A kind of preparation method of cathode layer of solid polymer electrolytic capacitor
An electrolytic capacitor and solid polymer technology, applied in solid electrolytic capacitors, capacitor electrodes, capacitor parts and other directions, can solve the problems of different thicknesses of polymer films, reduce the equivalent series resistance of solid polymer electrolytic capacitors, etc. Reduce cross-contamination and eliminate thin and thick effects
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preparation example Construction
[0025] The present invention provides a kind of preparation method of cathode layer of solid polymer electrolytic capacitor, in one embodiment, comprising:
[0026] The anode body of the solid polymer electrolytic capacitor is alternately immersed in the monomer liquid and the oxidation liquid, the solvent in the monomer liquid can dissolve the oxidant in the oxidation liquid, and the solvent in the oxidation liquid can dissolve the monomer in the monomer liquid body, the anode body includes an anode base body and an anode lead-out end drawn from the anode base body, and the barrier material is coated or worn on the anode lead-out end at a position ≤0.5 mm away from the shoulder of the anode base body, Among them, 0 is not taken, that is, there is a certain gap between the barrier material and the shoulder of the anode substrate;
[0027] Each immersion in the oxidizing solution includes two immersions, including the following steps: During the first immersion, the anode body ...
Embodiment 1
[0042] The anode body includes a tantalum block and a lead-out end drawn from the tantalum block, and a Teflon pad is placed on the lead-out end at a position 0.2mm away from the shoulder of the tantalum block to prevent liquid from entering the lead-out end. Alternately immerse the monomer liquid and the oxidizing liquid, wherein the oxidizing agent in the oxidizing liquid is iron p-toluenesulfonate, the dopant is p-toluenesulfonic acid and the solvent is ethanol, and in the oxidizing liquid, the mass concentration of the oxidizing agent is 60% , the mass concentration of the dopant is 0.5%, the monomer in the monomer liquid is 3,4-ethylenedioxythiophene, the solvent is a mixture of ethanol and butanol in any proportion, in the monomer liquid, 3,4-ethylenedioxythiophene The mass concentration of thiophene was 4%. Specifically: immerse the anode body completely in the oxidizing solution, take it out after 5 minutes, and let it dry for 3 minutes in an environment with humidity ...
Embodiment 2
[0044] The difference from Example 1 is that the solvent of the oxidizing agent in the oxidizing solution is a mixture of ethanol and butanol in any ratio, and the drying conditions of the oxidizing agent are: 25°C / 10min→50°C / 10min→70°C / 15min→120°C / 5min, the anode The height of 0.2 mm from the bottom of the body was immersed in the monomer liquid. In this example, the number of alternations is 12, and after every 3 alternations, the product is cleaned with ion exchange cleaning equipment.
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