High-temperature-resisting lacquered wire lacquer composition based on modified polyaryletherketone and preparation method thereof
A polyaryletherketone, enameled wire paint technology, applied in the direction of polyether coatings, coatings, etc., can solve the problem of poor solubility of polyaryletherketone, and achieve the effect of high heat resistance
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Embodiment 1
[0029] 30 grams of sulfonated polyetheretherketone (structure: Molecular weight: 121803; glass transition temperature is 163°C; 5% thermal weight loss temperature is 408°C. Zhang Pei, Synthesis and Properties of Modified Polyaryletherketone, Doctoral Dissertation of Beijing Institute of Technology, 2010. ) into 70 ml of N-methylpyrrolidone, dissolved at 90°C, stirred for 30 minutes to form a solution, then added 0.3 g of low molecular weight acrylic acid copolymer; 0.5 g of polyethylene wax was added to 90°C, 20 ml of xylene until completely dissolved, then mix the sulfonated polyether ether ketone solution with the xylene solution of polyethylene wax, add 10 ml of n-butanol, and keep stirring at 90°C for 3 hours. Use cold water at 30°C to quickly reduce the temperature of the emulsion to 45°C through internal and external circulation cooling to obtain the wire enamelled paint.
[0030] The solid content of the wire enamelled paint prepared in this example is 25%, and the r...
Embodiment 2
[0032] 40 grams of nitropolyether ether ketone ketone (structure: Molecular weight: 116284; glass transition temperature is 145°C; 5% thermal weight loss temperature is 255°C. Zhang Pei, Synthesis and Properties of Modified Polyaryletherketone, Doctoral Dissertation of Beijing Institute of Technology, 2010. ) into 90 ml of N,N-dimethylformamide, dissolved at 30°C, stirred for 50 minutes to form a solution, then added 1 gram of silicone polymer and 5 grams of polyester wax, and added 10 ml of toluene after complete dissolution , and kept stirring at 30°C for 3 hours to obtain wire enamelled paint.
[0033] The solid content of the wire enamel prepared in this example is 34%, and the rotational viscosity at 25° C. is 3500 mPas.
Embodiment 3
[0035] 57 grams of fluorinated polyetheretherketone (structure: Molecular weight: 7923; glass transition temperature is 125°C; 5% thermal weight loss temperature is 506°C. Pei Zhang, Yun Zhao, Xinliang Tang, Qingze Jiao.Synthesis and Characterization of Fluorine-containing Poly(ether ether ketone)s,Chemical Research in Chinese Universities,2010,26(4):672-674; Synthesis and properties of aryl ether ketone, doctoral dissertation of Beijing Institute of Technology, 2010. ) into a mixture of 65 ml of N-methylpyrrolidone and 5 ml of isopropanol, dissolved at 50°C, stirred for 30 minutes to form a solution, then added 3 g of polyamide wax and 0.5 g of polyether-modified polysiloxane, completely After dissolving, 15 ml of toluene was added, and stirred at 50° C. for 3 hours. Use cold water at 30°C to quickly reduce the temperature of the emulsion to 45°C through internal and external circulation cooling to obtain the wire enamelled paint.
[0036] The solid content of the wire en...
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