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Solar blind type organic-inorganic composite ultraviolet detector

An inorganic composite, ultraviolet light technology, applied in the field of detectors, can solve the problems of increasing the contact probability, unfavorable device working for a long time, etc., to avoid interference and achieve the effect of selective response

Active Publication Date: 2014-04-02
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the transparent metal electrode is used as the counter electrode and the light is incident from this side, although the detection range of the device can be extended to the wavelength band below 300nm, in order to increase the transmittance of the electromagnetic wave below 300nm in the transparent metal electrode layer as much as possible, it is generally necessary to The transparent metal electrode layer is made very thin, which greatly increases the contact probability between the active layer material in the detector and the water and oxygen in the external environment, which is not conducive to the long-term work of the device, which requires the design of a new device structure
At the same time, if the device is to achieve intrinsic solar-blind ultraviolet response, it is necessary to strictly limit the bandgap width of the active layer material.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The quartz substrate was ultrasonically washed with detergent, isopropanol, ethanol, and acetone in sequence for 5 minutes, then rinsed with deionized water and dried. A layer of metal aluminum with a thickness of 2 nm was vacuum-deposited on the quartz substrate. After UV-ozone treatment, a PEDOT:PSS (polyaniline derivative) electrode modification layer with a thickness of about 40 nm was prepared by spin coating, and baked at 120 °C. Remove after 15 minutes of baking. D (R is pyrazine) was chosen as the donor material, and sodium tantalate (particle size 3 nm) was chosen as the acceptor material A. First, D with a thickness of about 30 nm was prepared by spin coating on PEDOT:PSS, and then A with a thickness of about 20 nm was prepared by solution spin coating on the D film. The above two layers constitute an organic-inorganic composite of a planar heterojunction structure. active layer. Finally, 1 nm thick LiF and 100 nm thick aluminum electrodes were sequentially ...

Embodiment 2

[0023] The quartz substrate was ultrasonically washed with detergent, isopropanol, ethanol, and acetone in sequence for 5 minutes, then rinsed with deionized water and dried. A layer of metallic silver with a thickness of 20 nm was vacuum-deposited on the quartz substrate. After UV-ozone treatment, a PEDOT:PSS (polyaniline derivative) electrode transmission layer with a thickness of about 40 nm was prepared by spin coating, and baked at 120 °C. Remove after 15 minutes of baking. D (R is pyridine) was chosen as the donor material, and sodium tantalate (particle size 30 nm) was chosen as the acceptor material A. A mixed film with a thickness of about 70 nm was prepared by solution spin coating on PEDOT:PSS. The weight ratio of donor material D:acceptor material A in the mixed film was 95:5, forming an organic-inorganic structure with a bulk heterojunction structure. Composite active layer. Finally, 1 nm thick LiF and 200 nm silver electrodes were prepared sequentially by vacuu...

Embodiment 3

[0025] The quartz substrate was ultrasonically washed with detergent, isopropanol, ethanol, and acetone in sequence for 5 minutes, then rinsed with deionized water and dried. A layer of silver / aluminum mixture with a thickness of 15 nm was vacuum-deposited on a quartz substrate, and after UV-ozone treatment, a PEDOT:PSS (polyaniline derivative) electrode modification layer with a thickness of about 40 nm was prepared by spin coating at 120°C Remove after 15 minutes of baking. D (R is pyrimidine) was chosen as the donor material, and sodium tantalate (particle size 10 nm) was chosen as the acceptor material A. First, D with a thickness of about 30 nm was prepared by vacuum evaporation on PEDOT:PSS, and then A with a thickness of about 30 nm was prepared by solution spin coating on the D film. The above two layers constitute a planar heterojunction structure. - Inorganic composite active layer. Finally, 1 nm thick LiF and 300 nm gold electrodes were prepared sequentially by va...

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Abstract

The invention discloses a solar blind type organic-inorganic composite ultraviolet detector, which comprises a quartz substrate, a transparent metal electrode layer, an electrode modifying layer, an organic-inorganic composite active layer, a cathode modifying layer, and a metal electrode layer, wherein the transparent metal electrode layer, the electrode modifying layer, the organic-inorganic composite active layer, the cathode modifying layer, and the metal electrode layer are sequentially arranged on the quartz substrate from bottom to top; the organic-inorganic composite active layer is a mixing layer of organic donor material D and inorganic receptor material A, or an organic donor material layer D and an inorganic receptor material layer A which are arranged in an overlapping way. The molecular structural formula of the organic donor material layer D is shown in the figure, wherein R is pyridine, pyrazine, pyrimidine, pyridazine, triazine or triazole. The detector has the advantages that the carrier mobility of ultrawide bandgap organic donor material is improved, the selective response on the radiation with wavelength less than 300nm is realized, and the absorbing of the common ITO substrate on the radiation with wavelength less than 300nm is greatly avoided.

Description

technical field [0001] The invention relates to a detector, in particular to a solar-blind organic-inorganic composite ultraviolet light detector. technical background [0002] In the process of solar ultraviolet radiation passing through the atmosphere, due to the strong absorption of oxygen atoms in the thermosphere and ozone in the stratosphere, only ultraviolet rays in the 300-400nm band can reach the near-surface space (below 25,000 meters), resulting in There is almost no ultraviolet radiation in the 0-300nm band in the atmosphere, which is the so-called "solar blind zone"; while the ultraviolet rays reaching the surface form a uniform ultraviolet background due to the scattering of the atmosphere, which is called the "visible blind zone". In view of the advantages of the "solar blind area" ultraviolet signal with a clean surface background, no interference from sunlight, and light signal processing burden, the detection (reception) of the "solar blind area" ultraviole...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/42H01L51/46
CPCY02E10/549H10K85/30H10K30/82H10K30/30
Inventor 吴刚陈红征汪茫
Owner ZHEJIANG UNIV