A kind of preparation method of cathode layer of solid polymer electrolytic capacitor

An electrolytic capacitor and solid polymer technology, applied in solid electrolytic capacitors, capacitor electrodes, capacitor parts and other directions, can solve the problems of different thicknesses of polymer films, reduce the equivalent series resistance of solid polymer electrolytic capacitors, etc. Reduce cross-contamination and eliminate thin and thick effects

Active Publication Date: 2016-08-24
SHENZHEN SUNLORD ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to make up for the deficiencies of the above-mentioned prior art, and propose a method for preparing the cathode layer of a solid polymer electrolytic capacitor, which can greatly reduce the cross-contamination that exists in the process of immersing the oxidizing solution and the monomer solution And it solves the problem of different thickness of the polymer film, which can effectively reduce the equivalent series resistance of the solid polymer electrolytic capacitor

Method used

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Examples

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preparation example Construction

[0025] The present invention provides a kind of preparation method of cathode layer of solid polymer electrolytic capacitor, in one embodiment, comprising:

[0026] The anode body of the solid polymer electrolytic capacitor is alternately immersed in the monomer liquid and the oxidation liquid, the solvent in the monomer liquid can dissolve the oxidant in the oxidation liquid, and the solvent in the oxidation liquid can dissolve the monomer in the monomer liquid body, the anode body includes an anode base body and an anode lead-out end drawn from the anode base body, and the barrier material is coated or worn on the anode lead-out end at a position ≤0.5 mm away from the shoulder of the anode base body, Among them, 0 is not taken, that is, there is a certain gap between the barrier material and the shoulder of the anode substrate;

[0027] Each immersion in the oxidizing solution includes two immersions, including the following steps: During the first immersion, the anode body ...

Embodiment 1

[0042] The anode body includes a tantalum block and a lead-out end drawn from the tantalum block, and a Teflon pad is placed on the lead-out end at a position 0.2mm away from the shoulder of the tantalum block to prevent liquid from entering the lead-out end. Alternately immerse the monomer liquid and the oxidizing liquid, wherein the oxidizing agent in the oxidizing liquid is iron p-toluenesulfonate, the dopant is p-toluenesulfonic acid and the solvent is ethanol, and in the oxidizing liquid, the mass concentration of the oxidizing agent is 60% , the mass concentration of the dopant is 0.5%, the monomer in the monomer liquid is 3,4-ethylenedioxythiophene, the solvent is a mixture of ethanol and butanol in any proportion, in the monomer liquid, 3,4-ethylenedioxythiophene The mass concentration of thiophene was 4%. Specifically: immerse the anode body completely in the oxidizing solution, take it out after 5 minutes, and let it dry for 3 minutes in an environment with humidity ...

Embodiment 2

[0044] The difference from Example 1 is that the solvent of the oxidizing agent in the oxidizing solution is a mixture of ethanol and butanol in any ratio, and the drying conditions of the oxidizing agent are: 25°C / 10min→50°C / 10min→70°C / 15min→120°C / 5min, the anode The height of 0.2 mm from the bottom of the body was immersed in the monomer liquid. In this example, the number of alternations is 12, and after every 3 alternations, the product is cleaned with ion exchange cleaning equipment.

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Abstract

The invention discloses a method for preparing a cathode layer of a solid polymer electrolytic capacitor. The anode body of a solid polymer electrolytic capacitor is alternately immersed in a monomer liquid and an oxidizing liquid. The solvent in the monomer liquid can dissolve the oxidizing agent in the oxidizing liquid, and the oxidizing liquid The solvent in the monomer solution can dissolve the monomer in the monomer liquid. The anode body includes the anode base and the anode lead-out end drawn from the anode base. On the anode lead-out end, the distance from the shoulder of the anode base ≤ 0.5mm is coated or worn with a barrier material; Each dip in the oxidizing solution is dipped twice, and the part is dried after the first immersion. When dipping the monomer solution each time, the anode body is partially immersed, taken out from the monomer solution and then dipped in the oxidizing solution or taken out from the oxidizing solution and then dipped in the monolithic solution. Before removing body fluid, the anode body is dried at a stepwise gradient temperature and then cooled to room temperature. The method can greatly reduce the cross-contamination that exists when immersing the oxidizing solution and the monomer solution, solves the problem of uneven thickness of the polymer film, and can effectively reduce the ESR of the product.

Description

technical field [0001] The invention relates to a method for manufacturing a solid polymer electrolytic capacitor, in particular to a method for preparing a cathode layer of a solid polymer electrolytic capacitor. Background technique [0002] With the rapid development of technology, people have higher and higher requirements for the safety of capacitors. Traditional solid electrolytic capacitors use semiconductor materials (such as manganese dioxide) as cathode materials. The failure mechanism is: due to the large equivalent series resistance of traditional solid electrolytic capacitors, when the leakage current increases, the capacitor generates a lot of heat, resulting in two Manganese oxide degrades to release oxygen, which burns in contact with tantalum metal, which may easily cause flash fire or explosion of the product. However, when conductive polymers such as polythiophene, polypyrrole, polyaniline and their derivatives are used as cathode materials, a large amoun...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/04H01G9/15
Inventor 曾台彪齐兆雄吴维芬祁发安
Owner SHENZHEN SUNLORD ELECTRONICS
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