Pulverized Anthracite modifying agent and coal blending and coking method using same

A coking technology of anthracite coal powder and coal blending, which is applied in the field of anthracite coal powder modifiers and coal blending coking, can solve the problems of poor coke quality and unsatisfactory coke, and achieve reduced coking costs, significant economic benefits, and saving coking coal resources Effect

Active Publication Date: 2013-04-17
CHONGQING LUNIU TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if the addition of anthracite is further increased in coal blending, the quality of the produced coke is poor and cannot meet the needs of large and medium-sized blast furnaces.
At present, under the coking oven type and process conditions widely used in our country, there is no good solution for the extensive use of anthracite coking

Method used

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  • Pulverized Anthracite modifying agent and coal blending and coking method using same
  • Pulverized Anthracite modifying agent and coal blending and coking method using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Preparation of anthracite coal powder modifier: make coal powder modifier in the amount of 1kg, boric acid accounts for 60% of the weight of coal powder modifier in acidic substances, α-alanine 10%; Dialkyl dimethyl benzyl ammonium chloride accounts for 5% of the weight of the coal powder modifier, cationic cellulose polymer accounts for 10%; 10% by weight, and calcium-based bentonite accounts for 5% by weight of the coal powder modifier, which is ground and mixed uniformly;

[0035] Anthracite pulverized coal modification: take 0.4 kg of the above-mentioned pulverized coal modifier (accounting for 0.4‰ of the weight of the coking coal blend), and 50 kg of anthracite (accounting for 5% of the weight of the coking blend coal), and put them into a reformer with an automatic heating device Fully mix, react, and modify, the temperature in the modifier is controlled at 35°C, and the reaction time is 20 minutes;

[0036] Coal blending and coking: Take 50 kg of the above-ment...

Embodiment 2

[0039] The preparation of anthracite coal powder modifier: make coal powder modifier with the amount of 2kg, boric acid accounts for 55% of coal powder modifier weight, malonic acid 10%, azelaic acid 5% in acidic substance; Dodecyl dimethyl benzyl ammonium chloride accounts for 10% of the weight of the coal powder modifier, and cationic cellulose polymer accounts for 6% of the weight of the coal powder modifier; dicyclohexyl phthalate accounts for 6% of the weight of the coal powder 10% of the weight of the coal powder modifier, calcium-based bentonite accounts for 4% of the weight of the coal powder modifier, put into a ball mill and mix evenly through ball milling;

[0040] Anthracite pulverized coal modification: Take 2 kg of the above-mentioned pulverized coal modifier (accounting for 2‰ of the weight of the coking coal blend), and 100 kg of anthracite (accounting for 10% of the weight of the coking blend coal), and put them into the reformer with an automatic heating devic...

Embodiment 3

[0044] Preparation of anthracite coal powder modifier: make coal powder modifier in the amount of 5kg, boric acid accounts for 50% of coal powder modifier weight, azelaic acid accounts for 2%, a-alanine accounts for 10% of the weight of the coal powder modifier in acidic substances %; in surface active substances, dodecyl dimethyl benzyl ammonium chloride accounts for 8% of the weight of coal powder modifier, cationic cellulose polymer accounts for 5%, sodium stearate lactate accounts for 5%; plasticizer substances Dicyclohexyl phthalate accounts for 7% of the weight of the coal powder modifier, triphenyl phosphate 10%; calcium-based bentonite 3%, put into a ball mill, ball mill, and mix evenly;

[0045] Anthracite pulverized coal modification: Take 5 kg of the above-mentioned pulverized coal modifier (accounting for 5‰ of the weight of coking coal blend), 150 kg of anthracite (accounting for 15% of the weight of coking blend coal), and put them into the reformer with automatic...

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Abstract

The invention relates to a pulverized anthracite modifying agent and a coal blending and coking method using the same. The pulverized anthracite modifying agent comprises the components in percentage by weight: 30-60 percent of boric acid, 0.5-25 percent of malonic acid or azelaic acid or alpha-alanine or a mixture of the malonic acid or the azelaic acid or the alpha-alanine, 0.5-25 percent of dodecyl dimethyl benzyl ammonium chloride or cationic cellulose polymer or stearic acid sodium lactate or a mixture of two or three of the dodecyl dimethyl benzyl ammonium chloride or the cationic cellulose polymer or the stearic acid sodium lactate, and 0.5-25 percent of dicyclohexyl phthalate or triphenyl phosphate or a mixture of the dicyclohexyl phthalate or the triphenyl phosphate. The coal blending and coking method comprises the steps of: step 1. modifying anthracite; and step 2. weighing the modified anthracite and coking coal according to 1-50 percent of the mass of coking mixed coal, and blending the coal for coking according to a conventional production technology. The coal blending and coking method has the advantages that the proportion of the anthracite in the coking mixed coal is obviously increased, and the coking cost is substantially reduced. The coal blending and coking method provides a new approach for coking by using the anthracite and expands the resources of the coking coal.

Description

technical field [0001] The invention belongs to the field of coal processing, and in particular relates to an anthracite coal powder modifier and a coal blending coking method using the coal powder modifier. Background technique [0002] In 2012, the production capacity of iron and steel reached 700 million tons, and the demand for coking coal was 600 million tons. Domestic coking coal is far from meeting the needs of the rapid development of the metallurgical industry, and more than 45 million tons of coking coal need to be imported every year. The contradiction between increasingly higher coke quality requirements and worse coal quality has become increasingly prominent. Importing high-priced coal can only solve the short-term dilemma. The development of non-coking coal resources and coking is one of the important ways to expand coking coal resources. [0003] According to domestic and foreign literature records, my country's proven reserves of anthracite coal are nearly 1...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10B57/06
Inventor 朱慧强
Owner CHONGQING LUNIU TECH
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