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Nickel-coated graphite electric conduction powder used for electric conduction rubber and manufacturing method thereof

A technology of nickel-coated graphite and conductive powder, applied in the field of nickel-coated graphite conductive powder for conductive rubber and its preparation, can solve the problems that the shielding effect is not as good as that of copper-based conductive rubber, the density of metal fillers is high, and the surface resistivity is high, and the invention can achieve Low cost, improved mechanical strength, good coverage

Inactive Publication Date: 2014-05-28
杨福河
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current conductive fillers have some defects. For example, copper-based coatings have good conductivity, but poor oxidation resistance; silver powder has good conductivity, but is expensive; High density, high cost, etc. At the same time, when nickel powder is made into conductive rubber, its surface resistivity is higher than that of copper-based conductive rubber, and the shielding effect in the low-frequency region (<30MHz) is not as good as that of copper-based conductive rubber.

Method used

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  • Nickel-coated graphite electric conduction powder used for electric conduction rubber and manufacturing method thereof
  • Nickel-coated graphite electric conduction powder used for electric conduction rubber and manufacturing method thereof
  • Nickel-coated graphite electric conduction powder used for electric conduction rubber and manufacturing method thereof

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preparation example Construction

[0041] A preparation method of nickel-coated graphite conductive powder for conductive rubber includes the following steps:

[0042] (Ⅰ) Graphite powder degreasing treatment

[0043] Clean the graphite powder with degreasing liquid at room temperature, and the cleaning time is 10-15 minutes;

[0044] (Ⅱ) Graphite powder acid etching roughening treatment

[0045] Clean the graphite powder after degreasing with clean water, and then use a roughening solution to roughen the surface of the graphite powder under the condition of 40~50℃, and the roughening time is 10-20 minutes;

[0046] (Ⅲ) Surface activation treatment of graphite powder

[0047] Wash the roughened graphite powder with clean water, and then use the activation solution to perform surface activation treatment. Put the graphite powder in at 35~45°C and stir for 20 minutes;

[0048] (Ⅳ) Electroless nickel plating

[0049] The activated graphite powder is washed with clear water, and then electroless nickel plating solution is used ...

Embodiment 1

[0067] A nickel-coated graphite conductive powder for conductive rubber, the components and weight percentages are as follows:

[0068] Nickel 50%

[0069] Graphite 50%.

[0070] The average particle size of the graphite powder particles is 50 microns, the shape of the graphite powder particles is irregular flake, and the nickel is coated on the surface of the graphite powder.

[0071] A preparation method of nickel-coated graphite conductive powder for conductive rubber includes the following steps:

[0072] (Ⅰ) Graphite powder degreasing treatment

[0073] At room temperature, take 10 grams of flake graphite powder with an average particle size of 50 microns, and prepare the graphite powder with 6g / L sodium laureth sulfate and 3g / L nonylphenol polyoxyethylene ether. 500ml degreasing liquid for cleaning, cleaning time is 10 minutes;

[0074] (Ⅱ) Graphite powder acid etching roughening treatment

[0075] Wash the degreasing graphite powder with distilled water for 3 minu...

Embodiment 2

[0083] A nickel-coated graphite conductive powder for conductive rubber, which contains the following components and weight percentages:

[0084] Nickel 80%

[0085] Graphite 20%.

[0086] The average particle size of the graphite powder particles is 130 microns, the shape of the graphite powder particles is fibrous, and the nickel is coated on the surface of the graphite powder.

[0087] A preparation method of nickel-coated graphite conductive powder for conductive rubber includes the following steps:

[0088] (Ⅰ) Graphite powder degreasing treatment

[0089] At room temperature, take 10 grams of fritter-like graphite powder with an average particle size of 130 microns, and prepare the graphite powder with 8g / L sodium laureth sulfate and 4g / L nonylphenol polyoxyethylene ether. 500ml degreasing liquid for cleaning, cleaning time is 15 minutes;

[0090] (Ⅱ) Graphite powder acid etching roughening treatment

[0091] Wash the degreasing graphite powder with distilled water fo...

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Abstract

The invention concretely discloses a nickel-coated graphite electric conduction powder used for electric conduction rubber and a manufacturing method of the nickel-coated graphite electric conduction powder. The nickel-coated graphite electric conduction powder used for the electric conduction rubber comprises 50-80% of nickel and 20-50% of graphite. The manufacturing method of the nickel-coated graphite electric conduction powder used for the electric conduction rubber mainly includes the four steps of oil removing treatment on graphite powder, acid etching and roughening treatment on the graphite powder, surface activating treatment on the graphite powder and chemical nickel plating. The nickel-coated graphite electric conduction powder has the advantages of pure nickel and pure graphite, is low in cost and not prone to rusting and further can improve the mechanical strength of the electric conduction rubber material. The chemical nickel plating method is easy to operate and simple in technology, plated layers are even and compact, the throwing power is high, plating can be performed on particles in any shape, the covering power is high, and the even, fine and dispersed composite powder can be manufactured.

Description

Technical field [0001] The invention belongs to a conductive powder for electromagnetic shielding and a preparation method thereof, in particular to a nickel-coated graphite conductive powder for conductive rubber and a preparation method thereof. Background technique [0002] In recent years, with the popularization of various electrical appliances, computers, communication satellites, high-voltage transmission grids, and some medical equipment have been widely used, especially with the miniaturization, integration, lightweight and digitalization of electronic circuits and components, resulting in daily use Of electronic products are susceptible to interference from external electromagnetic waves and malfunction. Therefore, electromagnetic shielding and absorbing materials will become new materials in the application field, and conductive fillers are the main raw materials that constitute high-performance electromagnetic wave shielding and absorbing materials. However, current ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F1/02C23C18/36C23C18/18
Inventor 杨福河
Owner 杨福河
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