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Special polyethylene coloring masterbatch for white thin film and preparation method of masterbatch

A technology of white film and coloring masterbatch, applied in the field of plastic additives, can solve the problems of poor heat resistance of masterbatch, influence of dispersibility and high production cost, achieve strong price and quality advantages, improve mechanical properties, and low production cost Effect

Inactive Publication Date: 2014-09-24
BLUESTAR CHENGDU NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of ordinary white masterbatch in the field of film processing will bring two problems: 1. Poor dispersion due to uneven mixing or insufficient melting; 2. High production cost; 3. Poor heat resistance of the masterbatch , leading to yellowing of film products
Especially when the proportion of pigment is large, although high-concentration white masterbatch can be prepared, when it is used in film production, the dispersibility will be seriously affected, and the production cost is high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A special polyethylene coloring masterbatch for white films is composed of the following raw materials in parts by weight: 20 parts of resin, 5 parts of polyethylene wax, 0.5 part of white oil, 0.5 part of zinc stearate, 10 parts of titanium dioxide, and 25 parts of high-quality calcium carbonate; the resin is a mixture of low-density high-pressure polyethylene and linear low-density, and its ratio is 5:3.

[0017] The preparation method comprises the following steps: after weighing the above-mentioned raw materials respectively, adding the weighed mixed resin, titanium dioxide, heavy calcium carbonate, polyethylene wax, zinc stearate and white oil into a high-speed mixer in sequence, and first Control the speed at 475 r / min and run at low speed for 5 minutes, then control the speed at 850 r / min and run at high speed for 25 minutes, then control the speed at 600 r / min and run at low speed for 5 minutes; transfer the mixed material to the main engine at a speed of 200 r / m...

Embodiment 2

[0019] A special polyethylene coloring masterbatch for white films, consisting of the following raw materials in parts by weight: 38 parts of resin, 10 parts of polyethylene wax, 1.5 parts of white oil, 1.5 parts of zinc stearate, 35 parts of titanium dioxide, and 40 parts of high-quality calcium carbonate; the resin is a mixture of low-density high-pressure polyethylene and linear low-density, and its ratio is 8:3.

[0020] The polyethylene wax is a solid low-molecular polyethylene wax with a molecular weight of 2000-3000.

[0021] The said titanium dioxide is rutile type titanium dioxide, and its content of titanium dioxide is more than or equal to 93%.

[0022] The preparation method comprises the following steps: after weighing the above-mentioned raw materials respectively, adding the weighed mixed resin, titanium dioxide, heavy calcium carbonate, polyethylene wax, zinc stearate and white oil into a high-speed mixer in sequence, first Control the speed at 500r / min and ru...

Embodiment 3

[0024] A special polyethylene coloring masterbatch for white films, consisting of the following raw materials in parts by weight: 30 parts of resin, 8 parts of polyethylene wax, 1 part of white oil, 1 part of zinc stearate, 25 parts of titanium dioxide, and 35 parts of calcium carbonate. The resin is a mixture of low-density high-pressure polyethylene and linear low-density, and its ratio is 6:3.

[0025] The polyethylene wax is a solid low-molecular polyethylene wax with a molecular weight of 2000-3000.

[0026] The said titanium dioxide is rutile type titanium dioxide, and its content of titanium dioxide is more than or equal to 93%.

[0027] The preparation method comprises the following steps: after weighing the above-mentioned raw materials respectively, adding the weighed mixed resin, titanium dioxide, heavy calcium carbonate, polyethylene wax, zinc stearate and white oil into a high-speed mixer in sequence, and first Control the speed at 500r / min and run at low speed ...

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PUM

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Abstract

The invention discloses a special polyethylene coloring masterbatch for a white thin film. The special polyethylene coloring masterbatch is prepared from the following raw materials in parts by weight: 20-38 parts of resin, 5-10 parts of polyethylene wax, 0.5-1.5 parts of white oil, 0.5-1.5 parts of zinc stearate, 10-35 parts of titanium dioxide and 25-40 parts of ground calcium carbonate; the resin is a mixture of low-density high pressure polyethylene and linear low-density polyethylene in the ratio of (5-8):3. A preparation method of the special polyethylene coloring masterbatch comprises the steps of weighing the raw materials, namely the mixed resin, titanium dioxide, ground calcium carbonate, polyethylene wax, zinc stearate and white oil, orderly adding the raw materials to a high-speed mixer and mixing thoroughly; after finishing mixing, transferring the mixture to a twin-screw extruder for melt extrusion, and then cooling, drying and pelleting, and finally, packaging. The special polyethylene coloring masterbatch is applied to the plastic industry, and is good in dispersity, high in heat resistance and low in production cost, and meanwhile, capable of improving the mechanical properties and the printing performance of the thin film products, and has outstanding price and quality advantages.

Description

technical field [0001] The invention relates to a polyethylene coloring masterbatch and a preparation method thereof, in particular to a polyethylene coloring masterbatch special for white films and a preparation method thereof, belonging to the field of plastic additives. Background technique [0002] White film has a wide range of applications, and can be used in different fields according to different whiteness, thickness and dispersion, such as: agricultural film, supermarket shopping bags, food packaging bags, etc. In 2012, the national output of plastic films was 10.8935 million tons, a year-on-year increase of 7.61%, of which white films accounted for the majority, and the demand for coloring masterbatches needed to produce white films also increased. The conventional production of white film is generally to mix resin, titanium dioxide, dispersant, coupling agent, etc. through a high-speed mixer, and then directly melt extrude, cool, dry, and granulate. The use of or...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08K13/02C08K5/098C08K3/22C08K3/26C08J3/22B29B9/06B29C47/92B29C48/92
CPCB29B7/728B29B9/12B29C47/8895B29B7/46B29B9/06B29C47/92B29B7/72B29C48/92B29C2948/9258C08K2201/003C08L23/06C08L2203/16C08L2205/025C08L2205/03C08L2207/066C08L2310/00C08L23/0815C08K13/02C08K5/098C08K2003/2241C08K2003/265B29C48/40B29C2948/9259B29C2948/92828
Inventor 高川郭玲孙潜
Owner BLUESTAR CHENGDU NEW MATERIALS
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