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Method for separating mixture of catalytic cracking rich gas and methanol-to-olefin reaction product

A technology for producing olefins and reaction products from methanol, which is applied in the fields of producing hydrocarbons from oxygen-containing organic compounds, organic chemistry, refining and cracking processes only in multi-stage series, etc. To wait for the problem, to achieve the effect of reducing investment, reducing the degree of transformation, and small changes in kettle temperature

Active Publication Date: 2014-12-03
WISON ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method does not take into account that the proportion of C4-C6 circulating hydrocarbons contained in the methanol-to-olefins reaction product is larger than that of catalytic cracking rich gas. If all the methanol-to-olefins reaction products are directly sent to the catalytic cracking rich gas compression and absorption stabilization system for separation, The operating conditions will be greatly changed from the original design value, the degree of equipment transformation will be relatively large, and the investment required for transformation will be relatively high

Method used

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  • Method for separating mixture of catalytic cracking rich gas and methanol-to-olefin reaction product
  • Method for separating mixture of catalytic cracking rich gas and methanol-to-olefin reaction product
  • Method for separating mixture of catalytic cracking rich gas and methanol-to-olefin reaction product

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Effect test

Embodiment 1

[0041] Figure 4 In the method for mixing and separating catalytic cracking rich gas and methanol-to-olefins reaction products of the present invention: 100 methanol-to-olefins reaction units, 200 compression units, 300 separation heat zones, 600 catalytic cracking units, 700 absorption stabilization units, and 800 gas fractionation units.

[0042] Figure 5 with Image 6 In the flow chart of the compression unit of the present invention: T-201 pre-depropanizer;

[0043] Figure 7 In the flow chart of the separation heat zone of the present invention: T-301 dehexanizer, T-302 debutanizer;

[0044] Method for mixing and separating catalytic cracking rich gas and methanol to olefins reaction products ( Figure 4 ) is: methanol to olefins reaction unit 100 uses methanol 401 as raw material, steam 402, C4-C6 circulating hydrocarbon 403 and C4 circulating hydrocarbon 417 as diluent gas to carry out catalytic reaction in an adiabatic fixed bed, and the reaction product is heat r...

Embodiment 2

[0058] Near certain 1,000,000 tons / year catalytic cracking unit, newly build a set of 250,000 tons / year methanol feedstock methanol-to-olefins unit, the flow process used adopts catalytic cracking rich gas of the present invention and methanol-to-olefins reaction product mixed separation method ( Figure 4 ). The original absorption stabilization unit 700 and gas fractionation unit 800 of the catalytic cracking unit are used to separate the reaction products of the methanol-to-olefins unit, and the methanol-to-olefins unit only needs to build a methanol-to-olefins reaction unit 100 and a compression unit 200 ( Figure 5 ) and separation hot zone 300 ( Figure 7 ).

[0059] The pressure of the rich gas produced by the catalytic cracking unit is 1.00MPaG, and the mass ratio of C3 and C4 in the rich gas is 0.50. The reaction unit of the new methanol-to-olefins plant adopts the existing disclosed technology, and the compression unit 200 adopts the following Figure 5 The flow s...

Embodiment 3

[0071] Near a certain 1,500,000 tons / year catalytic cracking unit, newly build a set of 300,000 tons / year methanol feedstock methanol-to-olefins unit, the separation process adopts the mixed separation method of catalytic cracking rich gas and methanol-to-olefins reaction product of the present invention ( Figure 4 ). Using the original absorption stabilization unit 700 and gas fractionation unit 800 of the catalytic cracking unit to replace the separation cold zone 400 and the propylene refrigeration unit 500 to separate the reaction products of the methanol-to-olefins unit, the methanol-to-olefins unit only needs to build a new methanol-to-olefins reaction unit 100, Compression unit 200 ( Image 6 ) and separation hot zone 300 ( Figure 7 ), requiring only minor modifications to the original absorption stabilization unit 700 and gas fractionation unit 800.

[0072] The pressure of the rich gas produced by the catalytic cracking unit is 0.90 MPaG, and the mass ratio of C3 ...

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Abstract

The invention relates to a method for separating a mixture of catalytic cracking rich gas and a methanol-to-olefin reaction product. According to the method, a catalytic cracking unit, an absorption stabilization unit, a gas fractionation unit and a set of methanol-to-olefin device are provided; the device comprises a reaction unit, a compression unit and a separation hot region; the methanol-to-olefin reaction product is compressed and separated through a pre-depropanizing tower, C4 is non-clearly cut, C1-C4 at the top of the tower are mixed with the catalytic cracking rich gas to obtain a mixture, and the mixture is separated by virtue of the absorption stabilization unit and the gas fractionation unit; residual liquid is separated through the separation hot region to form C4 products, C4-C6 cyclic hydrocarbons and gasoline; all or part of C4 products (containing catalytic cracking byproducts C4) of the gas fractionation unit return to a methanol-to-olefin reaction unit. Compared with the prior art, the method is used for a catalytic cracking and methanol-to-olefin combined device, a separation cold region and a refrigeration unit of a conventional methanol-to-olefin device can be omitted, the treating capacity of a catalytic cracking device is increased to the maximum extent, the economy of the catalytic cracking byproducts C4 is improved through circular cracking, and the operating energy consumption of the methanol-to-olefin device is reduced.

Description

technical field [0001] The invention belongs to the technical field of light hydrocarbon separation, and relates to a catalytic cracking and methanol-to-olefin combined device, in particular to the separation of catalytic cracking rich gas and methanol-to-olefin reaction product mixture. Background technique [0002] Methanol to olefins technology is to convert methanol into low-carbon hydrocarbons under the action of catalysts, including fluidized bed technology and fixed bed technology: fluidized bed technology, DMTO technology of Dahua Institute, MTO technology of UOP company and Sinopec Represented by SMTO technology, etc., the main products of fluidized bed methanol to olefins technology are ethylene and propylene products, and by-product fuel gas and C4+ products. The fluidized bed removes heat quickly, uses steam as the dilution gas, and does not need to recycle hydrocarbons back to the reactor. Fixed bed technologies include Lurgi's MTP technology, Wison's WMTO tech...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C11/06C07C1/20C10G55/06
Inventor 吕建宁丁干红彭新文栾业志
Owner WISON ENG
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