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Method of preparing polrvinyl chloride/polyether sulfone/cellulose derivative blend membrane

A technology of cellulose derivatives and polyvinyl chloride, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve problems such as strong hydrophobicity, achieve hydrophilicity adjustable, good chemical stability and Heat resistance, large flux effect

Inactive Publication Date: 2013-04-03
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the material of polyethersulfone membrane also has the disadvantage of strong hydrophobicity.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) The mass fractions were 10% polyvinyl chloride, 5.5% polyethersulfone, 4% cellulose acetate, 3% nano-zinc oxide, and 77.5% solvent N,N-dimethyl Acetamide is put into the Erlenmeyer flask, placed in a water bath with a constant temperature of 80°C and stirred until completely dissolved, then left to stand and defoamed for subsequent use;

[0028] (2) Keep the temperature of the clean glass plate, scraper and film casting solution consistent, scrape out a flat film with a thickness of 200 μm on the glass plate, pre-evaporate for 20 seconds, and then immerse in a water bath at 20°C to solidify to form a film;

[0029] (3) After the film falls off, it is taken out of the water bath, fully washed with distilled water, soaked to remove the solvent remaining in the film, and dried at low temperature after pore-preserving treatment to obtain the finished film.

[0030] The water flux measured by the membrane under wet conditions is 900L / (m at 0.15MPa 2 .h), the contact ang...

Embodiment 2

[0032] (1) The mass fractions were 12% polyvinyl chloride, 6% polyethersulfone, 2% cellulose acetate, 2% nano-silicon oxide, and 78% solvent N,N-dimethyl Acetamide is put into the Erlenmeyer flask, placed in a water bath with a constant temperature of 80°C and stirred until completely dissolved, then left to stand and defoamed for subsequent use;

[0033] (2) Keep the temperature of the clean glass plate, the scraper and the casting liquid at the same temperature, scrape out a flat film with a thickness of 200 μm on the glass plate, pre-evaporate for 30 seconds, and then immerse in a water bath at 10°C to solidify to form a film;

[0034] (3) After the film falls off, it is taken out of the water bath, fully washed with distilled water, soaked to remove the solvent remaining in the film, and dried at low temperature after pore-preserving treatment to obtain the finished film.

[0035] The water flux measured by the membrane under wet conditions is 600L / (m at 0.15MPa 2 .h), th...

Embodiment 3

[0037] (1) The mass fractions were 5% polyvinyl chloride, 12% polyethersulfone, 1% cellulose acetate, 2% nano-titanium dioxide, and 80% solvent N,N-dimethyl Acetamide is put into the Erlenmeyer flask, placed in a water bath with a constant temperature of 80°C and stirred until completely dissolved, then left to stand and defoamed for subsequent use;

[0038] (2) Keep the temperature of the clean glass plate, scraper and casting solution consistent, scrape out a flat film with a thickness of 200 μm on the glass plate, pre-evaporate for 5 seconds, and then immerse in a water bath at 30°C to solidify to form a film;

[0039] (3) After the film falls off, it is taken out of the water bath, fully washed with distilled water, soaked to remove the solvent remaining in the film, and dried at low temperature after pore-preserving treatment to obtain the finished film.

[0040] The water flux measured by the membrane under wet conditions at 0.15MPa is 410L / (m 2 .h), the contact angle o...

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Abstract

The invention relates to a method of preparing a polrvinyl chloride / polyether sulfone / cellulose derivative blend membrane. The method comprises the steps: (1) mixing polrvinyl chloride, polyether sulfone, cellulose derivative and nanometer additives to be added into a solvent, heating and stirring for 3-6 hours under the condition of 60-90 DEG C, standing, and defoaming to obtain casting film liquid; and (2) paving a layer of casting film liquid with a scraper, preevaporating for 5-30seconds, then dipping into a coagulating bath of 10-30 DEG C for forming the membrane, washing, soaking and drying to obtain the polrvinyl chloride / polyether sulfone / cellulose derivative blend membrane. The blend membrane is large in flux, good in mechanical property, adjustable in hydrophilcity, low in membrane preparation cost, and better in chemical stability and heat resistance; and the blend membrane prepared can be applied to the fields of sewage treatment, purification of tap water plants, recycling of reclaimed water, food and biopharming and the like, and has good application prospects.

Description

technical field [0001] The invention belongs to the field of preparation of blended membranes, in particular to a preparation method of polyvinyl chloride / polyethersulfone / cellulose derivative blended membranes. Background technique [0002] Membrane separation technology is a new type of high separation, concentration, purification and purification technology. Its appearance has solved the problems of traditional water treatment technology in the treatment of wastewater. Compared with traditional water treatment technologies, membrane separation technology has the advantages of low energy consumption, continuous operation at room temperature, high separation efficiency, no secondary pollution, and low operating costs. Therefore, membrane separation technology has been widely used in wastewater treatment. application and has broad prospects. [0003] Ultrafiltration membrane is one of many membrane separation technologies, and industrialized production was realized in the 1...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/30B01D71/68B01D71/12B01D67/00B01D69/02
Inventor 王军陈高升李玉龙吴俊蒋淑红
Owner DONGHUA UNIV