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Nickel-niobium intermediate alloy and preparation method thereof

A master alloy and nickel-niobium technology, which is applied in the field of nickel-niobium master alloy and its preparation, can solve the problems of difficult separation of residues and alloy ingots, high nitrogen and oxygen content of the alloy, and low product purity, etc. Low content and good controllability

Active Publication Date: 2015-07-08
METALINK SPECIAL ALLOYS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The melting point of pure niobium bars in the prior art is 2467°C, which is too high to be conducive to industrial production. In addition, the current production of alloy materials does not strictly control the raw materials and reaction environment, resulting in low purity of the product, and the reaction process produces The residue and the alloy ingot are not easy to separate, so that the nitrogen and oxygen content in the alloy is high, resulting in low purity

Method used

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  • Nickel-niobium intermediate alloy and preparation method thereof
  • Nickel-niobium intermediate alloy and preparation method thereof
  • Nickel-niobium intermediate alloy and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1: The mass percent of a kind of nickel-niobium master alloy material is as table 1: table 1

[0020]

[0021] A preparation method of a nickel-niobium master alloy material, comprising the following steps:

[0022] 1) Selection and analysis of raw materials: The raw materials are niobium pentoxide, nickel oxide, aluminum powder, sodium chlorate and the purity control of the furnace charge is shown in Table 2:

[0023] Table 2

[0024]

[0025] 2) Raw material pretreatment: Put the raw material into a drying oven and dry it at 350°C (±20°C) for 24 hours.

[0026] 3) Preparation of alumina furnace barrel: Mix alumina and binder with a certain particle size ratio evenly, knot them into shapes, and place them in a drying furnace to bake and sinter, and the baked alumina furnace barrel is cooled to 300 The temperature below ℃ is ready for use, and the storage time of the alumina furnace barrel in the air should not exceed 24 hours.

[0027] 4) Mixing: We...

Embodiment 2

[0044] The mass percent of a kind of nickel niobium master alloy material is as table 6:

[0045] Table 6

[0046]

[0047] A kind of preparation method of nickel niobium master alloy material is basically the same as embodiment 1, difference is as follows:

[0048] 1. Process conditions: Table 7

[0049] raw material baking temperature

350℃(±20℃)

raw material baking time

24 hours

Mixing time

15 minutes

Charge temperature

65℃

Reaction time

2 minutes

cooling time

40 hours

Alloy ingot weight

150.5㎏

Broken particle size

10~30㎜

[0050] 2. Formula: Table 8

[0051] raw material

Weight (㎏)

Niobium pentoxide

140

Nickel oxide

74.5

Aluminum powder

70

sodium chlorate

4

Return charge

0

[0052] 3. Reaction situation: the reaction is intense, the recovery rate of niobium: 95.16%, and the recovery rate of nickel: 94.13%. ...

Embodiment 3

[0057] The mass percent of a kind of nickel-niobium master alloy material is shown in Table 10:

[0058] Table 10

[0059]

[0060] A kind of preparation method of nickel niobium master alloy material is basically the same as embodiment 1, difference is as follows:

[0061] 1. Process conditions are shown in Table 11:

[0062] Table 11

[0063] raw material baking temperature

350℃(±20℃)

raw material baking time

24 hours

Mixing time

15 minutes

Charge temperature

68℃

Reaction time

1 minute 35 seconds

cooling time

40 hours

Alloy ingot weight

156.3㎏

Broken particle size

10~30㎜

[0064] 2. The formula is shown in Table 12:

[0065] Table 12

[0066] raw material

Weight (㎏)

Niobium pentoxide

145

Nickel oxide

70.2

Aluminum powder

73.5

sodium chlorate

3.3

Return charge

4

[0067] 3. Reaction situation: the reaction i...

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Abstract

The invention discloses a nickel-niobium intermediate alloy material which comprises the following components in percentage by mass: 60-70% of niobium, 26.5-36.5% of nickel, less than or equal to 1.5% of aluminum, less than or equal to 0.1% of oxygen, less than or equal to 0.05% of nitrogen, less than or equal to 0.3% of silicon, less than or equal to 0.01% of phosphorus, less than or equal to 1% of iron, less than or equal to 0.2% of tantalum, less than or equal to 0.1% of titanium, less than or equal to 0.005% of lead, less than or equal to 0.005% of tin, less than or equal to 0.05% of carbon, less than or equal to 0.01% of sulfur and the balance being impurities. The invention further discloses a preparation method of the nickel-niobium intermediate alloy material. By utilizing the nickel-niobium intermediate alloy, the temperature of smelting of a niobium-nickel base containing alloy is greatly decreased; as strict raw material control is adopted during the preparation of the nickel-niobium intermediate alloy, the prepared product has high purity, low impurity content, good controllability; the prepared alloy using the nickel-niobium intermediate alloy has low alloy nitrogen oxygen content and is purer; and the production efficiency is high.

Description

technical field [0001] The invention relates to the field of metal materials, in particular to a nickel-niobium master alloy and a preparation method thereof. Background technique [0002] The melting point of pure niobium bars in the prior art is 2467°C, which is too high to be conducive to industrial production. In addition, the current production of alloy materials does not strictly control the raw materials and reaction environment, resulting in low purity of the product, and the reaction process produces The residue and the alloy ingot are not easy to separate, so that the nitrogen and oxygen content in the alloy is high, resulting in low purity. [0003] With the development of science and technology, more and more niobium elements are added to improve the performance of special alloy materials. For example, nickel-based superalloys are the most widely used and highest high-temperature strength alloys among superalloys. It not only has good high temperature oxidation ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C27/02C22C1/03C22B5/04
Inventor 陈道华蔡柯金马步洋王浩冰
Owner METALINK SPECIAL ALLOYS CORP