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Acid swelling treatment method of sheep hide

A sheepskin, acid swelling technology, applied in chemical treatment before tanning, small raw hide/large raw hide/leather/fur treatment, small raw hide/large raw hide/leather hide/fur chemical treatment, etc. High quality thin, light and soft sheep fur, reducing wool strength and warmth retention, weakening elastic fibers, etc., to achieve a good basis for industrial production, improve wearing comfort, and reduce weight.

Active Publication Date: 2014-10-22
SICHUAN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the fur cannot be subjected to alkali expansion, because the use of alkali expansion will cause a large area of ​​hair loss
On the other hand, alkali can cause great damage to the wool cover. The main component of sheep wool is keratin, and alkali can hydrolyze keratin, which will reduce the strength and warmth retention of wool
The second is enzymatic softening, which weakens the role of elastic fibers and arrector pili muscles in the skin tissue structure, and separates loose collagen fibers, but the controllability is poor. If the treatment is too light, the effect of loose skin collagen fibers cannot be achieved, and the hand feels stiff; If it is too heavy, the collagen will be overly hydrolyzed, hair loss, skin plate delamination and other phenomena will appear, and it is difficult to achieve the expected effect
[0004] To sum up, the existing technology cannot achieve sufficient and moderate separation and loosening of the collagen fibers of sheep skin, so it is impossible to produce high-quality thin, light and soft sheep fur, and another method must be found

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] (1) Acid swelling process: The sheepskin after standardization water soaking and degreasing is placed in the groove, and the weight is 100 parts; the temperature is room temperature, add 1000 parts of water, add 2 parts of formic acid, paddle for 30min, and then paddle 10min, stop 50min, paddle 10min, stop 50min, paddle 10min, stop 50min, paddle 10min, stop 50min, let stand overnight, the total acid swelling time is 18h;

[0024] (2) De-expansion process: place the acid-expanded sheepskin in a groove, and weigh 100 parts of the sheepskin after soaking and degreasing; the temperature is room temperature, add 1,000 parts of water, 2 parts of sodium acetate, and add chlorine 20 parts of sodium chloride, stroke for 30 minutes, then stroke for 10 minutes, stop for 50 minutes, stroke for 10 minutes, stop for 50 minutes, stroke for 10 minutes, stop for 50 minutes, stroke for 10 minutes, stop for 50 minutes, stand overnight, and control the de-inflation time at 18 hours.

Embodiment 2

[0026] (1) Acid swelling process: The sheepskin after standardization water soaking and degreasing is placed in a groove, and the weight is 100 parts; the temperature is normal temperature, 1500 parts of water are added, 6 parts of acetic acid are added, and 40 minutes are drawn, and then 10min, stop 50min, paddle 10min, stop 50min, paddle 10min, stop 50min, paddle 10min, stop 50min, let stand overnight, the total acid swelling time is 24h;

[0027] (2) De-expansion process: put the acid-expanded sheepskin in a groove, and weigh 100 parts of the sheepskin after soaking and degreasing; the temperature is room temperature, add 1500 parts of water, add 6 parts of sodium formate, and add chlorinated 80 parts of sodium, stroke for 40min, then stroke for 10min, stop for 50min, stroke for 10min, stop for 50min, stroke for 10min, stop for 50min, stroke for 10min, stop for 50min, stand overnight, and control the de-swelling time at 24h.

Embodiment 3

[0029] (1) Acid swelling process: The sheepskin after standardized water immersion and degreasing is placed in the groove, and the weight is 100 parts; the temperature is normal temperature, 2500 parts of water, 8 parts of citric acid are added, and the plan is 60 minutes. Move 10min, stop 50min, stroke 10min, stop 50min, stroke 10min, stop 50min, stroke 10min, stop 50min, let stand overnight, the total acid swelling time is 36h;

[0030] (2) De-expansion process: place the acid-expanded sheepskin in a groove, and take the weight of the sheepskin after soaking and degreasing as 100 parts; the temperature is normal temperature, add 2500 parts of water, add 8 parts of sodium citrate, add 150 parts of sodium chloride, paddle for 60min, then paddle for 10min, stop for 50min, paddle for 10min, stop for 50min, paddle for 10min, stop for 50min, paddle for 10min, stop for 50min, stand overnight, and control the de-swelling time at 36h.

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PUM

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Abstract

The invention discloses a sheep leather acid swelling treatment method. The method comprises a step of acid swelling and a step of de-swelling, wherein the acid swelling is carried out in an acidic swelling liquid, and the swelling is uniform and appropriate without hair dropping or excess leather loss; and the de-swelling is carried out in a de-swelling liquid, the de-swelling effect is very good, and a state before swelling can be completely recovered. Collagen fibers can be effectively loosened and elastic fibers and muscle tissues are digested to a certain degree through the acid swelling treatment. Compared with fur prepared through routine methods, fur prepared through the method disclosed in the invention has the advantages of obviously improved softness and fullness, elasticity, nearly 3-time improvement of the tensile strength, 20% reduction of the unit mass, obviously improved shrinkage temperature, and elimination of the sheep fur layering phenomenon. All the performance indexes of finished sheep fur accord with the Light Industry Standard of the PRC (QB / T1280-1991), and the finished sheep fur also has the characteristics of thinness, lightness, and softness.

Description

technical field [0001] The invention belongs to the field of fur inventions. Background technique [0002] Sheep fur has good warmth retention and practicality, and is widely used as coat liner, seat cushion, winter hat lining, and fur coat, etc. Especially after special processing, it can be imitated into other valuable furs, but the price is relatively low, and it is widely loved by the public. With the improvement of people's consumption level and the continuous development of the fur industry, people's requirements for sheep fur are not limited to warmth and cold protection, but more attention is paid to wearing comfort and functionality, such as the lightness, softness, lightness and natural warmth of fur. Fur products that are good but very heavy, inconvenient to carry, or have no special function are no longer popular. (See Liu Lan, Populus euphratica, Dan Weihua, etc., The Functional Effects of Leather and Fur, "China Leather", 2012, 41 (5): 44) Compared with the p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C14C1/08
Inventor 但卫华刘萌王建宇但年华王祎刘付江
Owner SICHUAN UNIV