Self-diverting agent for heterogeneous carbonate rock acidizing system

A carbonate rock and self-steering agent technology, which is applied in the preparation of organic compounds, organic chemistry, and drilling compositions, can solve problems such as poor system stability, reduced effective action distance, and increased injection pressure. Mild conditions, simple synthesis process, good high temperature resistance effect

Inactive Publication Date: 2013-05-08
YANGTZE UNIVERSITY
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the acidizing process of heterogeneous carbonate reservoirs, according to the principle of minimum permeability resistance, conventional acids such as gelled acid, emulsified acid, and cross-linked acid first enter the higher permeability layer, and it is difficult to enter the microscopic layer of the low permeability layer. The cracks and pores cause a large amount of acid fluid to be lost and quickly consumed, the effective distance of action is reduced, and the effect of acidification to increase production is not ideal; Injection pressure
At the same time, due to the superiority of conventional acid only in viscosity, it is more viscous, and

Method used

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  • Self-diverting agent for heterogeneous carbonate rock acidizing system
  • Self-diverting agent for heterogeneous carbonate rock acidizing system
  • Self-diverting agent for heterogeneous carbonate rock acidizing system

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[0018] The present invention will be further described below in conjunction with specific embodiments:

[0019] 1. Preparation of erucamide tertiary amine:

[0020] Add 0.3 mol of erucic acid to a clean and dry three-necked flask, connect the oil bath device and the reflux device, slowly heat until the erucic acid is completely dissolved, add 0.33 mol of 3-dimethylaminopropylamine and 15 g of water-carrying agent xylene in turn; stir for 30 3~5 minutes after seconds N 2 Then use a constant pressure dropping funnel to add 2g catalyst KOH dropwise, adjust the reaction temperature to 140°C, stir and react for 7 hours, take it out, immediately vacuumize it under reduced pressure, remove impurities, and cool to obtain the erucic acid amido tertiary amine.

[0021] 2. Preparation of erucamide propyl betaine:

[0022] Weigh 0.3 mol of the prepared erucamide tertiary amine; weigh 0.36 mol of sodium chloroacetate and prepare it into a 20% sodium chloroacetate solution. Use sodium bicarbonate t...

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Abstract

The invention relates to a self-diverting agent for a heterogeneous carbonate rock acidizing system. The self-diverting agent is characterized by: taking erucic acid as an initiator, adding 3-dimethylaminopropylamine to make them undergo a reaction under oil bath conditions and under the action of a water carrying agent dimethylbenzene and a catalyst KOH; subjecting the reacted mixed solution to pressure reduced vacuum pumping and cooling, thus obtaining erucamide tertiary amine; mixing the erucamide tertiary amine with a sodium chloroacetate solution and leaving them to react under water bath conditions; dissolving the reacted mixed solution in an acetone solution, conducting cooling to room temperature, and carrying out standing and pumping filtration so as to obtain erucamidopropyl betaine, i.e. the self-diverting agent for the heterogeneous carbonate rock acidizing system involved in the invention. Along with the progression of an acid-rock reaction, the acid solution system prepared in the invention can realize automatic viscosity change to generate high flow resistance, thus realizing effective distribution of the acid solution in a reservoir. The self-diverting agent has the characteristics of reducing acid solution filter loss, increasing the acid solution penetration distance, and ensuring effective self-diverting of the acid solution system.

Description

Technical field: [0001] The invention relates to a self-steering agent for heterogeneous carbonate rock acidification system, which belongs to the technical field of oil field chemical agent design. Background technique: [0002] For now, acidizing is still one of the most widely used stimulation measures for oil and gas reservoirs. In the acidizing process of heterogeneous carbonate reservoirs, according to the principle of minimum permeability resistance, conventional acids such as gelled acid, emulsified acid, and cross-linked acid first enter the higher permeability layer, and it is difficult to enter the microscopic layer of the low permeability layer. The cracks and pores cause a large amount of acid fluid to be lost and quickly consumed, the effective distance of action is reduced, and the effect of acidification to increase production is not ideal; Injection pressure. At the same time, conventional acid only shows superiority in viscosity, which is characterized by...

Claims

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Application Information

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IPC IPC(8): C07C233/38C07C231/12C09K8/76
Inventor 马超赵林徐良伟
Owner YANGTZE UNIVERSITY
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