Novel corrosion and scale inhibitor and preparation method thereof

A technology of corrosion and scale inhibitor, corrosion inhibitor, applied in chemical instruments and methods, descaling and water softening, water/sludge/sewage treatment, etc. Efficiency, pipe string corrosion and other issues, to achieve the effect of preventing scaling

Active Publication Date: 2014-04-16
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although antiscalants used in oil fields can effectively reduce the formation of scales, generally antiscalants are acidic reagents, and acidic reagents will corrode the pipe string, and the large amount of ions in the formation water will also corrode the pipe string, which will seriously Affect the service life of the pipe string and the production efficiency of the oil field

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] This example provides a new type of corrosion and scale inhibitor, which contains corrosion inhibitor, scale inhibitor and hydroxyethylidene diphosphonic acid in a mass ratio of 0.5:80:10.

[0023] The preparation method of above-mentioned novel corrosion and scale inhibitor specifically comprises the following steps:

[0024] 1, the preparation of corrosion inhibitor, it may further comprise the steps:

[0025] Step 1: Slowly add diethylenetriamine to the uniformly dissolved oleic acid containing 10mL water-carrying agent and 0.5g zeolite, the molar ratio of oleic acid and diethylenetriamine is 1:1.1, stir at 160°C, and carry out 2h acylation reaction, then heated up to 220°C, stirred, and cyclization reaction was carried out for 6h to obtain the imidazoline intermediate;

[0026] Step 2: Cool the imidazoline intermediate to 70°C, stir, add a quaternization reagent to the imidazoline intermediate, the molar ratio of the imidazoline intermediate to the quaternization r...

Embodiment 2

[0037] This example is based on the novel corrosion and scale inhibitor described in Example 1 and its preparation method. Corrosion inhibitors, scale inhibitors and Hydroxyethylidene diphosphonic acid, the preparation steps given in Example 1 were carried out under the same conditions to prepare a new type of corrosion and scale inhibitor, as the control group 1 and control group 2 of Example 1.

Embodiment 3

[0039] The new corrosion and scale inhibitors prepared in Example 1, control group 1 and control group 2 were evaluated for their corrosion and scale inhibition performance.

[0040] Corrosion inhibitor performance evaluation

[0041] Referring to the Petroleum and Natural Gas Industry Standard of the People's Republic of China SY / T5273-2000 "Evaluation Method for the Performance of Corrosion Inhibitors for Oilfield Produced Water", the new corrosion and scale inhibitors prepared in Example 1, Control Group 1 and Control Group 2 were tested by the classic weight loss method Evaluation of corrosion inhibition performance.

[0042] The experimental method includes the following steps:

[0043] Prepare the formation water samples of the simulated oil production site. Under the conditions of normal pressure and 45°C constant temperature, put the previously treated test piece (N80 steel piece) into the constant temperature formation water sample solution to be tested. The amount o...

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Abstract

The invention provides a novel corrosion and scale inhibitor and a preparation method thereof. The novel corrosion and scale inhibitor comprises a corrosion inhibitor, a scale inhibitor and etidronic acid with the mass ratio of (0.1-1):(1-90):(0.1-10), wherein the corrosion inhibitor is a compounded corrosion inhibitor and comprises the following raw materials: oleic acid, diethylenetriamine, a quaternary ammonium reagent, and a compound; the compounded corrosion inhibitor is prepared by the following steps: obtaining imidazoline intermediates through the reaction between the oleic acid and diethylenetriamine; reacting with the quaternary ammonium reagent and obtaining an imidazoline quaternary ammonium salt corrosion inhibitor; finally, adding the compound and compounding to obtain the compounded corrosion inhibitor. The invention further provides the preparation method of the corrosion and scale inhibitor. The novel corrosion and scale inhibitor provided by the invention has the function of inhibiting corrosion and scale simultaneously and can effectively solve the problem of oilfield water scaling in the field of oil fields.

Description

technical field [0001] The invention relates to a novel corrosion and scale inhibitor and a preparation method thereof, belonging to the technical field of petroleum exploitation and environmental protection materials. Background technique [0002] In the field of oilfields, the essence of scaling is that the oilfield water becomes supersaturated, and one of the salts can no longer dissolve. Scaling occurs. Scaling in oilfield water often causes problems such as stuck oil well pumps, blocked annulus between well pipes and sucker rods, sharply reduced inner diameters of gathering and transportation pipelines, and even severe blockages, seriously affecting oilfields. Production is going on as normal. [0003] At present, the methods of controlling oilfield water scaling can be mainly divided into chemical methods and physical methods. Chemical antiscaling methods include ion exchange softening method, lime softening method, acid addition method, CO 2 Method, adding antiscal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
Inventor 张群王浩郑猛周飞梁凌熏郭韬张俊戴倩倩齐海鹰刘万勇
Owner PETROCHINA CO LTD
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