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Anti-freezing emulsified asphalt and preparation method thereof

A technology for emulsified asphalt and frost resistance, which is applied in building components, building insulation materials, buildings, etc., can solve the problems of adding trouble to the structural design of mixer trucks, affecting the properties of emulsified asphalt, inconvenient production and transportation, etc. Improvement of residual quantity index, cement mixability index, improvement of long-term storage performance

Active Publication Date: 2015-05-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process of preparing mortar is carried out in a mixer truck, which is an intermittent operation. Due to the small amount of defoamer and water reducer, it is difficult to control the measurement accurately, and even if it is stirred quickly, the distribution of the two in the mortar It is also difficult to be uniform. Once the measurement is wrong or the distribution is uneven, it will affect the properties of the mortar. The main performance is that the defoaming is not complete. When the mortar is poured, more air bubbles will be accumulated under the four corners of the track plate. Insufficient strength of the corners
In addition, in order to make the high-iron emulsified asphalt mixed with a large amount of cement and fine sand not to be demulsified during high-speed stirring, and to have a certain strength against mechanical damage, generally when producing high-iron emulsified asphalt, the amount of surfactant will be If the emulsified asphalt is very large, it is easy to produce a large amount of foam during the production and loading of high-speed rail emulsified asphalt, occupying a large space in the product tank. If the operation is not done properly, the emulsified asphalt foam will easily emerge from the tank mouth, which will cause inconvenience to production and transportation.
In addition, if the foam of the emulsified asphalt is too much, a thick skin will be formed after the foam disappears. This skin is formed by linking the asphalt components on the foam after the foam disappears, and it can no longer be emulsified even if it is stirred. , so it will affect the properties of emulsified asphalt, especially the index of remaining amount on the sieve, and even easily lead to the demulsification of emulsified asphalt
In addition, adding defoamer and water reducing agent at the construction site is cumbersome, which affects the construction progress and adds trouble to the structural design of the mixer truck

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Take 6750g of Liaohe crude oil straight-run asphalt with a penetration of 108 (1 / 10mm), heat it to 115°C for later use; take 50g of cationic emulsifier cetyltrimethylammonium chloride, anionic emulsifier fat (18) Alcohol polyoxyethylene (3) ether sodium sulfate 50 g, zwitterionic emulsifier N-cocoyl-β-alanine sodium 10 g, nonionic emulsifier oleyl alcohol polyoxyethylene (20) ether 10 g, chlorine Dissolve 5 g of calcium chloride together in 3033 g of water not lower than 45°C, stir well, prepare soap and keep the temperature at 45°C for later use; take 1 g of methyl silicone oil (303-20), 10 g of calcium lignosulfonate g, 80 g of isopropanol, after mixing evenly, slowly add 1 g of carboxymethyl cellulose under stirring state, fully stir to make a paste for later use. Then the above-mentioned hot asphalt, soap liquid, and paste are transported to the colloid mill, and after being uniformly dispersed and ground by the colloid mill, it becomes an oil-in-water emulsion, and...

Embodiment 2

[0038] Take 6000g of Oman crude oil solvent deoiled bitumen from Maoming Petrochemical Company with a penetration of 98 (1 / 10mm), and heat it to 125°C for later use; take 90g of cationic emulsifier hydrogenated tallow-based propylene triamine, anionic emulsifier fat (1 ) amine polyoxyethylene (4) sodium sulfate 195g, zwitterionic emulsifier N-tallow-β-iminodipropionate disodium 69 g, nonionic emulsifier octylphenol polyoxyethylene (20) ether 50g, 15g of ammonium chloride, dissolved in 3371g of water at 65°C, stirred well, prepared into soap liquid and kept at 65°C for later use; take 5g of polyoxyethylene oxypropylene glycerin (GPE30), condense with naphthalenesulfonic acid formaldehyde 40 g of carboxyethyl cellulose, 60 g of ethanol, and 100 g of tert-butanol were mixed evenly, and 5 g of carboxyethyl cellulose was slowly added under stirring, and fully stirred to make a paste for later use. Then the above-mentioned hot asphalt, soap liquid, and paste are transported to the c...

Embodiment 3

[0040] Take 5550g of Kuwait crude oil oxidized bitumen from Qilu Petrochemical Company with a penetration of 62 (1 / 10mm), and heat it to 155°C for later use; take 195g of cationic emulsifier aminated lignin (RH-CO1) emulsifier, anionic emulsifier Sodium lauryl sulfate 125 g, zwitterionic emulsifier N-lauryl-β-alanine 40 g, non-ionic emulsifier lauryl polyoxyethylene (20) ether 40 g, magnesium chloride 25 g, dissolved in 3550 g of In water at 55°C, stir well, prepare soap liquid and keep the temperature at 55°C for later use; take 3g of high-carbon alcohol fatty acid ester (C18, concentration 30wt%), 69g of sulfonated melamine formaldehyde condensate, 400g of propanol, fully After mixing evenly, slowly add 3 g of hydroxyethyl cellulose under stirring state, and stir well to make a paste for later use. Then the above-mentioned hot asphalt, soap liquid, and paste are transported to the colloid mill, and after being uniformly dispersed and ground by the colloid mill, it becomes an...

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PUM

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Abstract

The invention discloses an anti-freezing emulsified asphalt and a preparation method thereof. A formula of the emulsified asphalt comprises asphalt, an anionic emulsifier, a cationic emulsifier, a thickener, a stabilizer, a water reducing agent, alcohol and water. The method provided by the invention comprises steps of: dissolving the water reducing agent and the thickener in alcohol at room temperature to prepare a paste, and adding a defoaming agent into the paste; and then participating the paste in the emulsion as a whole. The paste is combined with the cationic emulsifier and the anionic emulsifier emulsifier, so as to reduce usage amount and cost of emulsifier, and obviously improve sieve residue, storage stability, cement miscibility and frost resistance of the emulsified asphalt.

Description

technical field [0001] The invention relates to a frost-resistant emulsified asphalt and a preparation method thereof, in particular to a special frost-resistant emulsified asphalt for cement asphalt mortar and a preparation method thereof. The emulsified asphalt of the present invention is used for pouring cement asphalt mortar (abbreviated as CA mortar) into slab ballastless tracks when building high-speed railways. Background technique [0002] With the improvement of the level of railway construction and the requirements for railway transport capacity, it is necessary to build high-speed railways and urban light rails. In order to improve the stability of trains running at high speed and reduce the noise caused by vibrations when trains are running, slab ballastless track technology is adopted. The slab ballastless track technology is to lay two tracks on a reinforced concrete slab (called track slab), and a 3-5cm thick shock-absorbing layer needs to be laid under the tr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L95/00C08J3/03C04B26/26
Inventor 陈保莲张静范思远陈闯
Owner CHINA PETROLEUM & CHEM CORP
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