Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, optical component and touch panel
An adhesive layer and composition technology, applied in the directions of non-polymer adhesive additives, adhesive types, adhesive additives, etc., can solve the problems of corrosion, easy oxidation, etc. cost reduction effect
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manufacture example 1)
[0280]60 parts by weight of tetrahydrodicyclopentadienyl methacrylate (DCPMA), 40 parts by weight of methyl methacrylate (MMA), 3.5 parts by weight of α-thioglycerol as a chain transfer agent, and 3.5 parts by weight of α-thioglycerol as a polymerization solvent 100 parts by weight of toluene was charged into a four-necked flask, and stirred at 70° C. for 1 hour under a nitrogen atmosphere. Then, 0.2 parts by weight of 2,2'-azobisisobutyronitrile as a polymerization initiator was put into a four-necked flask, and reacted at 70°C for 2 hours, and then reacted at 80°C for 2 hours. Then, the reaction solution was put into a temperature environment of 130° C., and the toluene, the chain transfer agent, and the unreacted monomer were removed by drying to obtain a solid acrylic polymer. In addition, this acrylic polymer is called "acrylic polymer (B-1)".
[0281] In addition, the weight average molecular weight (Mw) of the acrylic polymer (B-1) was 5.1×10 3 .
Embodiment 1
[0283] In a monomer mixture composed of 68 parts by weight of 2-ethylhexyl acrylate (2EHA), 14.5 parts by weight of N-vinyl-2-pyrrolidone (NVP) and 17.5 parts by weight of 2-hydroxyethyl acrylate (HEA), Mix 0.035 parts by weight of a photopolymerization initiator (trade name "Irugakua 184", manufactured by BASF Corporation) and 0.035 parts by weight of a photopolymerization initiator (trade name "Irugakiure 651", manufactured by BASF Corporation), and then irradiate ultraviolet light until the viscosity (BH viscometer, No. 5 rotor, 10 rpm, measuring temperature 30°C) reached about 20 Pa·s, and obtained a prepolymer composition in which a part of the above-mentioned monomer components were polymerized.
[0284] Then, 5 parts by weight of the above-mentioned acrylic polymer (B-1), 0.075 parts by weight of hexanediol diacrylate (HDDA), a silane coupling agent (trade name "KBM -403", manufactured by Shin-Etsu Chemical Co., Ltd.) and 0.05 parts by weight of 1,2,3-benzotriazole (tra...
Embodiment 2
[0288] Except having made the usage-amount of 1,2,3-benzotriazole into 0.1 weight part, it carried out similarly to Example 1, and obtained the base material-less double-sided adhesive sheet.
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