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A kind of UV-curable ethylenic polyester coating for ceramics

A polyester coating, ultraviolet light technology, applied in the coating field, can solve the problems of low adhesion, slow drying, solvent resistance and abrasion resistance, etc.

Active Publication Date: 2017-01-04
广东百川化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above technical problems, the present application provides a UV-curable vinyl polyester coating for ceramics, which solves the problems of low adhesion, slow drying, solvent resistance and poor wear resistance of the existing ceramic UV-curable vinyl polyester coatings. question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] A kind of ceramic UV-curable vinyl polyester coating, its raw material ratio is as follows by weight: 100 parts of epoxy acrylate; 20 parts of triglycidyl isocyanurate; 50 parts of polyurethane acrylate; 1,2 - 5 parts of cyclohexane dicarboxylic anhydride; 70 parts of diethylene glycol diacrylate; 25 parts of xylene; 10 parts of benzoin ether; 40 parts of terebenzoic acid; 20 parts of trimethylolpropane triacrylate; 40 parts of ethylene ; 1 part of antioxidant 1010; 10 parts of vinyl acetate; 20 parts of acrylate; 30 parts of ethyl acrylate; 5 parts of hexamethoxymethyl melamine.

[0014] The above raw materials are mixed evenly in a reaction kettle and stored away from light, coated on ceramics, and the coating film can be irradiated with ultraviolet lamps.

[0015] Product adhesion level 2, hardness 3H; soaked in water for 10 days without blistering or falling off, surface dry time 5s, hard dry 15s; soaked in 5% hydrochloric acid solution for 2d without abnormalities,...

Embodiment 2

[0017] A kind of ceramic UV-curable vinyl polyester coating, its raw material ratio is as follows by weight: 100 parts of epoxy acrylate; 30 parts of triglycidyl isocyanurate; 70 parts of polyurethane acrylate; 1,2 - 15 parts of cyclohexane dicarboxylic anhydride; 90 parts of diethylene glycol diacrylate; 35 parts of xylene; 20 parts of 1-hydroxycyclohexyl phenyl ketone; 60 parts of terephthalic acid; 40 parts of ester; 50 parts of ethylene; 5 parts of antioxidant 1010; 30 parts of vinyl acetate; 30 parts of acrylate; 40 parts of ethyl acrylate; 15 parts of hexamethoxymethylmelamine.

[0018] The above raw materials are mixed evenly in a reaction kettle and stored away from light, coated on ceramics, and the coating film can be irradiated with ultraviolet lamps.

[0019] Product adhesion level 2, hardness 5H; soaked in water for 15 days without blistering or falling off, surface dry time 3s, hard dry 10s; soaked in 5% hydrochloric acid solution for 2d without abnormalities, so...

Embodiment 3

[0021] A kind of ceramic UV-curable vinyl polyester coating, its raw material ratio is as follows by weight: 100 parts of epoxy acrylate; 25 parts of triglycidyl isocyanurate; 60 parts of polyurethane acrylate; 1,2 - 10 parts of cyclohexane dicarboxylic anhydride; 80 parts of diethylene glycol diacrylate; 30 parts of xylene; 15 parts of 1-hydroxycyclohexyl phenyl ketone; 50 parts of terephthalic acid; 30 parts of ester; 45 parts of ethylene; 3 parts of antioxidant 1010; 20 parts of vinyl acetate; 25 parts of acrylate; 35 parts of ethyl acrylate; 10 parts of hexamethoxymethylmelamine.

[0022] The above raw materials are mixed evenly in a reaction kettle and stored away from light, coated on ceramics, and the coating film can be irradiated with ultraviolet lamps.

[0023] Product adhesion level 1, hardness 6H; no blistering or shedding after soaking in water for 20 days, surface dry time for 1 second, hard drying for 5 seconds; soaking in 5% hydrochloric acid solution for 3 day...

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Abstract

The invention discloses an ultraviolet light-curable vinyl polyester coating for ceramics. The raw materials are: epoxy acrylate, triglycidyl isocyanurate, polyurethane acrylate, 1,2-cyclohexanedicarboxylic anhydride, di Ethylene glycol diacrylate, xylene, photoinitiator, terebenzoic acid, trimethylolpropane triacrylate, ethylene, antioxidants, vinyl acetate, acrylates, ethyl acrylate, and hexamethoxymethylmelamine; product Adhesion level 1‑2, hardness 3‑6H; no blistering or shedding after soaking in water for 10‑20d, surface dry time 1‑5s, hard drying 5‑15s; soaking in 5% hydrochloric acid solution for 2‑3d without abnormalities, Soak in gasoline for 5‑10d without foaming and wrinkling; the product has a scrub resistance of 800‑1000 times.

Description

technical field [0001] The application belongs to the field of coatings, in particular to an ultraviolet light-curable ethylenic polyester coating for ceramics. Background technique [0002] Epoxy acrylate resin, also known as vinyl ester resin, is a denatured epoxy resin dissolved in styrene after the reaction of epoxy resin and acrylic acid. Epoxy acrylate resin has the excellent characteristics of epoxy resin, but it is more excellent in curability and formability, and it is not as cumbersome as epoxy resin, and it is a thermosetting resin. It has excellent water resistance, hot water resistance, drug resistance, cohesiveness, toughness. It can be cured by organic peroxide curing method (low temperature-high temperature) or light curing method, and is widely used in the following fields: corrosion-resistant FRP products, such as glass fiber reinforced plastic tanks, pipes, towers and corrosion-resistant grids, etc.; anti-corrosion Corrosion engineering, such as cement-b...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/10C09D175/14C09D7/12
Inventor 刘广灿
Owner 广东百川化工有限公司