstructure is a stack of flat carbon nanotubes, as shown in the attached figure 1 . Using concentrated sulfuric acid as a pre-oxidant and potassium permanganate as an oxidant, carbon tube flat carbon nanotubes were cut by acid oxidation to prepare graphene strips. The oxidation conditions are as follows: the mass ratio of concentrated sulfuric acid to flat carbon nanotubes is 6, and the mass ratio of potassium permanganate to flat carbon nanotubes is 4. Add flat carbon nanotubes into concentrated sulfuric acid (98%), 60 ° C water bath, 200 rpm magnetic stirring for 30 minutes; add potassium permanganate, keep stirring at 60 ° C for 90 minutes for oxidation; ad...

Embodiment 2

[0030] Embodiment 2: experimental process is the same as embodiment 1, changes the mass ratio of concentrated sulfuric acid and oxidant potassium permanganate and carbon tube, the mass ratio of concentrated sulfuric acid and flat carbon nanotube is 3, the mass ratio of potassium permanganate and flat carbon nanotube The mass ratio is 2 to prepare graphene strips.

Embodiment 3

[0031] Embodiment 3: experimental process is the same as embodiment 1, changes the mass ratio of concentrated sulfuric acid and oxidizer potassium permanganate and carbon tube, the mass ratio of concentrated sulfuric acid and flat carbon nanotube is 7.5, the mass ratio of potassium permanganate and flat carbon nanotube Mass ratio is 5, makes graphene strip, as attached Figure 6 .

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Abstract

The invention relates to a graphene band prepared with an acid oxidized flat carbon nano-tube and a method for preparing the graphene band. The method includes the specific and main steps: preliminarily oxidizing a carbon nano-tube with acid; oxidizing the carbon nano-tube with strong oxidizers; adding water for hydrolysis; adding hydrogen peroxide for purification; and preparing the graphene band after washing and drying. The acid oxidized flat carbon nano-tube is precisely, directionally and longitudinally cut along the edge of the acid oxidized flat carbon nano-tube, so that the regular and uniform high-quality graphene band is prepared. The method is simple and convenient, is easy to implement and control, and can be used for directional cutting in a wide temperature range and under various oxidization conditions, and preparing the graphene band on a large scale. The prepared graphene band is uniform, regular and narrow, has uniform layers and neat edges, and can be applied to composite materials, conductive and heat conducting materials, sensors, electronic circuits, micro-nano devices and related fields.

Description

technical field [0001] The invention relates to a graphene strip prepared by acid oxidation of flat carbon nanotubes and a preparation method thereof, in particular to the preparation of graphene strip material and its preparation method by directional cutting of flat carbon nanotubes by acid oxidation, which belongs to nanomaterial preparation technology field. Background technique [0002] Graphene ribbons are nanometer-wide graphene materials, typically containing 1 to 10 layers of graphite. Graphene ribbons have a unique two-dimensional layered nanostructure, high strength, high electrical conductivity, high thermal conductivity, and at the same time have semiconductor properties sensitive to one-dimensional nanoribbon structures, for example, narrow graphene ribbons (less than 10nm) Exhibiting semiconducting properties, the broad strips can be transformed into conductors. These excellent structural, mechanical, physical and semiconductor properties of graphene strips ...

Claims

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Application Information

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IPC IPC(8): C01B31/04B82Y40/00C01B32/168C01B32/184
Inventor 李亚利康艳茹邓岷阳
Owner TIANJIN UNIV
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