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A water-resistant curing agent for water glass binder

A curing agent, water glass technology, applied in non-polymer adhesive additives, adhesives, inorganic adhesives and other directions, can solve the problems of poor water resistance, complicated preparation process of curing agent, difficult to obtain satisfactory results, etc. Quick and easy process, high water resistance effect

Inactive Publication Date: 2016-08-17
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because water glass has strong water absorption alkali metal oxides and water-soluble sodium silicate remaining in the hardened product, it has poor water resistance and is not suitable for use in long-term humid environments, and cannot withstand the impact of hot water and boiling water. , which limits the application range of the adhesive
[0003] At present, curing agents such as sodium fluorosilicate and condensed phosphate are often used to improve the water resistance of water glass cured products. It is difficult to obtain satisfactory results in actual use of these curing agents.
[0004] Chinese patent CN85103047A describes a water glass hardening agent, the water resistance of its cured product has been greatly improved compared with that of sodium fluorosilicate as the curing agent, but the preparation process of its curing agent is relatively complicated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A water-resistant water glass curing agent, each component includes: 3 parts of calcium oxide, 2 parts of boric acid, 5 parts of aluminum oxide, 20 parts of silicon dioxide, 15 parts of zinc oxide, the particle size of each of the above components is less than 10 μm. Mix the above components evenly to obtain a curing agent;

[0031] According to the mass ratio of curing agent and water glass 2.5:5, mix evenly; in the process of adding curing agent, add appropriate amount of water according to the situation, adjust the viscosity of the slurry so that it can be fully mixed uniformly; the obtained slurry The material is left at room temperature for 2 hours, and then heated at 60°C for 8 hours to obtain a cured product with good water resistance. Divide the curing agent into three equal parts and slowly add it to the water glass three times, and mix well. Above-mentioned water glass adopts sodium water glass.

[0032] The cured product obtained in Example 1, after being ...

Embodiment 2

[0034] A kind of water glass water-resistant curing agent, each component comprises by mass parts: 3 parts of calcium oxide, 5 parts of boric acid, 22 parts of aluminum oxide, 10 parts of silicon dioxide, 20 parts of zinc oxide, and the particle size of above-mentioned each component is all less than 10 μm. Mix the above components evenly to obtain a curing agent;

[0035] According to the mass ratio of curing agent and water glass 3:5, mix evenly; in the process of adding curing agent, add appropriate amount of water according to the situation, adjust the viscosity of the slurry so that it can be fully mixed uniformly; the obtained slurry The material is left at room temperature for 2 hours, and then heated at 60°C for 8 hours to obtain a cured product with good water resistance. Divide the curing agent into three equal parts and slowly add it to the water glass three times, and mix well. Above-mentioned water glass adopts sodium water glass.

[0036] The cured product obt...

Embodiment 3

[0038] A kind of water glass water-resistant curing agent, each component comprises by mass parts: 0.5 parts of calcium oxide, 5 parts of boric acid, 20 parts of aluminum oxide, 5 parts of silicon dioxide, 50 parts of zinc oxide, and the particle size of above-mentioned each component is all less than 10 μm. Mix the above components evenly to obtain a curing agent;

[0039] According to the mass ratio of curing agent and water glass 4:5, mix evenly; in the process of adding curing agent, add appropriate amount of water according to the situation, adjust the viscosity of the slurry so that it can be fully mixed uniformly; the obtained slurry The material is left at room temperature for 2 hours, and then heated at 60°C for 8 hours to obtain a cured product with good water resistance. Divide the curing agent into three equal parts and slowly add it to the water glass three times, and mix well. Above-mentioned water glass adopts potassium water glass.

[0040] The cured product...

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PUM

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Abstract

The invention discloses a water-resistant curing agent for a sodium silicate binder. The water-resistant curing agent comprises the following components in parts by mass: 0.5-3 parts of calcium oxide, 1-5 parts of boric acid, 5-30 parts of alumina, 3-20 parts of silica and 15-50 parts of zinc oxide. The water-resistant curing agent for the sodium silicate binder has the characteristics that the curing product is relatively high in water resistance, the preparation process of the curing agent is rapid and convenient, sodium silicate is applied to preparation of a protective coating, and the like.

Description

technical field [0001] The invention relates to the field of water-resistant curing agents, in particular to a water-resistant curing agent used for water glass adhesives. Background technique [0002] Silicate aqueous solution is commonly known as water glass, which can be divided into sodium water glass, potassium water glass, lithium water glass and quaternary ammonium water glass according to the type of alkali metal. Sodium silicate glass is widely used in coatings, fireproof materials, furnace linings, ceramics, metal anticorrosion, cartons, grouting materials, casting materials and other fields because of its advantages of simple manufacture, low price, green environmental protection, acid resistance, and high temperature resistance. One of the most widely used inorganic binders. However, because water glass has strong water absorption alkali metal oxides and water-soluble sodium silicate remaining in the hardened product, it has poor water resistance and is not suit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J1/02C09J11/04C09D1/02C09D7/12
Inventor 王丽阁张凡王恩泽张政权李良锋周永生陈倛杨柳
Owner SOUTHWEAT UNIV OF SCI & TECH