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A kind of preparation method of hydrogenation catalyst

A technology of hydrogenation catalyst and pore-enlarging agent, which is applied in the field of hydrogenation catalyst preparation, can solve problems such as uneven distribution of active metal components, influence on catalyst performance, and poor catalyst strength, so as to prevent dust pollution and harm people Harm, shorten drying time, low cost effect

Active Publication Date: 2016-08-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the metal is added to the alumina powder in the form of metal salt powder, it is easy to cause uneven distribution of active metal components and the strength of the catalyst is relatively poor
[0008] In short, there are mainly the following problems in the above-mentioned prior art. Although the cost of the catalyst can be reduced when the catalyst is prepared by the kneading method, the pore volume and pore distribution of the catalyst and the dispersion of the active components will be affected to a certain extent (compared to the impregnation method), Affect the performance of the catalyst

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 2L sodium metaaluminate aqueous solution (with Al 2 o 3 The concentration is 15g / 100mL) and 3L aluminum sulfate aqueous solution (as Al 2 o 3 The concentration of the meter is 3g / 100mL) and put them into the container at the high position respectively, and the flow meter flows into the stainless steel container equipped with a 6L clean water belt agitator and a heating mantle, and heats to 60°C; Aluminum sulfate solution, reduce the pH value of the slurry to 3.0, and after stabilizing for 10 minutes, add the two materials into the stainless steel tank at a certain speed at the same time, keep the pH value at 7.3, and neutralize the gelling reaction for 15 minutes. Then stop adding aluminum sulfate solution, so that the pH value rises to 9.2, stop adding sodium metaaluminate solution, and stabilize for a period of time; pass through aluminum sulfate solution, reduce the pH value of the slurry to 3.0, and stabilize for a period of time; pass through sodium metaaluminate...

Embodiment 2

[0023] Compared with Example 1, after the slurry was filtered and washed, it was dried at 110° C. for 1 hour to obtain pseudo-boehmite with a dry basis of 50%. Weighed 200 grams of pseudo-boehmite and 5.0 grams of carbon black , 2.0 grams of extrusion aid squash powder and 80ml of active metal salt solution, containing ammonium molybdate and basic nickel carbonate in the active metal salt solution, the content is based on MoO 3 15 wt% as NiO, and 3 wt% as NiO. Other material consumption and operating conditions are identical with embodiment 1, make catalyst B.

Embodiment 3

[0025] Compared with Example 1, the slurry was filtered, washed, and dried at 100° C. for 1 hour to obtain pseudo-boehmite with a dry basis of 40%. Other material consumption and operating conditions are identical with embodiment 1, make catalyst C.

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PUM

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Abstract

The invention discloses a hydrogenation catalyst, and a preparation method thereof. The preparation method comprises following steps: pseudo-boehmite with a dry basis content below 55%, preferably ranges from 40% to 50%, is mixed with a salt solution containing high-concentration active metals, and an obtained material is kneaded uniformly so as to obtain a plastomer; the plastomer is subjected to moulding, is dried for 1 to 5h at a temperature of 80 to 120 DEG C, and is roasted for 1 to 6h at a temperature of 300 to 800 DEG C. Preparation processes of the preparation method are simple; cost is low; the preparation method is safe and friendly to the environment; and the hydrogenation catalyst is suitable to be used as a heavy oil hydrotreating catalyst.

Description

technical field [0001] The invention relates to a method for preparing a hydrogenation catalyst, in particular to a method for preparing a high-activity heavy oil hydrogenation catalyst by a kneading method. Background technique [0002] As the world's crude oil gradually becomes heavier and worse, and the market demand for light oil products, especially high-quality clean light oil products, grows rapidly, hydrogenation technology has received special attention worldwide. For example, hydrorefining of various light distillate oils, hydrotreating of heavy oils, etc. [0003] Heavy oil (such as atmospheric residue of crude oil, vacuum residue of crude oil, heavy crude oil, oil sands, synthetic heavy oil products, etc.) contains a large amount of heavy metals (such as nickel, vanadium), sulfur, nitrogen and other impurities, and The content of colloids and asphaltenes is relatively high. In order to meet the requirements of catalytic cracking feed and protect downstream catal...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/883B01J35/10C10G45/08
Inventor 刘杰孙素华朱慧红彭绍忠金浩杨光于淼
Owner CHINA PETROLEUM & CHEM CORP
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