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Method for continuously plating nickel on conductive metal band material

A non-metal and strip technology, applied in the direction of plating tank, etc., can solve the problems of difficult to achieve industrialized production, continuous reduction of PH, etc., and achieve the effect of improving performance, stabilizing plating current density, and stabilizing plating area.

Inactive Publication Date: 2014-03-26
WUZHOU HGP ADVANCED MATERIALS TECH CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Chinese patent ZL97104463.5 "Technology for Continuous Manufacturing of Coiled Foamed Metal Strips" proposes the use of insoluble anodes for the electroplating of conductive non-metallic strips, but this method fails to solve the problem caused by the continuous generation of sulfuric acid in the nickel plating process. The problem of continuous reduction of PH, therefore, it is difficult for this patented technology to realize the industrial production of large-scale continuous nickel plating

Method used

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  • Method for continuously plating nickel on conductive metal band material
  • Method for continuously plating nickel on conductive metal band material

Examples

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Effect test

Embodiment 1

[0040] Example 1 : Conductive non-metal strip continuous nickel plating

[0041] (1) Insoluble anodes are used, the solution containing nickel ions is used as the source of nickel for nickel plating, and the electrolytic cell is separated into an anode chamber and a cathode chamber by a diaphragm to form an electrolytic cell with an independent anode chamber structure, except for the independent anode chamber in the electrolytic cell The space outside is the cathode chamber, and the anode chamber is provided with a solution outlet directly outside the electrolytic cell; the diaphragm is a non-metallic fiber woven cloth. figure 1 shown;

[0042] (2) Connect the beginning of the continuous strip of conductive polyurethane sponge with a width of 1020mm and a thickness of 1.8mm into the electrolytic tank in advance, and connect it to the transmission device and the conductive device; the conductive treatment method of the conductive non-metallic strip is electroless plating Law...

Embodiment 2

[0048] Example 2 : Conductive non-metal strip continuous nickel plating

[0049] (1) Use insoluble anodes, use the solution containing nickel ions as the nickel source for nickel plating, and use a diaphragm to separate the electrolytic cell into an anode chamber and a cathode chamber to form an electrolytic cell with an independent cathode chamber structure, except for the independent cathode chamber in the electrolytic cell The outer space is the anode chamber, and the anode chamber is provided with a solution outlet directly outside the electrolytic cell; the diaphragm is selected from non-metallic fiber braids; the solution outlet of the anode chamber directly outside the electrolytic cell is an overflow port at the upper part of the anode chamber; its structure Schematic such as figure 2 shown;

[0050] (2) Connect the beginning of the continuous strip of conductive polyurethane sponge with a width of 1020mm and a thickness of 1.8mm into the electrolytic tank in advan...

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Abstract

The invention relates to a method for continuously plating nickel on a conductive metal band material. An insoluble anode is adopted, and a solution containing nickel ions is used as a nickel source for plating the nickel. The method comprises the following steps: (1), separating an electrolytic bath into an anode compartment and a cathode compartment by a diaphragm, and forming a solution outlet which is directly communicated with the outside of the electrolytic bath in the anode compartment; (2), conveying the fresh or regenerated solution first into the cathode compartment and then into the anode compartment through the diaphragm, and then promoting the solution to flow out of the electrolytic bath from the solution outlet of the anode compartment; (3), regenerating the solution which flows out of the electrolytic bath from the solution outlet of the anode compartment in the step (2) by one or a mixture of two or more of nickel carbonate, nickel subcarbonate, nickel hydroxide and nickel oxide; using nickel chlorinate or a previously prepared thick nickel chlorinate solution to regenerate, and adding a proper quantity of reductant in the regenerating process. The conductive metal band material which is prepared by the method for continuously plating the nickel on the conductive metal band material, which is provided by the invention is directly prepared from nickel salt through deep processing and has a high added value, and metal is uniformly distributed in the conductive metal band material which is suitable for industrial production.

Description

technical field [0001] The invention relates to a nickel plating method, in particular to a continuous nickel plating method for conductive non-metallic strips. Background technique [0002] In the technical field to which the present invention belongs, the current known technologies are divided into two types, one is a soluble anode nickel plating technology, and the other is an insoluble anode (DSA or inert anode) nickel plating technology. [0003] Soluble anode nickel plating technology uses electrolytic nickel or metallic nickel as the anode and nickel source for nickel plating. The anode is continuously dissolved into nickel ions and enters the solution during the nickel plating process. At the same time, the cathode (plated strip) near the surface The nickel ions in the solution are reduced to nickel atoms and complete the electrodeposition or electrocrystallization process on the surface of the cathode to form a nickel layer. The overall effect of soluble anode nick...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D7/06C25D5/54C25D17/02
Inventor 朱彦文穆俊江吴天和区柱石桑康西
Owner WUZHOU HGP ADVANCED MATERIALS TECH CORP