Polyurethane heat insulation foaming material and preparation method thereof

A technology of thermal insulation and foaming materials, applied in the field of polyurethane materials, can solve the problems that the foaming agent is not an environmentally friendly foaming agent, loses thermal insulation performance, does not specify the type of foaming agent, thermal insulation performance, mechanical properties, and flame retardant properties.

Active Publication Date: 2013-12-25
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

CN101130629A discloses a foaming polyurethane, expanded perlite composite building energy-saving material and on-site spraying construction technology, but the particle size range of perlite used in it is relatively large, which is 1-4 mm, and the added mass is 3-5 mm of the polyurethane reaction raw material. times, and did not specify the type of blowing agent used, the thermal insulation properties, mechanical properties, and flame retardant properties that the material can achieve
[0011] CN102531467A discloses a foamed polyurethane, expanded perlite composite thermal insulation and flame-retardant board and its preparation method, but the foaming agent used is not an environmentally friendly foaming agent, and the obtained polyurethane foam has a high thermal conductivity of 24 ~42mW/m·K, lost the excellent thermal insulation performance of polyur...

Method used

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  • Polyurethane heat insulation foaming material and preparation method thereof
  • Polyurethane heat insulation foaming material and preparation method thereof

Examples

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Embodiment

[0040] Step 1: Dry the polyether polyol, isocyanate and expanded perlite at 40°C for 8 hours, and place at room temperature for use.

[0041]The second step: according to the formula of Example 1-6 in Table 1, add the expanded perlite with an average particle size of 0.06 to 0.8 mm into the polyether polyol after weighing according to the formula, and add flame retardant and catalyst according to the formula , Foam stabilizer, stir fully with a mechanical stirring device, mix evenly, then add the physical foaming agent HFC-365mfc, use a mechanical stirring device to fully stir, mix evenly; quickly add isocyanate to the mixed components, and fully stir at the same time, 30 After ~50 seconds, it is poured into a mold and foamed freely to obtain a pouring mold blank. React with the mold at 40°C for 40 minutes, remove the mold, and then put it into an oven for aging at 50-100°C for more than 6 hours to obtain the product.

[0042] With the two steps of above-mentioned embodiment ...

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Abstract

The invention discloses a polyurethane heat insulation foaming material and a preparation method thereof. The polyurethane heat insulation foaming material comprises the following components in parts by weight: 100 parts of polyether polyol, 150-170 parts of polymethylene polyphenyl isocyanate, 5-30 parts of expanded perlite, 20-40 parts of a physical foaming agent, 10-15 parts of a flame retardant, 1-3 parts of a catalyst and 1.5-10 parts of a foam stabilizer. The density of hard polyurethane foams prepared by the preparation method is smaller than 65Kg/m<3>, the thermal conductivity is smaller than 21mW/m.K, the compressive strength is greater than 0.42MPa, the compression modulus is greater than 14MPa, and the oxygen index is more than or equal to 23, so that the polyurethane heat insulation foaming material is suitable for the field of heat insulation.

Description

technical field [0001] The invention belongs to the technical field of polyurethane materials, and in particular relates to a polyurethane thermal insulation foaming material and a preparation method thereof. Background technique [0002] Rigid polyurethane foam has become an irreplaceable thermal insulation material due to its low thermal conductivity, and is widely used in construction, aerospace, transportation, chemical and other fields. [0003] With the prohibition of the use of CFCs (that is, chlorofluorocarbons) blowing agents and the restriction of the use of HCFCs (that is, hydrofluorochlorocarbons) blowing agents, blowing agents with zero ODP (that is, Ozone Depression Potential ozone depletion potential) have become a research hotspot , commonly used blowing agents with zero ODP such as water, supercritical CO 2 , Pentane and HFCs etc. [0004] The disadvantage of pentane blowing agent is that it is flammable, and the mixture with air will explode under certain...

Claims

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Application Information

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IPC IPC(8): C08G18/76C08G18/48C08G18/24C08K7/26C08K5/521C08J9/14
Inventor 张子男周凝康丁张洪斌
Owner SHANGHAI JIAO TONG UNIV
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